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Interaction coefficients in the iron-carbon-titanium and titanium-silver systems

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Abstract

A liquid Fe-C-Ti system was studied by establishing an iso-titanium-activity state for ternary samples at 1600 °C through the medium of a bath of liquid silver which permits diffusion of titanium only. From the two iso-titanium-activity lines obtained, the self-interaction coefficients of titanium and interaction coefficients of carbon on titanium in liquid iron were estimated:ε Ti Ti = 4.67, ρTi Ti = 0.32, εTi C = −11.94, ρTi C = −4.52, ρTi Ti,C = −9.96 An experimental study has been made of the distribution of titanium between liquid silver and liquid iron at 1600 °C. By the use of the interaction coefficients of titanium and rTi o in liquid iron, the thermodynamic parameters of titanium in liquid silver were determined asr Ti o Ag = 2.44 X 10−3, (εTi Ti Ag = −6.17, (ρTi Ti)Ag = −16.3

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Authors and Affiliations

  1. Department of Metallurgical Physicochemistry, Northeast University of Technology, Shenyang, Liaoning, People’s Republic of China

    Guo Yuanchang (Teaching Assistant), Wang Changzhen (Professor) & Yu Hualong (Engineer)

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  1. Guo Yuanchang
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  2. Wang Changzhen
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  3. Yu Hualong
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Yuanchang, G., Changzhen, W. & Hualong, Y. Interaction coefficients in the iron-carbon-titanium and titanium-silver systems. Metall Trans B 21, 537–541 (1990). https://doi.org/10.1007/BF02667866

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