Skip to main content
Erschienen in: Journal of Polymer Research 7/2019

01.07.2019 | ORIGINAL PAPER

Iron-containing magnetic nanocomposites based on polyphenoxazine

verfasst von: Sveta Zhiraslanovna Ozkan, Galina Petrovna Karpacheva, Ella Leont’evna Dzidziguri, Mikhail Nikolaevich Efimov, Galina Nikolaevna Bondarenko, Georgii Aleksandrovich Shandryuk, Petr Aleksandrovich Chernavskii, Galina Viktorovna Pankina

Erschienen in: Journal of Polymer Research | Ausgabe 7/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Hybrid iron-containing nanocomposite materials based on polyphenoxazine (PPOA) were synthesized for the first time via chemical transformations of PPOA in the presence of iron(III) salt (FeCl3·6H2O, Fe(NO3)3·6H2O or Fe(CH3COCH=C(CH3)O)3) in an inert atmosphere under IR radiation in the temperature range of 350–600 °С. The developed hybrid nanocomposites were characterized by means of FTIR spectroscopy, X-ray diffraction (XRD), transmission (TEM) and scanning (SEM) electron microscopy, X-Ray fluorescence spectroscopy (XRF), Inductively coupled plasma atomic emission spectroscopy (ICP-AES), atomic absorption spectrometry (AAS), elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and magnetometry. The dependence of phase composition, magnetic and thermal properties of hybrid nanocomposites, as well as the size and shape of nanoparticles on synthesis temperature, Fe concentration and the nature of iron(III) salt was demonstrated.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Godovsky DY (2000) Device applications of polymer-nanocomposites. Adv Polym Sci 153:163–205CrossRef Godovsky DY (2000) Device applications of polymer-nanocomposites. Adv Polym Sci 153:163–205CrossRef
2.
Zurück zum Zitat Karpacheva GP (2016) Hybrid magnetic nanocomposites including polyconjugated polymers. Polym Sci 58:131–146 Karpacheva GP (2016) Hybrid magnetic nanocomposites including polyconjugated polymers. Polym Sci 58:131–146
3.
Zurück zum Zitat Yang С, Du J, Peng Q, Qiao R, Chen W, Xu C, Shuai Z, Gao M (2009) Polyaniline/Fe3O4 nanoparticle composite: synthesis and reaction mechanism. J Phys Chem B 113:5052–5058CrossRef Yang С, Du J, Peng Q, Qiao R, Chen W, Xu C, Shuai Z, Gao M (2009) Polyaniline/Fe3O4 nanoparticle composite: synthesis and reaction mechanism. J Phys Chem B 113:5052–5058CrossRef
4.
Zurück zum Zitat Xiao Q, Tan X, Ji L, Xue J (2007) Preparation and characterization of polyaniline/nano-Fe3O4 composites via a novel Pickering emulsion route. Synth Met 157:784–791CrossRef Xiao Q, Tan X, Ji L, Xue J (2007) Preparation and characterization of polyaniline/nano-Fe3O4 composites via a novel Pickering emulsion route. Synth Met 157:784–791CrossRef
5.
Zurück zum Zitat Araújo ACV, Oliveira RJ, Alves Jr S, Rodrigues AR, Machado FLA, Cabral FAO, Azevedo WM (2010) Synthesis, characterization and magnetic properties of polyaniline-magnetite nanocomposites. Synth Met 160:685–690CrossRef Araújo ACV, Oliveira RJ, Alves Jr S, Rodrigues AR, Machado FLA, Cabral FAO, Azevedo WM (2010) Synthesis, characterization and magnetic properties of polyaniline-magnetite nanocomposites. Synth Met 160:685–690CrossRef
6.
Zurück zum Zitat Qiu G, Wang Q, Nie M (2006) Polyaniline/Fe3O4 magnetic nanocomposite prepared by ultrasonic irradiation. J Appl Polym Sci 102:2107–2111CrossRef Qiu G, Wang Q, Nie M (2006) Polyaniline/Fe3O4 magnetic nanocomposite prepared by ultrasonic irradiation. J Appl Polym Sci 102:2107–2111CrossRef
7.
Zurück zum Zitat Khan A, Aldwayan AS, Alhoshan M, Alsalhi M (2010) Synthesis by in situ chemical oxidative polymerization and characterization of polyaniline/iron oxide nanoparticle composite. Polym Int 59:1690–1694CrossRef Khan A, Aldwayan AS, Alhoshan M, Alsalhi M (2010) Synthesis by in situ chemical oxidative polymerization and characterization of polyaniline/iron oxide nanoparticle composite. Polym Int 59:1690–1694CrossRef
8.
Zurück zum Zitat Umare SS, Shambharkar BH (2013) Synthesis, characterization, and corrosion inhibition study of polyaniline-α-Fe2O3 nanocomposite. J Appl Polym Sci 127:3349–3355CrossRef Umare SS, Shambharkar BH (2013) Synthesis, characterization, and corrosion inhibition study of polyaniline-α-Fe2O3 nanocomposite. J Appl Polym Sci 127:3349–3355CrossRef
9.
Zurück zum Zitat Mallikarjuna NN, Manohar SK, Kulkarni PV, Venkataraman A, Aminabhavi TM (2005) Novel high dielectric constant nanocomposites of polyaniline dispersed with γ-Fe2O3 nanoparticles. J Appl Polym Sci 97:1868–1874CrossRef Mallikarjuna NN, Manohar SK, Kulkarni PV, Venkataraman A, Aminabhavi TM (2005) Novel high dielectric constant nanocomposites of polyaniline dispersed with γ-Fe2O3 nanoparticles. J Appl Polym Sci 97:1868–1874CrossRef
10.
Zurück zum Zitat Bhaumik M, Leswifi TY, Maity A, Shrinivasu VV, Onyango MS (2011) Removal of fluoride from aqueous solution by polypyrrole/Fe3O4 magnetic nanocomposite. J Hasardous Mater 186:150–159CrossRef Bhaumik M, Leswifi TY, Maity A, Shrinivasu VV, Onyango MS (2011) Removal of fluoride from aqueous solution by polypyrrole/Fe3O4 magnetic nanocomposite. J Hasardous Mater 186:150–159CrossRef
11.
Zurück zum Zitat Jokar M, Foroutani R, Safaralizadeh MH, Farhadi K (2014) Synthesis and characterization of polyaniline/Fe3O4 magnetic nanocomposite as practical approach for fluoride removal process. Ann Res Rev Biol 4:3262–3273CrossRef Jokar M, Foroutani R, Safaralizadeh MH, Farhadi K (2014) Synthesis and characterization of polyaniline/Fe3O4 magnetic nanocomposite as practical approach for fluoride removal process. Ann Res Rev Biol 4:3262–3273CrossRef
12.
Zurück zum Zitat Shambharkar BH, Umare SS (2010) Production and characterization of polyaniline/Co3O4 nanocomposite as a cathode of Zn–polyaniline battery. Mater Sci Eng B 175:120–128CrossRef Shambharkar BH, Umare SS (2010) Production and characterization of polyaniline/Co3O4 nanocomposite as a cathode of Zn–polyaniline battery. Mater Sci Eng B 175:120–128CrossRef
13.
Zurück zum Zitat Sen T, Shimpi NG, Mishra S, Sharma R (2014) Polyaniline/γ-Fe2O3 nanocomposite for room temperature LPG sensing. Sensors Actuators B 190:120–126CrossRef Sen T, Shimpi NG, Mishra S, Sharma R (2014) Polyaniline/γ-Fe2O3 nanocomposite for room temperature LPG sensing. Sensors Actuators B 190:120–126CrossRef
14.
Zurück zum Zitat Rezvani M, Asgharinezhad AA, Ebrahimzadeh H, Shekari N (2014) A polyaniline-magnetite nanocomposite as an anion exchange sorbent for solid-phase extraction of chromium (VI) ions. Microchim Acta 181:1887–1895CrossRef Rezvani M, Asgharinezhad AA, Ebrahimzadeh H, Shekari N (2014) A polyaniline-magnetite nanocomposite as an anion exchange sorbent for solid-phase extraction of chromium (VI) ions. Microchim Acta 181:1887–1895CrossRef
15.
Zurück zum Zitat Chen A, Wang H, Zhao B, Wang J, Li X (2004) Preparation and characterization of Fe3O4/polypyrrole(PPy) composites. Acta Mater Compos Sin 21:157–160 Chen A, Wang H, Zhao B, Wang J, Li X (2004) Preparation and characterization of Fe3O4/polypyrrole(PPy) composites. Acta Mater Compos Sin 21:157–160
16.
Zurück zum Zitat Jacobo SE, Aphesteguy JC, Lopez Anton R, Schegoleva NN, Kurlyandskaya GV (2007) Influence of the preparation procedure on the properties of polyaniline based magnetic composites. Eur Polym J 43:1333–1346CrossRef Jacobo SE, Aphesteguy JC, Lopez Anton R, Schegoleva NN, Kurlyandskaya GV (2007) Influence of the preparation procedure on the properties of polyaniline based magnetic composites. Eur Polym J 43:1333–1346CrossRef
17.
Zurück zum Zitat Aphesteguy JC, Jacobo SE (2007) Synthesis of a soluble polyaniline–ferrite composite: magnetic and electric properties. J Mater Sci 42:7062–7068CrossRef Aphesteguy JC, Jacobo SE (2007) Synthesis of a soluble polyaniline–ferrite composite: magnetic and electric properties. J Mater Sci 42:7062–7068CrossRef
19.
Zurück zum Zitat Karpacheva GP, Ozkan SZh (2011) RU Patent for the invention of "Dispersed nanocomposite magnetic material and method of its obtaining". № 2426188 Karpacheva GP, Ozkan SZh (2011) RU Patent for the invention of "Dispersed nanocomposite magnetic material and method of its obtaining". № 2426188
20.
Zurück zum Zitat Eremeev IS, Ozkan SZ, Karpacheva GP, Bondarenko GN (2014) Hybrid dispersed magnetic nanomaterial based on polydiphenylamine-2-carbonic acid and Fe3O4. Nanotechnologies in Russia 9:38–44CrossRef Eremeev IS, Ozkan SZ, Karpacheva GP, Bondarenko GN (2014) Hybrid dispersed magnetic nanomaterial based on polydiphenylamine-2-carbonic acid and Fe3O4. Nanotechnologies in Russia 9:38–44CrossRef
21.
Zurück zum Zitat Karpacheva GP, Ozkan SZ, Eremeev IS, Bondarenko GN, Dzidziguri EL, Chernavskii PA (2014) Synthesis of hybrid magnetic nanomaterial based on polydiphenylamine-2-carboxylic acid and Fe3O4 in the interfacial process. Eur Chem Bull 3:1001–1007 Karpacheva GP, Ozkan SZ, Eremeev IS, Bondarenko GN, Dzidziguri EL, Chernavskii PA (2014) Synthesis of hybrid magnetic nanomaterial based on polydiphenylamine-2-carboxylic acid and Fe3O4 in the interfacial process. Eur Chem Bull 3:1001–1007
22.
Zurück zum Zitat Ozkan SZ, Karpacheva GP, Dzidziguri EL, Chernavskii PA, Bondarenko GN, Pankina GV (2017) Formation features of hybrid magnetic materials based on polyphenoxazine and magnetite nanoparticles. J Res Updates Polym Sci 5:137–148CrossRef Ozkan SZ, Karpacheva GP, Dzidziguri EL, Chernavskii PA, Bondarenko GN, Pankina GV (2017) Formation features of hybrid magnetic materials based on polyphenoxazine and magnetite nanoparticles. J Res Updates Polym Sci 5:137–148CrossRef
23.
Zurück zum Zitat Ozkan SZh, Karpacheva GP (2017) RU patent for the invention of "Metal-polymer nanocomposite magnetic material based on poly-3-amine-7-methylamine-2-methylphenazine and nanoparticles Fe3O4 and method of its production". № 2637333 C2 Ozkan SZh, Karpacheva GP (2017) RU patent for the invention of "Metal-polymer nanocomposite magnetic material based on poly-3-amine-7-methylamine-2-methylphenazine and nanoparticles Fe3O4 and method of its production". № 2637333 C2
24.
Zurück zum Zitat Ozkan SZ, Karpacheva GP, Chernavskii PA, Dzidziguri EL, Bondarenko GN, Pankina GV (2018) A hybrid material based on poly-3-amine-7-methylamine-2-methylphenazine and magnetite nanoparticles. Nanotechnologies in Russia 13:122–129CrossRef Ozkan SZ, Karpacheva GP, Chernavskii PA, Dzidziguri EL, Bondarenko GN, Pankina GV (2018) A hybrid material based on poly-3-amine-7-methylamine-2-methylphenazine and magnetite nanoparticles. Nanotechnologies in Russia 13:122–129CrossRef
25.
Zurück zum Zitat Ozkan SZh, Karpacheva GP (2017) RU patent for the invention of "Nanocomposite magnetic material based on poly-3-amine-7-methylamine-2-methylphenazine and Fe3O4 nanoparticles immobilized on single-walled carbon nanotubes and method of its production". № 2635254 С2 Ozkan SZh, Karpacheva GP (2017) RU patent for the invention of "Nanocomposite magnetic material based on poly-3-amine-7-methylamine-2-methylphenazine and Fe3O4 nanoparticles immobilized on single-walled carbon nanotubes and method of its production". № 2635254 С2
26.
Zurück zum Zitat Ozkan SZ, Karpacheva GP, Chernavskii PA, Dzidziguri EL, Bondarenko GN, Pankina GV (2018) Hybrid materials based on poly-3-amine-7-methylamine-2-methylphenazine and magnetite nanoparticles immobilized on single-walled carbon nanotubes. Polymers 10:544CrossRef Ozkan SZ, Karpacheva GP, Chernavskii PA, Dzidziguri EL, Bondarenko GN, Pankina GV (2018) Hybrid materials based on poly-3-amine-7-methylamine-2-methylphenazine and magnetite nanoparticles immobilized on single-walled carbon nanotubes. Polymers 10:544CrossRef
27.
Zurück zum Zitat Aphesteguy JC, Jacobo SE (2004) Composite of polyaniline containing iron oxides. Physica B 354:224–227CrossRef Aphesteguy JC, Jacobo SE (2004) Composite of polyaniline containing iron oxides. Physica B 354:224–227CrossRef
28.
Zurück zum Zitat Wan M, Li J (1998) Synthesis and electrical–magnetic properties of polyaniline composites. J Polym Sci A Polym Chem 36:2799–2805CrossRef Wan M, Li J (1998) Synthesis and electrical–magnetic properties of polyaniline composites. J Polym Sci A Polym Chem 36:2799–2805CrossRef
29.
Zurück zum Zitat Zhang Z, Wan M (2003) Nanostructures of polyaniline composites containing nano-magnet. Synth Met 132:205–212CrossRef Zhang Z, Wan M (2003) Nanostructures of polyaniline composites containing nano-magnet. Synth Met 132:205–212CrossRef
30.
Zurück zum Zitat Karpacheva G, Ozkan S (2013) Polymer-metal hybrid structures based on polydiphenylamine and Co nanoparticles. Procedia Mater Sci 2:52–59CrossRef Karpacheva G, Ozkan S (2013) Polymer-metal hybrid structures based on polydiphenylamine and Co nanoparticles. Procedia Mater Sci 2:52–59CrossRef
31.
Zurück zum Zitat Ozkan SZ, Dzidziguri EL, Chernavskii PA, Karpacheva GP, Efimov MN, Bondarenko GN (2013) Metal-polymer nanocomposites based on polydiphenylamine and cobalt nanoparticles. Nanotechnologies in Russia 8:452–460CrossRef Ozkan SZ, Dzidziguri EL, Chernavskii PA, Karpacheva GP, Efimov MN, Bondarenko GN (2013) Metal-polymer nanocomposites based on polydiphenylamine and cobalt nanoparticles. Nanotechnologies in Russia 8:452–460CrossRef
32.
Zurück zum Zitat Ozkan SZ, Dzidziguri EL, Karpacheva GP, Chernavskii PA, Efimov MN, Bondarenko GN (2015) A magnetic metal-polymer nanocomposite material based on polydiphenylamine and Fe3O4 nanoparticles. Russ Chem Bull 64:196–201CrossRef Ozkan SZ, Dzidziguri EL, Karpacheva GP, Chernavskii PA, Efimov MN, Bondarenko GN (2015) A magnetic metal-polymer nanocomposite material based on polydiphenylamine and Fe3O4 nanoparticles. Russ Chem Bull 64:196–201CrossRef
33.
Zurück zum Zitat Karpacheva GP, Ozkan SZ, Dzidziguri EL, Chernavskii PA, Eremeev IS, Efimov MN, Ivantsov MI, Bondarenko GN (2015) Hybrid metal-polymer nanocomposites based on polyphenoxazine and cobalt nanoparticles. Eur Chem Bull 4:135–141 Karpacheva GP, Ozkan SZ, Dzidziguri EL, Chernavskii PA, Eremeev IS, Efimov MN, Ivantsov MI, Bondarenko GN (2015) Hybrid metal-polymer nanocomposites based on polyphenoxazine and cobalt nanoparticles. Eur Chem Bull 4:135–141
34.
Zurück zum Zitat Karpacheva GP, Ozkan SZh (2016) RU patent for the invention of "Polymer dispersed magnetic material and method for production thereof". № 2601005 Karpacheva GP, Ozkan SZh (2016) RU patent for the invention of "Polymer dispersed magnetic material and method for production thereof". № 2601005
35.
Zurück zum Zitat Ozkan SZ, Karpacheva GP, Dzidziguri EL, Chernavskii PA, Bondarenko GN, Efimov MN, Pankina GV (2017) One step synthesis of hybrid magnetic material based on polyphenoxazine and bimetallic Co-Fe nanoparticles. Polym Bull 74:3043–3060CrossRef Ozkan SZ, Karpacheva GP, Dzidziguri EL, Chernavskii PA, Bondarenko GN, Efimov MN, Pankina GV (2017) One step synthesis of hybrid magnetic material based on polyphenoxazine and bimetallic Co-Fe nanoparticles. Polym Bull 74:3043–3060CrossRef
36.
Zurück zum Zitat Gubin SP, Koksharov YA, Khomutov GB, Yurkov GY (2005) Magnetic nanoparticles: preparation, structure and properties. Russ Chem Rev 74:489–520CrossRef Gubin SP, Koksharov YA, Khomutov GB, Yurkov GY (2005) Magnetic nanoparticles: preparation, structure and properties. Russ Chem Rev 74:489–520CrossRef
37.
Zurück zum Zitat Chernavskii PA, Pankina GV, Lunin VV (2011) Magnetometric methods of investigation of supported catalysts. Russ Chem Rev 80:579–604CrossRef Chernavskii PA, Pankina GV, Lunin VV (2011) Magnetometric methods of investigation of supported catalysts. Russ Chem Rev 80:579–604CrossRef
38.
Zurück zum Zitat Ozkan SZ, Karpacheva GP, Bondarenko GN (2011) Polymers of phenoxazine: synthesis, structure. Russ Chem Bull 60:1651–1656CrossRef Ozkan SZ, Karpacheva GP, Bondarenko GN (2011) Polymers of phenoxazine: synthesis, structure. Russ Chem Bull 60:1651–1656CrossRef
39.
Zurück zum Zitat Zemtsov LM, Karpacheva GP, Efimov MN, Muratov DG, Bagdasarova KA (2006) Carbon nanostructures based on IR-pyrolyzed polyacrylonitrile. Polym Sci A 48:633–637CrossRef Zemtsov LM, Karpacheva GP, Efimov MN, Muratov DG, Bagdasarova KA (2006) Carbon nanostructures based on IR-pyrolyzed polyacrylonitrile. Polym Sci A 48:633–637CrossRef
40.
Zurück zum Zitat Dzidziguri EL (2009) Dimensional characteristics of nanopowders. Nanotechnologies in Russia 4:857–870CrossRef Dzidziguri EL (2009) Dimensional characteristics of nanopowders. Nanotechnologies in Russia 4:857–870CrossRef
41.
Zurück zum Zitat Soloveva AY, Ioni YV, Gubin SP (2016) Synthesis of Fe3O4 nanoparticles on the surface of graphene. Mendeleev Comm 26:38–39CrossRef Soloveva AY, Ioni YV, Gubin SP (2016) Synthesis of Fe3O4 nanoparticles on the surface of graphene. Mendeleev Comm 26:38–39CrossRef
42.
Zurück zum Zitat Cornell RM, Schwertmann U (1996) The iron oxides: structure, properties, reactions, occurrences and uses. (VCH, New York) Cornell RM, Schwertmann U (1996) The iron oxides: structure, properties, reactions, occurrences and uses. (VCH, New York)
43.
Zurück zum Zitat Gubin SP (2000) What is nanoparticle? Development trends for nanochemistry and nanotechnology. Ross Khim Zh 44:23–31 Gubin SP (2000) What is nanoparticle? Development trends for nanochemistry and nanotechnology. Ross Khim Zh 44:23–31
Metadaten
Titel
Iron-containing magnetic nanocomposites based on polyphenoxazine
verfasst von
Sveta Zhiraslanovna Ozkan
Galina Petrovna Karpacheva
Ella Leont’evna Dzidziguri
Mikhail Nikolaevich Efimov
Galina Nikolaevna Bondarenko
Georgii Aleksandrovich Shandryuk
Petr Aleksandrovich Chernavskii
Galina Viktorovna Pankina
Publikationsdatum
01.07.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 7/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1843-0

Weitere Artikel der Ausgabe 7/2019

Journal of Polymer Research 7/2019 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.