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Erschienen in: Colloid and Polymer Science 9/2014

01.09.2014 | Original Contribution

Investigation of removal of Pb(II) and Hg(II) by a novel cross-linked chitosan-poly(aspartic acid) chelating resin containing disulfide bond

verfasst von: Xing Juan Chen, Jian Chong Cai, Zheng Han Zhang, Li Jia Liu, Guang Lei Yang

Erschienen in: Colloid and Polymer Science | Ausgabe 9/2014

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Abstract

A novel cross-linked chitosan-poly(aspartic acid) chelating resin was synthesized by combining chitosan and poly(aspartic acid) derivative with crosslinker. The structure and morphology of the resin containing disulfide bonds were characterized by 1H NMR, FT-IR, Raman spectra, and SEM. Adsorption of Pb(II) and Hg(II) from aqueous solution by the resulted chelating resin was investigated in batch techniques. The result of the Raman spectra suggests that the disulfide bonds in the resin also play an important role in the adsorption of Pb(II) and Hg(II). The kinetic data were fitted to pseudo-first-order, pseudo-second-order, and intraparticle diffusion models, which is suggestive of following closely the pseudo-second-order kinetic model. Equilibrium data were fitted to Langmuir, Freundlich, and D–R isotherm models. The results of equilibrium isotherm reveal that the empirical Langmuir equation provides an accurate description of the experimental data under the studied concentration range. In addition, thermodynamic and regeneration properties of the adsorbent were also studied.

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Metadaten
Titel
Investigation of removal of Pb(II) and Hg(II) by a novel cross-linked chitosan-poly(aspartic acid) chelating resin containing disulfide bond
verfasst von
Xing Juan Chen
Jian Chong Cai
Zheng Han Zhang
Li Jia Liu
Guang Lei Yang
Publikationsdatum
01.09.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 9/2014
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3240-x

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