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Synthesis and reactivity of metal-containing monomers

Evolution of short-range surrounding of Fe atoms during thermal transformation of [Fe3O(OOCCH=CHCOOH)6]OH·3H2O

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Thermal transformations of FeIII maleate, [Fe3O(OOCCH=CHCOOH)6]OH·3H2O (1), in an autogenerated atmosphere and the change in the short-range surrounding of Fe atoms during thermolysis were studied. The thermal transformations of1 are accompanied by the following processes: dehydration with simultaneous rearrangement of the ligand environment and formation of maleic acid, and polymerization of the rearranged monomer and its decarboxylation at high temperatures. In the initial stage of decarboxylation, the destruction of the metal-carboxylate Fe3O complex occurs followed by the formation of the Fe−Fe bond (r=0.246 nm). The oxidation of the Fe atoms is observed when the thermolysis duration increases.

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Authors and Affiliations

  1. Institute of Physics of Rostov State University, 194 prosp. Stachki, 344104, Rostov-on-Don, Russian Federation

    A. T. Shuvaev, V. G. Vlasenko, T. I. Nedoseikina & T. A. Lyubeznova

  2. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. S. Rozenberg, G. I. Dzhardimalieva, N. P. Ivleva & A. D. Pomogailo

  3. Rostov State Pedagogical University, 33 ul. B. Sadovaya, 344082, Rostov-on-Don, Russian Federation

    I. E. Uflyand

Authors
  1. A. T. Shuvaev
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  2. A. S. Rozenberg
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  3. G. I. Dzhardimalieva
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  4. N. P. Ivleva
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  5. V. G. Vlasenko
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  6. T. I. Nedoseikina
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  7. T. A. Lyubeznova
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  8. I. E. Uflyand
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  9. A. D. Pomogailo
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Additional information

For Part 49, seeIzv. Akad. Nauk, Ser. Khim., 1998; 1145 [Russ. Chem. Bull., 1998,47, 1113 (Engl. Transl.)].

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1505–1510, August, 1998.

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Shuvaev, A.T., Rozenberg, A.S., Dzhardimalieva, G.I. et al. Synthesis and reactivity of metal-containing monomers. Russ Chem Bull 47, 1460–1465 (1998). https://doi.org/10.1007/BF02495593

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  • DOI: https://doi.org/10.1007/BF02495593

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