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Erschienen in: Adsorption 4-6/2016

25.11.2015

Kinetics of protein adsorption by nanoporous carbons with different pore size

verfasst von: Alexander M. Puziy, Olga I. Poddubnaya, Anna Derylo-Marczewska, Adam W. Marczewski, Magdalena Blachnio, Mykola M. Tsyba, Vitaliy I. Sapsay, Dmytro O. Klymchuk

Erschienen in: Adsorption | Ausgabe 4-6/2016

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Abstract

Kinetics of bovine serum albumin and ovalbumin adsorption by nanoporous carbons with different main pore sizes (1.6, 5, 7.8 and 28 nm) was studied. Experimental kinetics curves were well described by multi-exponential equation with different number of exponents (from 1 to 4). Protein adsorption kinetics showed significant dependence on pore size of carbonaceous adsorbent. Correlation between pore size distribution and amount of protein adsorbed revealed threshold pore size 7.3 nm for BSA and 6.8 nm for OVA, which are close to hydrodynamic diameter of protein molecules. The fastest and the highest adsorption of proteins were observed in carbons having developed porosity with pore sizes larger than 15 nm.

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Metadaten
Titel
Kinetics of protein adsorption by nanoporous carbons with different pore size
verfasst von
Alexander M. Puziy
Olga I. Poddubnaya
Anna Derylo-Marczewska
Adam W. Marczewski
Magdalena Blachnio
Mykola M. Tsyba
Vitaliy I. Sapsay
Dmytro O. Klymchuk
Publikationsdatum
25.11.2015
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 4-6/2016
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-015-9723-3

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