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Erschienen in:

2017 | OriginalPaper | Buchkapitel

1. Introduction

verfasst von : Guangmin Zhou

Erschienen in: Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries

Verlag: Springer Singapore

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Abstract

Despite the great promise of Li–S batteries, many challenges need to be addressed before they can find practical applications. For example, the low electrical conductivities of sulfur, polysulfide products and the final Li₂S product affect the utilization of the active sulfur material and the rate capability of the battery. The highly soluble polysulfides in the electrolyte, which can shuttle between the anode and cathode and form a deposit of solid Li₂S₂/Li₂S on the cathode and anode, cause an irreversible loss of sulfur, which leads to low Coulombic efficiency, low cyclic capacity and an increase in impedance. A volume change (80%) between sulfur and Li₂S during charge/discharge induces stress in the electrode and destroys its structural stability, which leads to rapid capacity decay. In this book, firstly I will introduce the background of rechargeable Li–S batteries, then I will demonstrate three strategies to improve the performance of Li–S batteries from physical confinement, chemical binding and battery configuration design. Finally, conclusions and perspective were included.

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Titel: Introduction
verfasst von: Guangmin Zhou
Verlag: Springer Singapore
Buch: Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries
Print ISBN: 978-981-10-3405-3

Electronic ISBN: 978-981-10-3406-0

Copyright-Jahr: 2017
DOI: https://doi.org/10.1007/978-981-10-3406-0_1