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Catalytic properties of bismuth vanadates based catalysts in oxidative coupling of methane and oxidative dehydrogenation of propane

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Abstract

The oxidative coupling of methane (OCM) and the oxidative dehydrogenation of propane (ODHP) have been performed on new mixed Bi-V oxides having a -γ-Bi2MoO6-like structure. The results yield a correlation between the methane conversion and the oxygen diffusivity. The introduction of metals (Fe, Cu, Sr with 10 mol%) improves the C2 selectivity. The use of an oxide with a scheelite structure (BiVO4) shows that, under catalytic conditions, this oxide has the same behaviour as the above solids.

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Authors and Affiliations

  1. Laboratoire de Catalyse Hétérogène et Homogène, UA CNRS No. 402, Université des Sciences et Techniques de Lille Flandres - Artois, 59655, Villeneuve d'Ascq Cedex, France

    A. Cherrak, R. Hubaut & Y. Barbaux

  2. Laboratoire de Cristallochimie et Physicochimie du Solide, UA CNRS No. 452, Ecole Nationale Supérieure de Chimie de Lille, BP108, 59652, Villeneuve d'Ascq Cedex, France

    G. Mairesse

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  1. A. Cherrak
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  2. R. Hubaut
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  3. Y. Barbaux
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  4. G. Mairesse
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Cherrak, A., Hubaut, R., Barbaux, Y. et al. Catalytic properties of bismuth vanadates based catalysts in oxidative coupling of methane and oxidative dehydrogenation of propane. Catal Lett 15, 377–383 (1992). https://doi.org/10.1007/BF00769161

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  • DOI: https://doi.org/10.1007/BF00769161

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