Abstract
Interactions in solution between a hydrophobic polymer and surfactants were studied by viscometry, light scattering and conductimetry measurements. One polymer, poly(2-ethyl hexyl methacrylate) (P2EHMA), five surfactants, sodium dodecyl sulfate (SDS), hexadecyl trimethylammonium bromide (HTAB), hexadecyl pyridinium chloride (HPCl), and ethoxylated nonyl phenol containing 10 or 25 segments of ethylene oxide (NP10 or NP25), and one solvent mixture, THF/6 vol% H2O were used in this work. For the P2EHMA/surfactant mixtures in THF/6 vol% H2O, the viscosity versus surfactant concentration curves are similar in shape for all surfactants. They show a minimum at low surfactant concentration followed at higher concentration by a maximum and a plateau. An interpretation of these curve shapes is proposed. The relevance of these findings to the problem of the polymer/surfactant interactions in latexes and latex films is also discussed.
Similar content being viewed by others
References
Zhao CL, Holl Y, Pith T, Lambla M (1989) Br Polym J 21:155
Evanson KW, Urban MW (1991) J Appl Polym Sci 42:2287
Evanson KW, Thorstenson TA, Urban MW (1991) J Appl Polym Sci 42:2297
Evanson KW, Urban MW (1991) J Appl Polym Sci 42:2309
Zhao CL, Holl Y, Pith T, Lambla M (1987) Colloid Polym Sci 265:823
Zhao CL, Dobler F, Pith T, Holl Y, Lambla M (1989) J Coll Interf Sci 128:437
Kientz E (1992) PhD dissertation. University of Strasbourg, France
Kientz E, Danicher L, Lambla M, Holl Y (1993) Polym Int 31:297
Sabz A, Noor A (1982) Br Polym J 14:113
Taber JJ (1980) Pure & Appl Chem 52:1323
Horin S, Arai H (1970) J Coll Interf Sci 32:547
Arai H, Murata M, Shinoda K (1971) J Coll Interf Sci 37:346
Saito S, Kitamura K (1971) J Coll Interf Sci 35:346
Lopez de Sa TG, Fernandez LMG, Allende Rianos JL (1988) Br Polym J 20:39
Lopez de Sa TG (1988) Br Polym J 20:457
Saito S, Yukama M (1969) J Coll Interf Sci 30:211
Magny B, Iliopoulos I, Audebert R, Piculell L, Lindman B (1991) Langmuir 7:617
Saito S (1957) Kolloid Z 154:19
Cabane B (1977) J Phys Chem 81:1639
Carlsson A, Karltron G, Lindman B (1989) J Phys Chem 93:3673
Turro NJ, Barretz BH, Kuo PL (1984) Macromol 17:1321
Cabane B, Duplessix R (1982) J Phys 43:1529
Saito S (1967) J Coll Interf Sci 24:227
Goddard ED (1986) Colloid Surf 19:255
McGlade MJ, Randall FJ, Tcheurekdjian N (1987) Macromol 20:1782
Goddard ED (1986) Colloid Surf 19:301
Zhao CL (1987) PhD dissertation. University of Strasbourg, France
Miles GD, Shedhousky L (1944) J Phys Chem 48:57
Harrold SP (1960) J Coll Sci 15:280
Hirsch E, Candau S, Zana R (1984) J Coll Interf Sci 97:318; Heckmann K, Schwartz R, Strnad J (1987) J Coll Interf Sci 120:114
Gargallo L, Radic D (1983) Polym 24:91
Anacker EW, Ghose HM (1968) J Amer Chem Soc 90:3161
Robinson RA, Stokes RH (eds) (1959) Electrolyte solutions. Butterworths, London
Muller N (1978) J Coll Interf Sci 63:383
Amorim da Costa AM, Geraldes CFC, Teixeira-Dias JJC (1982) J Coll Interf Sci 86:254
Binana-Limbele W, Zana R (1989) Colloid Polym Sci 267:254
Knoesel R, Ehrmann M, Galin JC (1993) Polym 34:1925
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kientz, E., Holl, Y. Interactions in solution between a hydrophobic polymer and various kinds of surfactants. Colloid Polym Sci 272, 141–150 (1994). https://doi.org/10.1007/BF00658840
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00658840