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Erschienen in:
Molecular Motion and Dynamic Crystal Structures of Hybrid Halide Perovskites Kapitel lesen Erstes Kapitel lesen

2016 | OriginalPaper | Buchkapitel

Ionic Conductivity of Organic–Inorganic Perovskites: Relevance for Long-Time and Low Frequency Behavior

verfasst von : Giuliano Gregori, Tae-Youl Yang, Alessandro Senocrate, Michael Grätzel, Joachim Maier

Erschienen in: Organic-Inorganic Halide Perovskite Photovoltaics

Verlag: Springer International Publishing

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Abstract

This chapter is focused on the relevance of the ionic transport in hybrid organic–inorganic perovskites. The occurrence of significant ionic conductivity along with electronic conductivity leads to stoichiometric polarization on current flow. Such a polarization yields a large apparent dielectric constant at low frequencies and a pronounced hysteresis behavior in i-V sweep experiments. We describe electrochemical background, precise measurements, and the impact of these phenomena for the photo-perovskites.

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Vorheriges Kapitel Defect Physics of CH3NH3PbX3 (X = I, Br, Cl) Perovskites
Nächstes Kapitel Ion Migration in Hybrid Perovskite Solar Cells
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Metadaten
Titel
Ionic Conductivity of Organic–Inorganic Perovskites: Relevance for Long-Time and Low Frequency Behavior
verfasst von
Giuliano Gregori
Tae-Youl Yang
Alessandro Senocrate
Michael Grätzel
Joachim Maier
Copyright-Jahr
2016
Buch
Organic-Inorganic Halide Perovskite Photovoltaics

Print ISBN: 978-3-319-35112-4

Electronic ISBN: 978-3-319-35114-8

Copyright-Jahr: 2016

DOI
https://doi.org/10.1007/978-3-319-35114-8_5