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Characterization of dispersion state of filler and polymer-filler interactions in rubber-carbon black composites

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Abstract

The physical properties of carbon black-filled rubbers are affected mainly by the distribution of filler, carbon black properties and polymer-filler interactions. A number of experimental methods and approaches for characterization of the dispersion state of filler in rubber-carbon black composites and an investigation of polymer-filler interactions are reviewed. The dispersion state characterization, electrical conductivity measurements, bound rubber evaluations, mechanical properties measurements, carbon black surface properties study, small angle X-ray scattering (SAXS) and nuclear magnetic resonance (NMR) spectroscopy are among the most important ones.

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References

  1. B. B. Boonstra andA. I. Medalia.Rubber Chem. Technol. 36 (1963) 115.

    Google Scholar 

  2. G. Kraus, Reinforcement of Elastomers (Interscience, New York, 1965).

    Google Scholar 

  3. B. B. Boonstra,Rubber Chem. Technol. 50 (1977) 194.

    Google Scholar 

  4. R. J. Cembrola,Polym. Eng. Sci. 22 (1982) 601.

    Google Scholar 

  5. W. M. Hess, R. A. Swor andE. J. Micek,Rubber Chem. Technol. 57 (1984) 959.

    Google Scholar 

  6. W. M. Hess,ibid. 64 (1991) 386.

    Google Scholar 

  7. Idem, ibid. 35 (1962) 228.

    Google Scholar 

  8. W. M. Hess andF. P. Ford,ibid. 36 (1963) 1175.

    Google Scholar 

  9. W. F. Ford, J. E. Callan andW. M. Hess,Rubber Age 92 (1963) 738.

    Google Scholar 

  10. P. C. Vegvari, W. M. Hess andV. E. Chiroco,Rubber Chem. Technol. 51 (1978) 817.

    Google Scholar 

  11. P. C. Ebell andD. A. Hemsley,ibid. 54 (1981) 698.

    Google Scholar 

  12. R. Oono,J. Appl. Polym. Sci. 21 (1977) 1743.

    Google Scholar 

  13. H. Tanaka, T. Hayashi andT. Nishi,Polym. Prepr. Jpn. 34 (1985) 777.

    Google Scholar 

  14. Idem, ibid. 34 (1985) 778.

    Google Scholar 

  15. A. C. Roulin-Moloney, in "Fractography and Failure Mechanisms of Polymers and Composites" (Elsevier, London, 1989) p. 145.

    Google Scholar 

  16. Y. Shimizu, M. Tanemura, M. Sumita, N. Miyadera andK. Miyasaka,Sen-i Gakkaishi 42 (1986) T-261.

    Google Scholar 

  17. M. Sumita, K. Sakata, Y. Hayakawa, S. Asai, K. Miyasaka andM. Tanemura,Colloid Polym. Sci. 270 (1992) 134.

    Google Scholar 

  18. M. Sumita, K. Takenaka andS. Asai,Compos. Interfac. Submitted.

  19. M. Morishita, Memoirs of the Faculty of Science Ser. E, Biology, vol. 2 (Kyushu University 1959) p. 215.

  20. R. Herzig andW. E. Baker,J. Mater. Sci. 28 (1993) 6531.

    Google Scholar 

  21. P. T. K. Shih andG. C. Goldfinger,Rubber World 199 (1989) 31.

    Google Scholar 

  22. B. B. S. T. Boonstra andE. M. Dannenberg,Ind. Eng. Chem. 46 (1954) 218.

    Google Scholar 

  23. M. H. Polley andB. B. S. T. Boonstra,Rubber Chem. Technol. 30 (1957) 170.

    Google Scholar 

  24. W. F. Verhelst, K. G. Wolthuis, A. Voet, P. Ehrburger andJ. B. Donnet,ibid. 50 (1977) 735.

    Google Scholar 

  25. A. Voet,ibid. 54 (1981) 42.

    Google Scholar 

  26. M. Amin, H. H. Hassan andE. M. Abdel-Bary,J. Polym. Sci., Polym. Chem. Ed 12 (1974) 2651.

    Google Scholar 

  27. H. H. Hassan, A. A. Ghani,A. E. Eatah andA. A. Hashem,Ang. Makromol. Chem. 115 (1982) 39.

    Google Scholar 

  28. A. A. Ghani, A. I. Eatah, A. A. Hashem andH. Hassan,ibid. 129 (1984) 1.

    Google Scholar 

  29. E. M. Cashell, J. M. D. Coey, G. E. Wardell, V. J. McBrierty andD. C. Douglass,J. Appl. Phys. 52 (1981) 1542.

    Google Scholar 

  30. R. R. Juengel,Rubber World 192 (1985) 30.

    Google Scholar 

  31. K. Miyasaka, K. Watanabe, E. Jojima, H. Aida, M. Sumita andK. Ishikawa,J. Mater. Sci. 17 (1982) 1610.

    Google Scholar 

  32. M. Amin, G. M. Nasr andM. S. Sobhy,ibid. 26 (1991) 4615.

    Google Scholar 

  33. A. I. Medalia,Rubber Chem. Technol. 59 (1986) 432.

    Google Scholar 

  34. T. M. Aminabhavi, P. E. Cassidy andC. M. Thompson,ibid. 63 (1990) 451.

    Google Scholar 

  35. L. Karásek, Unpublished work.

  36. L. C. Burton, K. Hwang andT. Zhang,Rubber Chem. Technol. 62 (1989) 838.

    Google Scholar 

  37. D. R. Parris, L. C. Burton andM. G. Siswanto ibid. 60 (1987) 705.

    Google Scholar 

  38. A. K. Sjrcar andT. G. Lamond,ibid. 51 (1978) 126.

    Google Scholar 

  39. F. Lux,J. Mater. Sci. 28 (1993) 285.

    Google Scholar 

  40. F. J. Balta-Calleja andC. G. Vonk Polymer Science Library 8, X-Ray Scattering of Synthetic Polymers (Elsevier, Amsterdam, 1989).

    Google Scholar 

  41. J. V. Dawkins, (Ed.) inDevelopments in Polymer Characterization-I (Applied Science, London, 1978) Ch. 6.

    Google Scholar 

  42. D. S. Brown, F. P. Warner andR. E. Wetton,Polymer 13 (1972) 575.

    Google Scholar 

  43. R. J. Young, D. H. A. Al-Khudhairy andA. G. Thomas,J. Mater. Sci. 21 (1986) 1211.

    Google Scholar 

  44. G. D. Wignall, N. R. Farrar andS. Morris,ibid. 25 (1990) 69.

    Google Scholar 

  45. Y. Deslandes, M. D. Whitmore, T. L. Bluhm andA. Hokansson,J. Dispersion Sci. Technol. 9 (1988) 235.

    Google Scholar 

  46. P. W. Schmidt,J. Appl. Crystallog. 24 (1991) 414.

    Google Scholar 

  47. J. E. Martin, andA. J. Hurd,ibid. 20 (1987) 61.

    Google Scholar 

  48. M. Gerspracher andC. M. Lansinger, in Proceedings of the Rubber Division of the American Ceramic Society, April 1988, (Dallas, TX, 1988) No. 7.

  49. T. W. Zerda, H. Yang andM. Gerspracher,Rubber Chem. Technol. 65 (1992) 130.

    Google Scholar 

  50. C. R. Herd, G. C. McDonald andW. M. Hess,ibid. 65 (1992) 107.

    Google Scholar 

  51. L. Salome andF. Carmona,Carbon 29 (1991) 599.

    Google Scholar 

  52. J. A. Ayala, W. M. Hess, A. O. Dotson andG. A. Joyce,Rubber Chem. Technol. 63 (1990) 747.

    Google Scholar 

  53. J. A. Ayala, W. M. Hess, F. D. Kistler andG. A. Joyce,ibid. 64 (1991) 19.

    Google Scholar 

  54. J. A. Ayala, W. M. Hess, G. A. Joyce andF. D. Kistler,ibid. 66 (1993) 772.

    Google Scholar 

  55. M. J. Wang, S. Wolff andJ. B. Donnet,ibid. 64 (1991) 714.

    Google Scholar 

  56. S. Wolff andM. J. Wang,ibid. 65 (1992) 329.

    Google Scholar 

  57. N. Nakajima, J. J. Scobbo Jr andE. R. Harrell,ibid. 60 (1987) 761.

    Google Scholar 

  58. N. Nakajima andJ. J. Scobbo Jr. ibid. 61 (1988) 137.

    Google Scholar 

  59. N. Nakajima,ibid. 1 (1988) 938.

    Google Scholar 

  60. N. Nakajima andM. H. Chu,ibid. 63 (1990) 110.

    Google Scholar 

  61. N. Nakajima, M. H. Chu andZ. G. Wang,J. Elast. Plast. 22 (1990) 174.

    Google Scholar 

  62. C. M. Blow,Polymer 14 (1973) 309.

    Google Scholar 

  63. G. Kraus,Adv. Polym. Sci. 8 (1971) 155.

    Google Scholar 

  64. E. M. Dannenberg,Rubber Chem. Technol. 59 (1986) 512.

    Google Scholar 

  65. A. M. Gessler, W. M. Hess andA. I. Medalia, in “Reinforcement of Elastomers with Carbon Black, Plastics and Rubber: Processing” (1978).

  66. C. Hepburn,Plast. & Rubber Int. 9 (1984) 11.

    Google Scholar 

  67. B. B. Boonstra,Polymer 20 (1979) 691.

    Google Scholar 

  68. G. Kraus,Rubber Chem. Technol. 51 (1978) 297.

    Google Scholar 

  69. Z. Rigbi,Adv. Polym. Sci. 36 (1981) 21.

    Google Scholar 

  70. J. B. Donnet andA. Vidal,ibid. 76 (1986) 103.

    Google Scholar 

  71. P. B. Stickney andR. D. Falb.Rubber Chem. Technol. 37 (1964) 1299.

    Google Scholar 

  72. D. S. Villars,J. Polym. Sci. 21 (1956) 257.

    Google Scholar 

  73. G. Kraus andJ. T. Gruver,Rubber Chem. Technol. 41 (1968) 1256.

    Google Scholar 

  74. I. Pliskin andN. Tokita,J. Appl. Polym. Sci. 16 (1972) 473.

    Google Scholar 

  75. B. Meissner,ibid. 18 (1974) 2483.

    Google Scholar 

  76. B. Meissner, Scientific Papers of the Prague Institute of Chemical TechnologyS1 (1978) 287.

    Google Scholar 

  77. G. R. Cotten,Rubber Chem. Technol. 48 (1975) 548.

    Google Scholar 

  78. S. Shiga,ibid. 60 (1987) 14.

    Google Scholar 

  79. G. R. Hamed andS. Hatfield,ibid. 62 (1989) 143.

    Google Scholar 

  80. J. P. Cohen-Addad,Polymer 30 (1989) 1820.

    Google Scholar 

  81. O. Girard andJ. P. Cohen-Addad,ibid. 32 (1991) 860.

    Google Scholar 

  82. J. P. Cohen-Addad,ibid. 33 (1992) 2762.

    Google Scholar 

  83. B. Meissner,J. Appl. Polym. Sci. 50 (1993) 285.

    Google Scholar 

  84. L. Karásek andB. Meissner,ibid. 52 (1994) 1925.

    Google Scholar 

  85. B. Meissner andL. Karásek, to be published.

  86. L. Karásek, thesis, Prague Institute of Chemical Technology (1994).

  87. L. L. Ban, W. M. Hess andL. A. Papazian,Rubber Chem. Technol. 47 (1974) 858.

    Google Scholar 

  88. J. L. Leblanc andP. Hardy,Kautsch. Gummi, Kunstst. 44 (1991) 1119.

    Google Scholar 

  89. S. Wolff, M. J. Wang andE. H. Tan,Rubber Chem. Technol. 66 (1993) 163.

    Google Scholar 

  90. A. Roychoudhury andP. P. De,J. Appl. Polym. Sci. 55 (1995) 9.

    Google Scholar 

  91. S. Kaufman, W. P. Slichter andD. D. Davis,J. Polym. Sci. A-2 9 (1971) 829.

    Google Scholar 

  92. T. Nishi,J. Polym. Sci., Polym. Phys. Ed 12 (1974) 685.

    Google Scholar 

  93. C. R. Dybowski andR. W. Vaughan,Macromol. 8 (1975) 50.

    Google Scholar 

  94. J. O'Brien, E. Cashell, G. E. Wardell andV. J. Mc Brierty,Rubber Chem. Technol. 50 (1977) 747.

    Google Scholar 

  95. M. Furuta, T. Hikasa andE. Kato,J. Appl. Polym. Sci. 31 (1986) 2661.

    Google Scholar 

  96. H. Serizawa, M. Ito, T. Kanamoto, K. Tanaka andA. Nomura,Polym. J. 14 (1982) 149.

    Google Scholar 

  97. G. E. Wardell, V. J. McBrierty andV. Marsland,Rubber Chem. Technol. 55 (1982) 1095.

    Google Scholar 

  98. H. Serizawa, T. Nakamura, M. Ito, K. Tanaka andA. Nomura,Polym. J. 15 (1983) 201.

    Google Scholar 

  99. Idem, ibid. 15 (1983) 543.

    Google Scholar 

  100. S. Asai, H. Kanaki, M.Sumita andK. Miyasaka,J. Appl. Polym. Sci. 43 (1991) 1253.

    Google Scholar 

  101. M. Ito, T. Nakamura andK. Tanaka,ibid. 30 (1985) 3493.

    Google Scholar 

  102. J. C. Kenny, V. J. McBrierty, Z. Rigbi andD. C. Douglass,Macromol. 24 (1991) 436.

    Google Scholar 

  103. V. J. McBrierty, J. C. Kenny, in Proceedings of The Second International Conference on Carbon Black, September 1993, (Mulhouse, 1993) p. 355.

  104. A. P. Legrand, N. Lecomte, A. Vidal, B. Haidar andE. Papirer,J. Appl. Polym. Sci. 46 (1992) 2223.

    Google Scholar 

  105. A. Y. Coran andJ. B. Donnet,Rubber Chem. Technol. 65 (1992) 973.

    Google Scholar 

  106. Idem, ibid. 65 (1992) 998.

    Google Scholar 

  107. Idem, ibid. 65 (1992) 1116.

    Google Scholar 

  108. A. R. Payne andR. E. Whittaker,ibid. 44 (1971) 440.

    Google Scholar 

  109. R. A. Hall,J. Mater. Sci. 26 (1991) 5631.

    Google Scholar 

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  1. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Ookayama 2-12-1, 152, Meguro-ku, Tokyo, Japan

    L. Karásek & M. Sumita

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  1. L. Karásek
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Karásek, L., Sumita, M. Characterization of dispersion state of filler and polymer-filler interactions in rubber-carbon black composites. J Mater Sci 31, 281–289 (1996). https://doi.org/10.1007/BF01139141

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