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Copper precipitation during continuous cooling and isothermal aging of a710-type steels

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Abstract

Precipitation in copper-containing A710 (also referred to as HSLA-80) and modified-A710 steels was investigated by transmission electron microscopy. Isothermal aging of as-quenched specimens at 675 °C produced e-copper precipitates located primarily at α-iron matrix dislocations. The precipitates exhibited multiple variants of an orientation relationship (OR) consistent with that reported by Kurdjumov and Sachs, fine fault formation, and associated streaking in electron diffraction patterns. For reaustenitized and continuously cooled specimens, the primary precipitation event was associated with interphase precipitation of copper at ferrite/austenite interfaces. Interphase precipitates frequently displayed ORs other than that reported by Kurdjumov and Sachs, although a unique crystallographic variant was observed within any one region of interphase precipitation, faults were observed infrequently, and streaking was not observed in diffraction patterns. At high temperatures during cooling, precipitate-free ferrite formed, whereas at lower temperatures, nucleation of copper precipitates occurred at ferrite/austenite interfaces for crystals of polygonal ferrite and Widmanstätten ferrite. This latter feature precludes the formation of Widmanstätten ferritevia a displacive mechanism. Interphase precipitation was not observed for granular ferrite or acicular ferrite. Less-common precipitation events during continuous cooling included the formation of AIN and CuS.

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References

  1. H.B. Kinnear:Iron Age, 1931, vol. 128, pp. 696–99 and pp. 820–24.

    CAS  Google Scholar 

  2. F. Nehl:Stahl Eisen, 1930, vol 50, pp. 678–86.

    CAS  Google Scholar 

  3. H. Buchholtz and W. KostenStahl Eisen, 1930, vol. 50, pp. 687–95.

    CAS  Google Scholar 

  4. C.E. Williams and C.H. Long:Met. Alloys, 1936, vol. 7, pp. 57–63.

    CAS  Google Scholar 

  5. C.S. Smith and E.W. Palmer:Trans. AIME, 1933, vol. 105, pp. 133- 68.

    Google Scholar 

  6. J.T. Norton:Trans. AIME, 1935, vol. 116, pp. 386–96.

    Google Scholar 

  7. S.K. Lahiri, D. Chandra, L.H. Schwartz, and M.E. Fine:Trans. TMS- AIME, 1969, vol. 245, pp. 1865–68.

    CAS  Google Scholar 

  8. E. Hornbogen and R.C. Glenn:Trans. TMS-AIME, 1960, vol. 218, pp. 1064–70.

    CAS  Google Scholar 

  9. E. Hornbogen: inPrecipitation from Iron-Base Alloys, G.R. Speich and J.B. Clark, eds., Gordon and Breach, New York, NY, 1965, pp. 1–67.

    Google Scholar 

  10. G.R. Speich and R.A. Oriani:Trans. TMS-AIME, 1965, vol. 233, pp. 623–31.

    CAS  Google Scholar 

  11. G. Kurdjumov and G. Sachs:Z Phys., 1930, vol. 64, pp. 325–43.

    Article  Google Scholar 

  12. U. Dahmen, P. Ferguson, and K.H. Westmacott:Acta Metall., 1984, vol. 32, pp. 803–10.

    Article  CAS  Google Scholar 

  13. A. Youle and B. Ralph:Met. Sci., 1972, vol. 6, pp. 149–52.

    Article  CAS  Google Scholar 

  14. S.R. Goodman, S.S. Brenner, and J.R. Low, Jr.:Metall. Trans., 1973, vol. 4, pp. 2363–69.

    CAS  Google Scholar 

  15. S.R. Goodman, S.S. Brenner, and J.R. Low, Jr.:Metall. Trans., 1973, vol. 4, pp. 2371–78.

    CAS  Google Scholar 

  16. D.A. Porter and K.E. Easterling:Phase Transformations in Metals and Alloys, Van Nostrand Reinhold, New York, NY, 1981, pp. 142–50.

    Google Scholar 

  17. J.M. Rigsbee and H.I. Aaronson:Acta Metall., 1979, vol. 27, pp. 351- 63.

    Google Scholar 

  18. J.M. Rigsbee and H.I. Aaronson:Acta Metall., 1979, vol. 27, pp. 365- 76.

    Google Scholar 

  19. W.T. Reynolds, Jr.,M. Enomoto, and H.I. Aaronson: inPhase Transformations in Ferrous Alloys, A.R. Marder and J.I. Goldstein, eds., TMS, Warrendale, PA, 1984, pp. 155–200.

    Google Scholar 

  20. W.J. Phythian, A.J.E. Foreman, C.A. English, J.T. Buswell, M. Hetherington, K. Roberts, and S. Pizzini: inEffects of Radiation on Materials: 15th Int. Symp., ASTM STP 1125, R.E. Stoller, A.S. Kumar, and D.S. Gelles, eds., ASTM, Philadelphia, PA, 1992, pp. 131–50.

    Google Scholar 

  21. P.J. Othen, M.L. Jenkins, G.D.W. Smith, and W.J. Phythian:Phil. Mag. Lett., 1991, vol. 64, pp. 383–91.

    Article  CAS  Google Scholar 

  22. G.M. Worrall, J.T. Buswell, C.A. English, M.G. Hetherington, and G.D.W. Smith:J. Nucl. Mater., 1987, vol. 148, pp. 107–14.

    Article  CAS  Google Scholar 

  23. S. Pizzini, K.J. Roberts, W.J. Phythian, C.A. English, and G.N. Greaves:Phil. Mag. Lett., 1990, vol. 61, pp. 223–29.

    Article  CAS  Google Scholar 

  24. R.A. Ricks, P.R. Howell, and R.W.K. Honeycombe:Metall. Trans. A, 1979, vol. 10A, pp. 1049–58.

    CAS  Google Scholar 

  25. P.R. Howell, R.A. Ricks, J.V. Bee, and R.W.K. Honeycombe:Phil. Mag. A, 1980, vol. 41, pp. 165–75.

    Article  CAS  Google Scholar 

  26. P.R. Howell, R.A. Ricks, and R.W.K. Honeycombe:J. Mater. Sci., 1980, vol. 15, pp. 376–80.

    Article  CAS  Google Scholar 

  27. R.W.K. Honeycombe:Met. Sci., 1980, vol. 14, pp. 201–14.

    Article  CAS  Google Scholar 

  28. R.A. Ricks, P.R. Howell, and R.W.K. Honeycombe:Met. Sci., 1980, vol. 14, pp. 562–68.

    Article  CAS  Google Scholar 

  29. R.A. Ricks:J. Mater. Sci., 1981, vol. 16, pp. 3006–12.

    Article  CAS  Google Scholar 

  30. R.W.K. Honeycombe:Metall. Trans. A, 1976, vol. 7A, pp. 915–36.

    CAS  Google Scholar 

  31. G.R. Speich and T.M. Scoonover: inProcessing, Microstructure and Properties of HSLA Steels, A.J. DeArdo, ed., TMS, Warrendale, PA, 1988, pp. 263–86.

    Google Scholar 

  32. S.W. Thompson, D.J. Colvin, and G. Krauss:Metall. Trans. A, 1996, vol. 27A, pp. 1554–68.

    Google Scholar 

  33. S.W. Thompson, D.J. Colvin, and G. Krauss:Metall. Trans. A, 1990, vol. 21A, pp. 1493–1507.

    CAS  Google Scholar 

  34. J.A. Wasynczuk, R.M. Fisher, and G. Thomas:Metall. Trans. A, 1986, vol. 17A, pp. 2163–73.

    CAS  Google Scholar 

  35. F.A. Khalid and D.V. Edmonds:Metall. Trans. A, 1993, vol. 24A, pp. 781–93.

    CAS  Google Scholar 

  36. F.A. Khalid and D.V. Edmonds: inSolid-Solid Phase Transformations, W.C. Johnson, J.M. Howe, D.E. Laughlin, and W.A. Sofia, eds., TMS, Warrendale, PA, 1994, pp. 225–30.

    Google Scholar 

  37. G. Fourlaris, A.J. Baker, and G.D. Papadimitriou: inSolid-Solid Phase Transformations, W.C. Johnson, J.M. Howe, D.E. Laughlin, and W.A. Sofia, eds., TMS, Warrendale, PA, 1994, pp. 923–28.

    Google Scholar 

  38. G. Fourlaris, A.J. Baker, and G.D. Papadimitriou: inSolid-Solid Phase Transformations, W.C. Johnson, J.M. Howe, D.E. Laughlin, and W.A. Soffa, eds., TMS, Warrendale, PA, 1994, pp. 553–58.

    Google Scholar 

  39. G. Fourlaris, A.J. Baker, and G.D. Papadimitriou:Acta Metall. Mater., 1995, vol. 43, pp. 2589–2604.

    Article  CAS  Google Scholar 

  40. D.J. Colvin: Master's Thesis, Colorado School of Mines, Golden, CO, 1988.

    Google Scholar 

  41. S.W. Thompson and G. Krauss:Proc. 47th Annual Meeting of the Electron Microscopy Society of America, G.W. Bailey, ed., San Francisco Press, Inc., San Francisco, CA, 1989, pp. 282–83.

    Google Scholar 

  42. H.I. Aaronson and J.K. Lee: inLectures on the Theory of Phase Transformations, H.I. Aaronson, ed., TMS-AIME, Warrendale, PA, 1975, pp. 83–115.

    Google Scholar 

  43. E. Hornbogen:Acta Metall., 1962, vol. 10, pp. 525–33.

    Article  CAS  Google Scholar 

  44. E. Hornbogen and H.-P. Jung:Z Metallkd., 1964, vol. 55, pp. 691–98.

    CAS  Google Scholar 

  45. Hirsch, A. Howie, R.B. Nicholson, D.W. Pashley, and M.J. Whelan,Electron Microscopy of Thin Crystals, 2nd ed., Krieger Publishing Co., Malabar, FL, 1977, pp. 105–07.

    Google Scholar 

  46. V.K. Heikkinen:Scand. J. Metall., 1973, vol. 2, pp. 109–12.

    CAS  Google Scholar 

  47. R.A. Ricks and P.R. Howell:Met. Sci., 1982, vol. 16, pp. 317–21.

    Article  CAS  Google Scholar 

  48. R.A. Ricks and P.R. Howell:Acta Metall., 1983, vol. 31, pp. 853–61.

    Article  CAS  Google Scholar 

  49. H.I. Aaronson: inDecomposition of Austenite by Diffusional Processes, V.F. Zackay and H.I. Aaronson, eds., Interscience Publishers, New York, NY, 1962, pp. 387–548.

    Google Scholar 

  50. P.R. Howell and R.W.K. Honeycombe: inSolid-Solid Phase Transformations, H.I. Aaronson, D.E. Laughlin, R.F. Sekerka, and C.M. Wayman, eds., TMS-AIME, Warrendale, PA, 1982, pp. 399- 425.

    Google Scholar 

  51. N.K. Balliger and R.W.K. Honeycombe:Metall. Trans. A, 1980, vol. 11 A, pp. 421–29.

    Google Scholar 

  52. D.A. Porter and K.E. Easterling:Phase Transformations in Metals and Alloys, Van Nostrand Reinhold, New York, NY, 1981, pp. 265- 78.

    Google Scholar 

  53. J.R. Bradley, G.J. Shiflet, and H.I. Aaronson, inSolid-Solid Phase Transformations, H.I. Aaronson, D.E. Laughlin, R.F. Sekerka, and C.M. Wayman, eds., TMS-AIME, Warrendale, PA, 1982, pp. 819–24.

    Google Scholar 

  54. A.D. King and T. Bell:Metall. Trans. A, 1975, vol. 6A, pp. 1419–29.

    CAS  Google Scholar 

  55. A.D. King and T. Bell:Metallography, 1976, vol. 9, pp. 397–413.

    Article  CAS  Google Scholar 

  56. D.E. Coates:Metall. Trans., 1972, vol. 3, pp. 1203–12.

    Article  CAS  Google Scholar 

  57. H.I. Aaronson and H.A. Domian:Trans. TMS-AIME, 1966, vol. 236, pp. 781–96.

    CAS  Google Scholar 

  58. M. Hillert: inThe Mechanism of Phase Transformations in Crystalline Solids, Institute of Metals, London, 1969, pp. 231–47.

    Google Scholar 

  59. H.K.D.H. Bhadeshia:Acta Metall., 1981, vol. 29, pp. 1117–1130.

    Article  CAS  Google Scholar 

  60. H.I. Aaronson: inThe Mechanism of Phase Transformations in Crystalline Solids, Institute of Metals, London, 1969, pp. 270–281.

    Google Scholar 

  61. H.I. Aaronson, J.M. Rigsbee, and R.K. Trivedi:Scripta Metall., 1986, vol. 20, pp. 1299–1304.

    Article  CAS  Google Scholar 

  62. C.S. Smith:Trans. ASM, 1953, vol. 45, pp. 533–75.

    CAS  Google Scholar 

  63. C.A. English: inRadiation Embrittlement of Nuclear Reactor Pressure Vessel Steels: An International Review, ASTM STP 909, L.E. Steele, ed., ASTM, Philadelphia, PA, 1986, vol. 2, pp. 187–205.

    Google Scholar 

  64. S.W. Thompson, D.J. Colvin, and G. Krauss:Scripta Metall., 1988, vol. 22, pp. 1069–74.

    Article  CAS  Google Scholar 

  65. T.L. Davis: Master's Thesis, Colorado School of Mines, Golden, CO, 1995.

    Google Scholar 

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This article is based on a presentation made during TMS/ASM Materials Week in the symposium entitled “Atomistic Mechanisms of Nucleation and Growth in Solids,” organized in honor of H.I. Aaronson’s 70th Anniversary and given October 3–5, 1994, in Rosemont, Illinois.

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Thompson, S.W., Krauss, G. Copper precipitation during continuous cooling and isothermal aging of a710-type steels. Metall Mater Trans A 27, 1573–1588 (1996). https://doi.org/10.1007/BF02649816

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