Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 11/2014

01.11.2014

Interaction of Benzimidazoles and Benzotriazole: Its Corrosion Protection Properties on Mild Steel in Hydrochloric Acid

verfasst von: K. Ramya, Revathi Mohan, Abraham Joseph

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 11/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Synergistic hydrogen-bonded interaction of alkyl benzimidazoles and 1,2,3-benzotrizole and its corrosion protection properties on mild steel in hydrochloric acid at different temperatures have been studied using polarization, EIS, adsorption, surface studies, and computational methods. The extent of synergistic interaction increases with temperature. Quantum chemical approach is used to calculate some electronic properties of the molecules and to ascertain the synergistic interaction, inhibitive effect, and molecular structures. The corrosion inhibition efficiencies and the global chemical reactivity relate to some parameters, such as total energy, E HOMO, E LUMO, and gap energy (ΔE). 1,2,3-Benzotrizole interacts with benzimidazoles derivatives up to a bond length of approximately 1.99 Å. This interaction represents the formation of a hydrogen bond between the 1,2,3-benzotrizole and benzimidazoles. This synergistic interaction of 1,2,3-benzotrizole and benzimidazole derivatives offers extended inhibition efficiency toward mild steel in hydrochloric acid.
Vorheriger Artikel Investigating the Significance of Bicarbonate with the Corrosion of High-Strength Steel in CO2-Saturated Solutions
Nächster Artikel Inhibitive Performance of a Rust Converter on Corrosion of Mild Steel

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
B. Xu, W. Yang, Y. Liu, X. Yin, W. Gong, and Y. Chen, Experimental and Theoretical Evaluation of Two Pyridinecarboxaldehyde Thiosemicarbazone Compounds as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution, Corros. Sci., 2014, 78, p 260–268CrossRef
2.
R.A. Prabhu, T.V. Venkatesha, A.V. Shanbhag, B.M. Praveen, G.M. Kulkarni, and R.G. Kalkhambkar, Quinol-2-thione Compounds as Corrosion Inhibitors for Mild Steel in Acid Solution, Mater. Chem. Phys., 2008, 108, p 283–289CrossRef
3.
K. Mallaiya, R. Subramaniam, S.S. Srikandan, S. Gowri, N. Rajasekaran, and A. Selvaraj, Electrochemical Characterization of the Protective Film Formed by the Unsymmetrical Schiff’s Base on the Mild Steel Surface in Acid Media, Electrochim. Acta., 2011, 56, p 3857–3863CrossRef
4.
D.D.N. Singh, T.B. Singh, and B. Gaur, The Role of Metal Cations in Improving the Inhibitive Performance of Hexamine on the Corrosion of Steel in Hydrochloric Acid Solutions, Corros. Sci., 1995, 37, p 1005–1019CrossRef
5.
X.H. Li, S.D. Deng, H. Fu, and T.H. Li, Adsorption and Inhibition Effect of 6-Benzylaminopurine on Cold Rolled Steel in 1.0 M HCl, Electrochim. Acta., 2009, 54, p 4089–4098CrossRef
6.
A. Doner, E.A. Sahin, G. Kardas, and O. Serindag, Investigation of Corrosion Inhibition Effect of 3-[(2-Hydroxy-benzylidene)-amino]-2-thioxo-thiazolidin-4-one on Corrosion of Mild Steel in the Acidic Medium, Corros. Sci., 2013, 66, p 278–284CrossRef
7.
M.A. Hegazy, A.M. Hasan, M.M. Emara, M.F. Bakr, and A.H. Youssef, Evaluating Four Synthesized SCHIFF Bases as Corrosion Inhibitors on the Carbon Steel in 1 M Hydrochloric Acid, Corros. Sci., 2012, 65, p 67–76CrossRef
8.
M. Mahdavian and S. Ashhari, Corrosion Inhibition Performance of 2-Mercaptobenzimidazole and 2-Mercaptobenzoxazole Compounds for Protection of Mild Steel in Hydrochloric Acid Solution, Electrochim. Acta., 2010, 55, p 1720–1724CrossRef
9.
G. Avci, Corrosion Inhibition of Indole-3-acetic Acid on Mild Steel in 0.5 M HCl, Colloids Surf. A, 2008, 317, p 730–736CrossRef
10.
A. Kokalj, Is the Analysis of Molecular Electronic Structure of Corrosion Inhibitors Sufficient to Predict the Trend of Their Inhibition Performance, Electrochim. Acta., 2010, 56, p 745–755CrossRef
11.
M.M. Antonijevic and M.B. Petrovic, Copper Corrosion Inhibitors. A Review, Int. J. Electrochem. Sci., 2008, 3, p 1–28
12.
J.O. Bockris and A.K.N. Reddy, Modern Electrochemistry, 2nd ed., Kluwer Academic/Plenum Publishers, New York, 2000
13.
V. Sastri, Corrosion Inhibition Mechanisms, John Wiley & Sons Inc, Hoboken, NJ, 2011
14.
A. Kosari, M.H. Moayed, A. Davoodi, R. Parvizi, M. Momeni, H. Eshghi, and H. Moradi, Electrochemical and Quantum Chemical Assessment of Two Organic Compounds from Pyridine Derivatives as Corrosion Inhibitors for Mild Steel in HCl Solution Under Stagnant Condition and Hydrodynamic Flow, Corros. Sci., 2014, 78, p 138–150CrossRef
15.
M.A. Quraishi, F.A. Ansari, and D. Jamal, Thiourea Derivatives as Corrosion Inhibitors for Mild Steel in Formic Acid, Mater. Chem. Phys., 2002, 77, p 687–690CrossRef
16.
A.M. Fekry and R.R. Mohamed, Acetyl Thiourea Chitosan as an Eco-friendly Inhibitor for Mild Steel in Sulphuric Acid Medium, Electrochim. Acta., 2010, 55, p 1933–1939CrossRef
17.
R. Agrawal and T.K.G. Namboodhiri, The Inhibition of Sulphuric Acid Corrosion of 410 Stainless Steel by Thioureas, Corros. Sci., 1990, 30, p 37–52CrossRef
18.
V.V. Torres, R.S. Amado, C.F. de Sa, T.L. Fernandez, C.A.S. Riehl, A.G. Torres, and E.D. Elia, Inhibitory Action of Aqueous Coffee Ground Extracts on the Corrosion of Carbon Steel in HCl Solution, Corros. Sci., 2011, 53, p 2385–2392CrossRef
19.
K.F. Khaled, Experimental, Density Function Theory Calculations and Molecular Dynamics Simulations to Investigate the Adsorption of Some Thiourea Derivatives on Iron Surface in Nitric Acid Solutions, Appl. Surf. Sci., 2010, 256, p 6753–6763CrossRef
20.
K.F. Khaled, Application of Electrochemical Frequency Modulation for Monitoring Corrosion and Corrosion Inhibition of Iron by Some Indole Derivatives in Molar Hydrochloric Acid, Mater. Chem. Phys., 2008, 112, p 290–300CrossRef
21.
J. Alijourani, K. Raessi, and M.A. Golozar, Benzimidazole and Its Derivatives as Corrosion Inhibitors for Mild Steel in 1 M HCl Solution, Corros. Sci., 2009, 51, p 1836–1843CrossRef
22.
E.E. Ebenso, Synergistic Effect of Halide Ions on the Corrosion Inhibition of Aluminium in H2SO4 Using 2-Acetylphenothiazine, Mater. Chem. Phys., 2003, 79, p 58–70CrossRef
23.
F. Bentiss, M. Lagrenee, M. Traisnel, and J.C. Hornez, The Corrosion Inhibition of Mild Steel in Acidic Media by a New Triazole Derivative, Corros. Sci., 1999, 41, p 789–803CrossRef
24.
M.G. Hosseini, H. Tavakoli, and T. Shahrabi, Synergism in Copper Corrosion Inhibition by Sodium Dodecylbenzenesulphonate and 2-Mercaptobenzoimidazole, J. Appl. Electrochem., 2008, 38, p 1629–1636CrossRef
25.
S.F. Mertens, C. Xhoffer, B.C. De Cooman, and E. Temerman, Short-Term Deterioration of Polymer-Coated 55% Al-Zn—Part 1: Behavior of Thin Polymer Films, Corrosion, 1997, 53, p 381–387CrossRef
26.
K. Ramya and A. Joseph, Dependence of Temperature on the Corrosion Protection Properties of Vanillin and Its Derivatives, HMATD, Towards Copper in Nitric Acid. Theor. Electro Anal. Stud. Doi: 10.​1007/​s11164-013-1254-5
27.
W.J. Hehre, L. Radom, P.V.R. Schleyer, and A.J. Pople, Ab initio Molecular Orbital Theory, Wiley-Interscience, New York, 1986
28.
J.F. Janak, Proof that δE/δni = ε in Density Functional Theory, Phys. Rev. B., 1978, 18, p 7138–7165CrossRef
29.
R. Stowasser and R. Hoffmann, What Do the Kohn−Sham Orbitals and Eigenvalues Mean?, J. Am. Chem. Soc., 1999, 121, p 3414–3420CrossRef
30.
A.E. Reed, L.A. Curtiss, and F. Weinhold, Intermolecular Interactions from a Natural Bond Orbital, Donor-Acceptor Viewpoint, Chem. Rev., 1988, 88, p 899–926CrossRef
31.
R.G. Pearson, Absolute Electronegativity and Hardness: Application to Inorganic Chemistry, Inorg. Chem., 1988, 27, p 734–740CrossRef
32.
R.G. Parr and W. Yang, Density Functional Approach to the Frontier—Electron Theory of Chemical Reactivity, J. Am. Chem. Soc., 1984, 106, p 4049–4050CrossRef
33.
K.F. Khaled, Studies of Iron Corrosion Inhibition Using Chemical, Electrochemical and Computer Simulation Techniques, Electrochim. Acta., 2010, 55, p 6523–6532CrossRef
34.
W. Yang and W.J. Mortier, The Use of Global and Local Molecular Parameters for the Analysis of the Gas-Phase Basicity of Amines, J. Am. Chem. Soc., 1986, 108, p 5708–5711CrossRef
35.
M. Mobin, M. Parveen, and M.Z.A. Rafiquee, Synergistic Influence of Sodium Dodecyl Sulfate and Cetyltrimethyl Ammonium Bromide on the Corrosion Inhibition Behavior of l-Methionine on Mild Steel in Acidic Medium, Arab. J. chem., Doi: 10.​1016/​j.​arabjc.​2013.​04.​006
36.
I. Dehri, H. Sozusag˘lam, and M. Erbil, EIS Study of the Effect of High Levels of NH3 on the Deformation of Polyester-Coated Galvanised Steel at Different Relative Humidities, Prog. Org. Coat., 2003, 48, p 118–123CrossRef
37.
F. Bentiss, M. Lebrini, and M. Lagrenee, Benzimidazole and Its Derivatives as Corrosion Inhibitors for Mild Steel in 1 M HCl Solution, Corros. Sci., 2005, 47, p 2915–2931CrossRef
38.
M. El Azhar, B. Mernari, M. Traisnel, F. Bentiss, and M. Lagrenee, Corrosion Inhibition of Mild Steel by the New Class of Inhibitors [2,5-Bis(n-pyridyl)-1,3,4-thiadiazoles] in Acidic Media, Corros. Sci., 2001, 43, p 2229–2238CrossRef
39.
A. Yurt, A. Balaban, S.U. Kandemir, G. Bereket, and B. Erk, Investigation on Some Schiff Bases as HCl Corrosion Inhibitors for Carbon Steel, Mater. Chem. Phys., 2004, 85, p 420–426CrossRef
40.
B.M. Mistry and S. Jauhari, Synthesis and Evaluation of Some Quinoline Schiff Bases as a Corrosion Inhibitor for Mild Steel in 1 N HCl, Res. Chem. Intermed., 2013, 39, p 1049–1068CrossRef
41.
I. Ahamad, R. Prasad, and M.A. Quraishi, Inhibition of Mild Steel Corrosion in Acid Solution by Pheniramine Drug: Experimental and Theoretical Study, Corros. Sci., 2010, 52, p 3033–3041CrossRef
42.
I. Ahamad, R. Prasad, and M.A. Quraishi, Experimental and Quantum Chemical Characterization of the Adsorption of Some Schiff Base Compounds of Phthaloyl Thiocarbohydrazide on the Mild Steel in Acid Solutions, Mater. Chem. Phys., 2010, 124, p 1155–1165CrossRef
43.
E. McCafferty, Introduction to Corrosion Science, Springer, New York, 2010CrossRef
44.
E. McCafferty and N. Hackerman, Double Layer Capacitance of Iron and Corrosion Inhibition with Polymethylene Diamines, J. Electrochem. Soc., 1972, 119, p 146–154CrossRef
45.
A.K. Singh and M.A. Quraishi, Effect of Cefazolin on the Corrosion of Mild Steel in HCl Solution, Corros. Sci., 2010, 52, p 152–160CrossRef
46.
A. Kosari, M. Momeni, R. Parvizi, M. Zakeri, M.H. Moayed, A. Davoodi, and H. Eshghi, Theoretical and Electrochemical Assessment of Inhibitive Behavior of Some Thiophenol Derivatives on Mild Steel in HCl, Corros. Sci., 2011, 53, p 3058–3067CrossRef
47.
E.E. Oguzie, Y. Li, and F.H. Wang, Effect of 2-Amino-3-mercaptopropanoic Acid (Cysteine) on the Corrosion Behaviour of Low Carbon Steel in Sulphuric Acid, Electrochim. Acta., 2007, 53, p 909–914CrossRef
48.
N.A. Negm, F.M. Ghuiba, and S.M. Tawfik, Novel Isoxazolium Cationic Schiff Base Compounds as Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid, Corros. Sci., 2011, 53, p 3566–3575CrossRef
49.
F. Bentiss, M. Traisnel, and M. Lagrenee, The Substituted 1,3,4-Oxadiazoles: A New Class of Corrosion Inhibitors of Mild Steel in Acidic Media, Corros. Sci., 2000, 42, p 127–146CrossRef
50.
E.S. Ferreira, C. Giancomelli, F.C. Giacomelli, and A. Spinelli, Evaluation of the Inhibitor Effect of l-Ascorbic Acid on the Corrosion of Mild Steel, Mater. Chem. Phys., 2004, 83, p 129–134CrossRef
51.
F. Zhang, Y. Tang, Z. Cao, W. Jing, Z. Wu, and Y. Chen, Performance and Theoretical Study on Corrosion Inhibition of 2-(4-Pyridyl)-benzimidazole for Mild Steel in Hydrochloric Acid, Corros. Sci., 2012, 61, p 1–9CrossRef
52.
P. Zhao, Q. Liang, and Y. Li, Electrochemical, SEM/EDS and Quantum Chemical Study of Phthalocyanines as Corrosion Inhibitors for Mild Steel in 1 mol/L HCl, Appl. Surf. Sci., 2005, 252, p 1596–1607CrossRef
53.
I. Ahamad, R. Prasad, and M.A. Quraishi, Thermodynamic, Electrochemical and Quantum Chemical Investigation of Some Schiff Bases as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solutions, Corros. Sci., 2010, 52, p 933–942CrossRef
54.
G. Gao and C. Liang, Electrochemical and DFT Studies of β-Amino-Alcohols as Corrosion Inhibitors for Brass, Electrochim. Acta., 2007, 52, p 4554–4559CrossRef
55.
S.K. Rajak, N. Islam, and D.C. Ghosh, Modeling of the Chemico-physical Process of Protonation of Molecules Entailing Some Quantum Chemical Descriptors, J. Quantum Inf. Sci., 2011, 1, p 87–95CrossRef
56.
E.E. Ebenso, D.A. Isabirye, and N.O. Eddy, Adsorption and Quantum Chemical Studies on the Inhibition Potentials of Some Thiosemicarbazides for the Corrosion of Mild Steel in Acidic Medium, Int. J. Mol. Sci., 2010, 11, p 2473–2498CrossRef
57.
K. Aramaki and N. Hackerman, Inhibition Mechanism of Medium-Sized Polymethyleneimine, J. Electrochem. Soc., 1969, 116, p 568–574CrossRef
58.
M.K. Pavithr, T.V. Venkatesh, K. Vathsal, and K.O. Nayan, Synergistic Effect of Halide Ions on Improving Corrosion Inhibition Behaviour of Benzisothiozole-3-piperizine Hydrochloride on Mild Steel in 0.5 M H2SO4 Medium, Corros. Sci., 2010, 52, p 3811–3819CrossRef
59.
J.M. Cases and F. Villieras, Thermodynamic Model of Ionic and Nonionic Surfactants Adsorption-Abstraction on Heterogeneous Surfaces, Langmuir, 1992, 8, p 1251–1264CrossRef
60.
G. Moretti, G. Quartarone, A. Tassan, and A. Zingales, 5-Amino- and 5-Chloro-indole as Mild Steel Corrosion Inhibitors in 1 N Sulphuric Acid, Electrochim. Acta., 1996, 41, p 1971–1980CrossRef
61.
F. Bentiss, M. Traisnel, and M. Lagrenee, Influence of 2,5-Bis(4-dimethylaminophenyl)-1,3,4-thiadiazole on Corrosion Inhibition of Mild Steel in Acidic Media, J. Appl. Electrochem., 2001, 31, p 41–48CrossRef
62.
M.A. Quraishi, I. Ahamed, and R. Prasad, Adsorption and Inhibitive Properties of Some New Mannich Bases of Isatin Derivatives on Corrosion of Mild Steel in Acidic Media, Corros. Sci., 2010, 52, p 1472–1481CrossRef
63.
K. Parameswari, S. Rekha, S. Chitra, and E. Kayalvizhy, Study on the Inhibition of Mild Steel Corrosion by Benzoisoxazole and Benzopyrazole Derivatives in H2SO4 Medium, Port. Electrochim. Acta., 2010, 28, p 189–201CrossRef
64.
N.M. Guan, L. Xueming, and L. Fei, Synergistic Inhibition Between o-Phenanthroline and Chloride Ion on Cold Rolled Steel Corrosion in Phosphoric Acid, Mater. Chem. Phys., 2004, 86, p 59–68CrossRef
65.
A.J.A. Nasser and M.A. Sathiq, Comparative study of N-[(4-Methoxyphenyl) (morpholin-4-yl)methyl]acetamide (MMPA) and N-[Morpholin-4-yl(phenyl)methyl]acetamide (MPA) as Corrosion Inhibitors for Mild Steel in Sulfuric Acid Solution, Arab. J. Chem., Doi:10.​1016/​j.​arabjc.​2012.​07.​032
66.
S.A.M. Refaey, F. Taha, and A.M. Abd El-Malak, Inhibition of Stainless Steel Pitting Corrosion in Acidic Medium by 2-Mercaptobenzoxazole, Appl. Surf. Sci., 2004, 236, p 175–185CrossRef
Metadaten
Titel
Interaction of Benzimidazoles and Benzotriazole: Its Corrosion Protection Properties on Mild Steel in Hydrochloric Acid
verfasst von
K. Ramya
Revathi Mohan
Abraham Joseph
Publikationsdatum
01.11.2014
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 11/2014
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-014-1183-5

Weitere Artikel der Ausgabe 11/2014

Journal of Materials Engineering and Performance 11/2014 Zur Ausgabe

OriginalPaper

The Synthesis and Electrochemical Behavior of High-Nitrogen Nickel-Free Austenitic Stainless Steel

OriginalPaper

Mechanical Characterization of Copper-Copper Wires Joined by Friction Welding Using Instrumented Indentation Technique

OriginalPaper

Influence of Electropolishing and Magnetoelectropolishing on Corrosion and Biocompatibility of Titanium Implants

OriginalPaper

Effect of Partial Replacement of Si with Al on the Microstructures and Mechanical Properties of 1000 MPa TRIP Steels

OriginalPaper

Dissimilar Arc Welding of Advanced High-Strength Car-Body Steel Sheets

OriginalPaper

Mechanical Properties of Steel Surfaces Coated with HfN/VN Superlattices

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise