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Erschienen in: Metallurgist 11-12/2016

28.03.2016

Intermetallic Compound Formation During Reaction of Molten Aluminum with Titanium

verfasst von: L. M. Gurevich, V. G. Shmorgun

Erschienen in: Metallurgist | Ausgabe 11-12/2016

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Abstract

A multistage process is described as the basis for metallographic studies of intermetallic formation during reaction of molten aluminum with titanium. A mechanism is proposed explaining the complex nature of the change in aluminide formation rate, including aluminide inclusion formation by breakdown. Stages are separated for reaction of titanium with molten aluminum: latent period; continuous intermetallic layer formation at a titanium-aluminum boundary; titanium dissolution in aluminum; band formation and growth within a melt with intermetallic fragments; increase in aluminide content in crystallizing melt. x-Ray structural and energy-dispersion analysis methods are used to demonstrate formation of just a single intermetallic TiAl3, which confirms thermodynamic calculations performed by Kattner.

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Literatur
1.
Zurück zum Zitat Yu. P. Trykov, L. M. Gurevich, and V. G. Shmorgun, Layered Composites Based on Aluminum and Its Alloys, Metallurgizdat, Moscow (2004). Yu. P. Trykov, L. M. Gurevich, and V. G. Shmorgun, Layered Composites Based on Aluminum and Its Alloys, Metallurgizdat, Moscow (2004).
2.
Zurück zum Zitat K. S. Vecchio, “Synthetic multifunctional metallic-intermetallic laminate composites,” JОМ, 57, No. 3, 25–32 (2005). K. S. Vecchio, “Synthetic multifunctional metallic-intermetallic laminate composites,” JОМ, 57, No. 3, 25–32 (2005).
3.
Zurück zum Zitat X. Cui et al., “Fabrication of fully dense TiAl-based composite sheets with a novel microlaminated microstructure,” Scr. Mater., 66, No. 5, 276–279 (2012). X. Cui et al., “Fabrication of fully dense TiAl-based composite sheets with a novel microlaminated microstructure,” Scr. Mater., 66, No. 5, 276–279 (2012).
4.
Zurück zum Zitat Yu. P. Trykov, V. G. Shmorgun, and L. M. Gurevich, “Creation of layered intermetallic composites for various purposes with improved heat-resistance properties,” Nauka – Proizv., No. 1, 25–29 (2005). Yu. P. Trykov, V. G. Shmorgun, and L. M. Gurevich, “Creation of layered intermetallic composites for various purposes with improved heat-resistance properties,” Nauka – Proizv., No. 1, 25–29 (2005).
5.
Zurück zum Zitat L. A. Fridlyand, T. N. Zinov’eva, and Yu. K. Kononov, “Welding aluminum with titanium,” Svar. Proizv., No. 1, 5–8 (1963). L. A. Fridlyand, T. N. Zinov’eva, and Yu. K. Kononov, “Welding aluminum with titanium,” Svar. Proizv., No. 1, 5–8 (1963).
6.
Zurück zum Zitat Yu. P. Trykov, L. M. Gurevich, and A. N. Zhorov, “Diffusion processes in explosion welded titanium-aluminum joints,” Konstr. Komp. Mater., No. 2, 19–23 (2005). Yu. P. Trykov, L. M. Gurevich, and A. N. Zhorov, “Diffusion processes in explosion welded titanium-aluminum joints,” Konstr. Komp. Mater., No. 2, 19–23 (2005).
7.
Zurück zum Zitat M. A. Lagosa, I. Agotea, M. Gutiérreza, et al., “Synthesis of γ-TiAl by thermal explosion + compaction route: effect of process parameters and post-combustion treatment on product microstructure,” Int. J. Self-Propag. High-Temp. Synth., 19, No. 1, 23–27 (2010).CrossRef M. A. Lagosa, I. Agotea, M. Gutiérreza, et al., “Synthesis of γ-TiAl by thermal explosion + compaction route: effect of process parameters and post-combustion treatment on product microstructure,” Int. J. Self-Propag. High-Temp. Synth., 19, No. 1, 23–27 (2010).CrossRef
8.
Zurück zum Zitat M. Kh. Shorshorov, “Physical and chemical bases of methods for joining different materials,” Results of Science and Technology. Welding, VINITI, Moscow (1966). M. Kh. Shorshorov, “Physical and chemical bases of methods for joining different materials,” Results of Science and Technology. Welding, VINITI, Moscow (1966).
9.
Zurück zum Zitat L. N. Lartikov, V. R. Ryabov, and V. M. Falchenko, Diffusion Processes in the Solid Phase During Welding, Mashinostroenie, Moscow (1975). L. N. Lartikov, V. R. Ryabov, and V. M. Falchenko, Diffusion Processes in the Solid Phase During Welding, Mashinostroenie, Moscow (1975).
10.
Zurück zum Zitat Ya. E. Geguzin, Diffusion Zone, Nauka, Moscow (1979). Ya. E. Geguzin, Diffusion Zone, Nauka, Moscow (1979).
11.
Zurück zum Zitat F. J. J. Van Loo and G. D. Rieck, “Diffusion in the titanium-aluminium system – I. Interdiffusion between solid Al and Ti or Ti–Al alloys,” Acta Metallur., 21, No. 1, 61–71 (1973).CrossRef F. J. J. Van Loo and G. D. Rieck, “Diffusion in the titanium-aluminium system – I. Interdiffusion between solid Al and Ti or Ti–Al alloys,” Acta Metallur., 21, No. 1, 61–71 (1973).CrossRef
12.
Zurück zum Zitat V. R. Ryabov, Steel Calorizing, Metallurgiya, Moscow (1973). V. R. Ryabov, Steel Calorizing, Metallurgiya, Moscow (1973).
13.
Zurück zum Zitat L. M. Gurevich, Yu. P. Trykov, and D. V. Pronichev, “Thermal conductivity of titanium-aluminum layered metal-intermetallic composites,” Science Yesterday, Today, Tomorrow. Theory and Practice: Proc. Int. Electron. Symp. (2015), pp. 76–81. L. M. Gurevich, Yu. P. Trykov, and D. V. Pronichev, “Thermal conductivity of titanium-aluminum layered metal-intermetallic composites,” Science Yesterday, Today, Tomorrow. Theory and Practice: Proc. Int. Electron. Symp. (2015), pp. 76–81.
14.
Zurück zum Zitat U. R. Kattner, J. C. Lin, and Y. A. Chang, “Thermodynamic assessment and calculation of the Ti–Al system,” Metal. Mater. Trans., 23, No. 8, 2081–2090 (1992).CrossRef U. R. Kattner, J. C. Lin, and Y. A. Chang, “Thermodynamic assessment and calculation of the Ti–Al system,” Metal. Mater. Trans., 23, No. 8, 2081–2090 (1992).CrossRef
15.
Zurück zum Zitat M. Sujata, S. Bhargava, and S. Sangal, “Microstructural features of TiAl3 base сompounds formed by reaction synthesis,” Mater. Design, 32, No. 1, 207–216 (2011).CrossRef M. Sujata, S. Bhargava, and S. Sangal, “Microstructural features of TiAl3 base сompounds formed by reaction synthesis,” Mater. Design, 32, No. 1, 207–216 (2011).CrossRef
16.
Zurück zum Zitat L. M. Gurevich, Yu. P. Trykov, A. N. Zhorov, et al., “Structure formation in titanium-aluminum composites in the presence of liquid phase,” Zh. Funkts. Mater., 2, No. 4, 153–157 (2008). L. M. Gurevich, Yu. P. Trykov, A. N. Zhorov, et al., “Structure formation in titanium-aluminum composites in the presence of liquid phase,” Zh. Funkts. Mater., 2, No. 4, 153–157 (2008).
17.
Zurück zum Zitat P. A. Rebinder and E. D. Shchukin, “Surface phenomena in solids during deformation and failure,” UFN, 108, No. 1, 3–42 (1972). P. A. Rebinder and E. D. Shchukin, “Surface phenomena in solids during deformation and failure,” UFN, 108, No. 1, 3–42 (1972).
Metadaten
Titel
Intermetallic Compound Formation During Reaction of Molten Aluminum with Titanium
verfasst von
L. M. Gurevich
V. G. Shmorgun
Publikationsdatum
28.03.2016
Verlag
Springer US
Erschienen in
Metallurgist / Ausgabe 11-12/2016
Print ISSN: 0026-0894
Elektronische ISSN: 1573-8892
DOI
https://doi.org/10.1007/s11015-016-0241-7

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