nach oben

Erschienen in:

2020 | OriginalPaper | Buchkapitel

Lanthanum Hydroxide Nanoparticles/Multi-Wall Carbon Nanotubes Nanocomposites

verfasst von : Arvind K. Bhakta, Sunita Kumari, Sahid Hussain, Ronald J. Mascarenhas, Praveen Martis, Joseph Delhalle, Zineb Mekhalif

Erschienen in: Advanced Materials for Defense

Verlag: Springer International Publishing

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A simple and effective approach using infrared (IR) irradiation and diazonium chemistry has been applied to decorate multi-wall carbon nanotubes (MWCNTs) with lanthanum hydroxide nanoparticles (LaH NPs). The decoration process comprised four steps: purification, functionalization, impregnation and calcination. The resulting materials were characterized with XPS, TEM, PXRD, EDX and Raman spectroscopy. Sodium hydroxide treatment led to the purification of MWCNTs (p-MWCNTs). Functionalizing purified MWCNTs with in situ generated tricarboxylic aryl diazonium salts (p-MWCNTs-D3) followed by impregnation using IR irradiation was the key step in efficiently impregnating p-MWCNTs-D3 with lanthanum nitrate (p-MWCNTs-D3/LaN). Calcination of p-MWCNTs-D3/LaN at 500 °C under argon atmosphere resulted in homogeneously distributed LaH NPs on MWCNTs (p-MWCNTs/LaH) in the size range of 1.5–6.0 nm, with a Gaussian mean diameter of 3.0 nm. LaH nanoparticles were found to be amorphous. This method is applicable to large-scale production, which opens interesting outlooks for nanotechnology applications such as energy storage material and sensor for detection of chemical warfare agents in the defense sector.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Molecularly Imprinted Polymers and Optical Fiber Sensors for Security Applications

Nächstes Kapitel Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide

Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58. https://doi.org/10.1038/354056a0CrossRef

Ajayan PM (1999) Nanotubes from carbon. Chem Rev 99:1787–1799. https://doi.org/10.1021/cr970102gCrossRef

Favero VO, Oliveira DA, Lutkenhaus JL, Siqueira JR Jr (2018) Layer-by-layer nanostructured supercapacitor electrodes consisting of ZnO nanoparticles and multi- walled carbon nanotubes. J Mater Sci 53:6719–6728. https://doi.org/10.1007/s10853-018-2010-4CrossRef

Bhakta AK, Mascarenhas RJ, D’Souza OJ, Satpati AK, Detriche S, Mekhalif Z, Dalhalle J (2015) Iron nanoparticles decorated multi-wall carbon nanotubes modified carbon paste electrode as an electrochemical sensor for the simultaneous determination of uric acid in the presence of ascorbic acid, dopamine and l-tyrosine. Mater Sci Eng C 57:328–337. https://doi.org/10.1016/j.msec.2015.08.003CrossRef

Bhakta AK, Detriche S, Kumari S, Hussain S, Martis P, Mascarenhas RJ, Delhalle J, Mekhalif Z (2018) Multi-wall carbon nanotubes decorated with bismuth oxide nanocrystals using infrared irradiation and diazonium chemistry. J Inorg Organomet Polym Mater. https://doi.org/10.1007/s10904-018-0800-4CrossRef

Bhakta AK, Mascarenhas RJ, Martis P, Delhalle J, Mekhalif Z (2018) Multi-wall carbon nanotubes decorated with barium oxide nanoparticles. Synth Catal Open Access 3. https://doi.org/10.4172/2574-0431.100019

Karousis N, Tagmatarchis N, Tasis D (2010) Current progress on the chemical modification of carbon nanotubes. Chem Rev 110:5366–5397. https://doi.org/10.1021/cr100018gCrossRef

Kaynak N, Aysen O, Karahasanog M (2018) Photoactive multi-walled carbon nanotubes: synthesis and utilization of benzoin functional MWCNTs. J Mater Sci 53:9598–9610. https://doi.org/10.1007/s10853-018-2233-4CrossRef

Salavati-niasari M, Hosseinzadeh G, Davar F (2011) Synthesis of lanthanum hydroxide and lanthanum oxide nanoparticles by sonochemical method. J Alloys Compd 509:4098–4103. https://doi.org/10.1016/j.jallcom.2010.07.083CrossRef

10.

Ho K, Liu H, Ke QQ, Mao L, Hu Y, Xu L, Wang J (2017) Nickel and lanthanum hydroxide nanocomposites with much improved electrochemical performance for supercapacitors. J Am Ceram Soc 100:247–256. https://doi.org/10.1111/jace.14546CrossRef

11.

Zong E, Liu X, Wang J, Yang S, Jiang J, Fu S (2017) Facile preparation and characterization of lanthanum- loaded carboxylated multi-walled carbon nanotubes and their application for the adsorption of phosphate ions. J Mater Sci 52:7294–7310. https://doi.org/10.1007/s10853-017-0966-0CrossRef

12.

Ghiasi M, Malekzadeh A (2015) Synthesis, characterization and photocatalytic properties of lanthanum oxy-carbonate, lanthanum oxide and lanthanum hydroxide nanoparticles. Superlattices Microstruct 77:295–304. https://doi.org/10.1016/j.spmi.2014.09.027CrossRef

13.

Ziaee F, Gholizadeh M, Seyedi SM (2018) Magnetically recoverable lanthanum hydroxide as an efficient catalyst for aerobic oxidative conversions of primary alcohols to the nitriles. Appl Organometal Chem 1–8. https://doi.org/10.1002/aoc.4253CrossRef

14.

Martis P, Venugopal BR, Seffer J-F, Delhalle J, Mekhalif Z (2011) Infrared irradiation controlled decoration of multiwalled carbon nanotubes with copper/copper oxide nanocrystals. Acta Mater 59:5040–5047. https://doi.org/10.1016/j.actamat.2011.04.061CrossRef

15.

Venugopal BR, Detriche S, Delhalle J, Mekhalif Z (2012) Effect of infrared irradiation on immobilization of ZnO nanocrystals on multiwalled carbon nanotubes. J. Nanopart Res 14:1079. https://doi.org/10.1007/s11051-012-1079-yCrossRef

16.

Bhakta AK, Detriche S, Martis P, Mascarenhas RJ, Delhalle J, Mekhalif Z (2017) Decoration of tricarboxylic and monocarboxylic aryl diazonium functionalized multi-wall carbon nanotubes with iron nanoparticles. J Mater Sci 52:9648–9660. https://doi.org/10.1007/s10853-017-1100-zCrossRef

17.

Sunding MF, Hadidi K, Diplas S, Løvvik OM, Norby TE, Gunnæs AE (2011) XPS characterisation of in situ treated lanthanum oxide and hydroxide using tailored charge referencing and peak fitting procedures. J Electron Spectrosc Relat Phenomena 184:399–409. https://doi.org/10.1016/j.elspec.2011.04.002CrossRef

18.

Bosch CE, Copley MP, Eralp T, Bilbé E, Thybaut JW, Marin GB, Collier P (2017) Tailoring the physical and catalytic properties of lanthanum oxycarbonate nanoparticles. Appl Catal A Gen 536:104–112. https://doi.org/10.1016/j.apcata.2017.01.019CrossRef

19.

Lacombe S, Geantet C, Mirodatos C (1994) Oxidative coupling of methane over lanthana catalysts. J Catal 151:439–452CrossRef

20.

Chehimi MM (ed) (2012) Aryl diazonium salts: new coupling agents in polymer and surface science. Wiley-VCH Weinheim Germany. ISBN 978-3-527-32998-4

21.

Bhakta AK, Kumari S, Hussain S, Martis P, Mascarenhas RJ, Delhalle J, Mekhalif Z (2019) Synthesis and characterization of maghemite nanocrystals decorated multi-wall carbon nanotubes for methylene blue dye removal. J Mater Sci 54:200–216. https://doi.org/10.1007/s10853-018-2818-yCrossRef

22.

Kilinç E (2016) γ-Fe₂O₃ magnetic nanoparticle functionalized with carboxylated multi walled carbon nanotube: Synthesis, characterization, analytical and biomedical application. J Magn Magn Mater 401:949–955. https://doi.org/10.1016/j.jmmm.2015.11.003CrossRef

23.

Chen J, Hamon MA, Hu H, Chen Y, Rao AM, Eklund PC, Haddon RC (1998) Solution properties of single-walled carbon nanotubes. Science (80) 282:95–98. https://doi.org/10.1126/science.282.5386.95CrossRef

24.

Yan F, Liu L, Li M, Zhang M, Xiao L, Ao Y (2018) Preparation of carbon nanotube/ copper/ carbon fiber hierarchical composites by electrophoretic deposition for enhanced thermal conductivity and interfacial properties. J Mater Sci 53:8108–8119. https://doi.org/10.1007/s10853-018-2115-9CrossRef

Titel: Lanthanum Hydroxide Nanoparticles/Multi-Wall Carbon Nanotubes Nanocomposites
verfasst von: Arvind K. Bhakta
Sunita Kumari
Sahid Hussain
Ronald J. Mascarenhas
Praveen Martis
Joseph Delhalle
Zineb Mekhalif
Verlag: Springer International Publishing
Buch: Advanced Materials for Defense
Print ISBN: 978-3-030-34122-0

Electronic ISBN: 978-3-030-34123-7

Copyright-Jahr: 2020
DOI: https://doi.org/10.1007/978-3-030-34123-7_3

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht