Abstract
The thermal behaviour of pineapple leaf fibre (PALF) reinforced polyethylene composites was studied by thermogravimetric and dynamic mechanical thermal analysis. Fibre treatment was carried out using isocyanate, silane and peroxide to improve the interfacial adhesion between fibre and matrix. The effects of fibre loading and surface modification on the thermal properties were evaluated. It was found that at high temperature PALF degrades before the polyethylene matrix. The storage modulus increased with increase of fibre loading and decreased with increase of temperature. The treated fibre composites impart better properties compared to untreated system. Tan δ showed a distinct peak at low temperature ascribed to the glass transition temperature of polyethylene but no peak was observed for PALF fibre. The relative damping increased with fibre loading. Cole-Cole analysis was made to understand the phase behaviour of the composite samples.
Similar content being viewed by others
References
K. Akita and M. J. Kase, Polym. Sci. A-1, 5 (1967) 833.
A. Basch and M. Lewin, J. Polym. Sci., Polym. Chem. Ed., 11 (1973) 3071.
A. Basch and M. Lewin, J. Polym. Sci., Polym. Chem. Ed., 11 (1973) 3097.
A. Basch and M. Lewin, J. Polym. Sci., Polym. Chem. Ed., 12 (1974) 2053.
H. Rodrig, A. Basch and M. Lewin, J. Polym. Sci., Polym. Chem. Ed., 13 (1975) 1921.
W. D. Major, Tappi, 41 (1956) 530.
M. V. Ramiah, J. Appl. Polym. Sci., 14 (1970) 1323.
B. V. Kokta and J. L. Valde, Tappi, 55 (1972) 375.
L. Kessira and A. Richard, J. Appl. Polym. Sci., 49 (1993) 1603.
V. M. Murty, S. K. De, S. S. Bhagawan, R. S. Krishna and S. K. Athithan, J. Appl. Polym. Sci., 28 (1983) 3845.
D. H. Droste and A. T. Di Benedetto, J. Appl. Polym. Sci., 13 (1969) 2149.
G. J. Howard and R. A. Shanks, J. Macromol. Sci. Phys., B19 (1981) 167.
M. V. Boluk and P. H. Schreiber, Polym. Compos., 7 (1986) 295.
J. George, K. Joseph, S. S. Bhagawan and S. Thomas, Mater. Lett., 18 (1993) 163.
J. George, N. Prabhakaran, S. S. Bhagawan and S. Thomas, J. Appl. Polym. Sci., 57 (1995) 843.
N. J. Chu, J. Appl. Polym. Sci., 14 (1970) 3129.
F. J. Kilzer and A. Broido, WSS/C1 Paper 64-4, Stanford University, 1964.
W. Guo and M. Ashida, J. Appl. Polym. Sci., 56 (1993) 1435.
L. Ibarra, M. Macias and E. Palma, J. Appl. Polym. Sci., 57 (1995) 831.
D. MaIdas, B. V. Kokta and C. Daneault, J. Appl. Polym. Sci., 37 (1989) 751.
F. D. Ozterholz, Moden Plastics Ency., 63 (10A) (1986–1987) 126.
B. N. Misra, I. K. Mehta and R. C. Khetarpal, J. Polym. Sci. Polym. Chem. Ed., 22 (1984) 230.
S. Sapieha, P. Allard and Y. H. Zang, J. Appl. Polym. Sci., 41 (1990) 2039.
J. D. Ferry, 3rd Edn., Wiley, New York, 1980.
M. L. William, R. F. Landel and J. D. Ferry, J. Am. Chem. Soc., 77 (1954) 3701.
C. Wismie, G. Maria and P. Monge, Eur. Polym. J., 21 (1985) 479.
Author information
Authors and Affiliations
Additional information
One of the authors (J. George) is thankful to Council of Scientific and Industrial Research, New Delhi, for financial support.
Rights and permissions
About this article
Cite this article
George, J., Bhagawan, S.S. & Thomas, S. Thermogravimetric and dynamic mechanical thermal analysis of pineapple fibre reinforced polyethylene composites. Journal of Thermal Analysis 47, 1121–1140 (1996). https://doi.org/10.1007/BF01979452
Issue Date:
DOI: https://doi.org/10.1007/BF01979452