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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 11-12/2019

23.10.2019 | Original Contribution

Interaction of ninhydrin with zinc(II) complex of tryptophan in the three dicationic gemini surfactants

verfasst von: Malik Abdul Rub, Dileep Kumar

Erschienen in: Colloid and Polymer Science | Ausgabe 11-12/2019

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Abstract

Present work concerns with the interaction of ninhydrin with zinc(II) complex of tryptophan ([Zn(II)-Trp]+) in the three dicationic gemini surfactant systems. To record critical micellar concentration (CMC) and absorbance, we have used Systronics conductivity meter and UV-visible spectrophotometer, respectively. Experiment opens up the fractional- and first-order paths in ninhydrin and complex, respectively. Gemini micellar medium is found more superior over aqueous medium. Rate constant (kψ) vs. [gemini] plot shows the unusual role of geminis on kψ. kψ increases with gemini concentration (at concentrations lower than the CMC, part I) and leveling-off regions obtain (concentration up to 400 × 10−5 mol dm−3, part II). Characteristics of part I and part II are just the same as that of conventional surfactant. Later, gemini produces a third region of increasing kψ at higher concentrations ([gemini] > 400 × 10−5 mol dm−3, part III). Detail and systematic elucidation about the effect of surfactants are mentioned and discussed in the text. Binding constants (KS for [Zn(II)-Trp]+ and KN for ninhydrin) and rate constant (km in geminis) were determined by nonlinear least squares regression technique. The kinetic results acquired can reasonably be interpreted by pseudo-phase model of surfactant micelles.
Vorheriger Artikel Tunable viscosity modification with diluted particles: when particles decrease the viscosity of complex fluids
Nächster Artikel Functionalized graphene nanoplatelets/modified polybutadiene hybrid composite

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Metadaten
Titel
Interaction of ninhydrin with zinc(II) complex of tryptophan in the three dicationic gemini surfactants
verfasst von
Malik Abdul Rub
Dileep Kumar
Publikationsdatum
23.10.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 11-12/2019
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-019-04569-4

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