Regular ArticleBeta Zeolite as a Catalyst for the Preparation of Alkyl Glucoside Surfactants: The Role of Crystal Size and Hydrophobicity
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Synthesis of butyl glucoside over sulphated Zr-SBA-15 and tungstophosphoric acid incorporated SBA-15 catalysts
2021, Catalysis TodayCitation Excerpt :Alkyl glucosides are non-ionic chemicals with excellent properties such as low toxicity and good biodegradability. They have attracted the interest of researchers due to their diverse applications as food emulsifiers, personal care products, cleaning agents, textile lubricants, drug carriers and antimicrobial agents [1–3]. Alkyl glucosides are termed as green surfactants since they are synthesized using renewable carbohydrates and alcohols.
Catalytic glycosylation of glucose with alkyl alcohols over sulfonated mesoporous carbons
2019, Molecular CatalysisCitation Excerpt :The first option consists in synthesizing AAG by the direct catalytic Fischer glycosylation of glucose with fatty alcohols under biphasic conditions. In this case, zeolite H-BEA (Si/Al = 25) [22], ZnFe2O4 supported on ZrO2 [23], H2SO4/SiO2 [24,25], polyvinyl bound tri- and disulfonate ethylamine chloride[26] and Aquivion PFSA [27] have been previously investigated and good to excellent yields were claimed. Cellulose, and even lignocellulosic biomass, were also successfully employed as a source of glucose in the synthesis of AAGs through glycosylation reaction [28].
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2017, Microporous and Mesoporous MaterialsCitation Excerpt :NaA zeolite membranes are ideally suited for organic dehydration because they are highly hydrophilic and their pore diameter (0.4 nm) is smaller than almost all organic molecules, except water molecules. The NaA membranes also have nonzeolite pores containing hydrophilic silanol groups [254–257]. These properties allow preferential permeation of water over organic compounds with separation factors that are often over 1000 and sometimes higher than 10,000.
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