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Hydrogen-enhanced localization of plasticity in an austenitic stainless steel

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Abstract

Microscopic observations and the results of static strain aging, stress relaxation, and strain rate change tests on 310s stainless steel foils, with and without hydrogen, have been presented to complement the stress-strain curves in a previous article. The hydrogen-free specimens showed minute yield points during static strain aging, while the hydrogen-containing specimens demonstrated “preyield microstrain. ” Thermal activation analysis of the strain rate change and stress relaxation plots led to the conclusion that the activation area for dislocation motion is decreased by hydrogen. Microstructural examination with the scanning electron microscope (SEM) revealed extensive strain localization, while transmission electron microscopy (TEM) studies showed microtwinning and austenite faulting in hydrogenated specimens tested at room temperature. The relation of hydrogen-induced changes in plastic deformation to hydrogen embrittlement is discussed.

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References

  1. A. Luft:Progress in Materials Science, Pergamon Press, Oxford, United Kingdom, 1991, vol. 35, p. 97.

    Google Scholar 

  2. O.A. Onyewuenyi: inHydrogen Degradation of Ferrous Alloys,R.A. Oriani, J.P. Hirth, and M. Smialowski, eds., Noyes Publications, Park Ridge, NJ, 1985, p. 414.

    Google Scholar 

  3. CD. Beachem:Metall. Trans., 1972, vol. 3, pp. 437–51.

    CAS  Google Scholar 

  4. T.D. Lee, T. Goldenberg, and J.P. Hirth:Metall. Trans. A, 1979, vol. 10A, pp. 199–208.

    CAS  Google Scholar 

  5. T.D. Lee, T. Goldenberg, and J.P. Hirth:Metall. Trans. A, 1979, vol. 10A, pp. 439–48.

    CAS  Google Scholar 

  6. J.P. Hirth: inHydrogen Effects on Material Behavior, N.R. Moody and A.W. Thompson, eds., TMS, Warrendale, PA, 1990, p. 677.

    Google Scholar 

  7. S.P. Lynch:Acta Metall, 1988, vol. 36, p. 2639.

    Article  CAS  Google Scholar 

  8. T. Matsumoto, J. Eastman, and H.K. Birnbaum:Scripte Metall, 1981, vol. 15, p. 1033.

    Article  CAS  Google Scholar 

  9. J. Eastman, F. Heubaum, T. Matsumoto, and H.K. Birnbaum:Acta Metall., 1982, vol. 30, p. 1579.

    Article  CAS  Google Scholar 

  10. T. Tabata and H.K. Birnbaum:Scripta Metall, 1984, vol. 18, p. 231.

    Article  CAS  Google Scholar 

  11. I.M. Robertson and H.K. Birnbaum:Ada Metall, 1986, vol. 34, p. 353.

    Article  CAS  Google Scholar 

  12. D. Shih, I.M. Robertson, and H.K. Birnbaum:Acta Metall, 1988, vol. 36, p. 111.

    Article  CAS  Google Scholar 

  13. G. Bond, I.M. Robertson, and H.K. Birnbaum:Acta Metall, 1988, vol. 36, p. 2193.

    Article  CAS  Google Scholar 

  14. D.P. Abraham and C.J. Altstetter:Metall. Mater. Trans. A, 1995, vol. 26A, pp. 2849–2858.

    CAS  Google Scholar 

  15. M.A. Meyers:Mechanical Metallurgy, Prentice-Hall, Englewood Cliffs, NJ, 1984, pp. 586–93.

    Google Scholar 

  16. H.E. Deve, S.V. Harren, C. McCullough, and R.J. Asaro:Acta Metall., 1988, vol. 36, p. 341.

    Article  CAS  Google Scholar 

  17. S.V. Harren, H.E. Deve, and R.J. Asaro:Acta Metall, 1988, vol. 36, p. 2435.

    Article  CAS  Google Scholar 

  18. H.E. Deve and R.J. Asaro:Metall. Trans. A, 1989, vol. 20A, pp. 579–93.

    CAS  Google Scholar 

  19. P.R. Swann:Corrosion, 1963, vol. 19, p. 102.

    Google Scholar 

  20. D.L. Douglass, G. Thomas, and W.R. Roser:Corrosion, 1964, vol. 20, p. 15t.

  21. F. Lecroisey and A. Pineau:Metall. Trans., 1972, vol. 3, pp. 387–96.

    CAS  Google Scholar 

  22. L.E. Murr, K.P. Staudhammer, and S.S. Hecker:Metall. Trans. A, 1982, vol. 13A, pp. 627–35.

    Google Scholar 

  23. P.B. Hirsch, A. Howie, R.B. Nicholson, and D.W. Pashley:Electron Microscopy of Thin Crystals, Butterworth and Co., London, 1965, pp. 242–46.

    Google Scholar 

  24. I.M. Robertson:Phil. Mag. A, 1986, vol. 54, p. 821.

    Article  CAS  Google Scholar 

  25. D. Cherns:Phil. Mag. A, 1974, vol. 30, p. 549.

    Article  CAS  Google Scholar 

  26. D.W. Pashley and M.J. Stowell:Phil. Mag. A, 1963, vol. 8, p. 94.

    Google Scholar 

  27. A. Ourmazd, G.R. Anstis, and P.B. Hirsch:Phil. Mag. A, 1983, vol. 48, p. 139.

    Article  CAS  Google Scholar 

  28. H. Alexander, J.C.H. Spence, D. Shindo, H. Gottschalk, and N. Long:Phil. Mag. A, 1986, vol. 53, p. 627.

    Article  CAS  Google Scholar 

  29. D.G. Ulmer and C.J. Altstetter:Acta Metall. Mater., 1993, vol. 41, p. 2235.

    Article  CAS  Google Scholar 

  30. N. Narita, C.J. Altstetter, and H.K. Birnbaum:Metall. Trans. A, 1982, vol. 13A, pp. 1355–65.

    Google Scholar 

  31. L.P. Kubin, Y. Estrin, and C. Perrier:Acta Metall. Mater., 1992, vol. 40, p. 1037.

    Article  CAS  Google Scholar 

  32. U.F. Kocks, R.E. Cook, and R.A. Mulford:Acta Metall, 1985, vol. 33, p. 623.

    Article  CAS  Google Scholar 

  33. H.K. Birnbaum:Acta Metall., 1961, vol. 9, p. 320.

    Article  CAS  Google Scholar 

  34. H.B. Aaron and H.K. Birnbaum:Acta Metall, 1965, vol. 13, p. 205.

    Article  CAS  Google Scholar 

  35. U.F. Kocks, A.S. Argon, and M.F. Ashby:Progress in Materials Science, Pergamon Press, Oxford, United Kingdom, 1975, vol. 19.

    Google Scholar 

  36. E. Sirois: Ph.D. Thesis, University of Illinois at Urbana-Champaign, Urbana, IL, 1990.

    Google Scholar 

  37. E. Sirois and H.K. Birnbaum:Acta Metall, 1992, vol. 40, p. 1377.

    Article  CAS  Google Scholar 

  38. E. Sirois, P. Sofronis, and H.K. Birnbaum:Fundamental Aspects of Stress Corrosion Cracking, Parkins Symp., S.M. Bruemmer,E.I. Meletis, R.H. Jones, W.W. Gerberich, F.P. Ford, and R.W. Staehle, eds., TMS, Warrendale, PA 1992, p. 173.

    Google Scholar 

  39. D.G. Ulmer and C.J. Altstetter:Acta Metall, 1991, vol. 28, p. 1237.

    Article  Google Scholar 

  40. R.N. Gardner and H.G.F. Wilsdorf:Metall Trans. A, 1980, vol. 11A, pp. 659–69.

    CAS  Google Scholar 

  41. J.K. Tien, S.V. Nair, and R.R. Jensen: inHydrogen Effects in Metals, I.M. Bernstein and A.W. Thompson, eds., TMS-AIME, Warrendale, PA, 1981, p. 37.

    Google Scholar 

  42. John K. Tien, Anthony W. Thompson, I.M. Bernstein, and Rebecca J. Richards:Metall. Trans. A, 1976, vol. 7A, pp. 821–29.

    CAS  Google Scholar 

  43. M.R. Louthan, Jr., G.R. Caskey, J.A. Donavan, and D.E. Rawl, Jr.:Mater. Sci. Eng., 1972, vol. 10, p. 357.

    Article  CAS  Google Scholar 

  44. A.J. West, Jr. and M.R. Louthan, Jr.:Metall. Trans. A, 1982, vol. 13A, pp. 2049–58.

    Google Scholar 

  45. A.H. Cottrell:Dislocations and Plastic Flow in Crystals, Clarendon Press, Oxford, United Kingdom, 1953, p. 136.

    Google Scholar 

  46. P. Sofronis:J. Mech. Phys. Sol., in press.

  47. C. Hwang and I.M. Bernstein:Scripta Metall, 1982, vol. 16, p. 85.

    Article  CAS  Google Scholar 

  48. T.D. Le, I.M. Bernstein, and S. Mahajan:Acta Metall. Mater., 1993, vol. 41, p. 3363.

    Article  CAS  Google Scholar 

  49. G.R. Caskey, Jr.:Environmental Degradation of Engineering Materials, Proc. Conf., Virginia Polytechnic Institute, Blacksburg, VA, 1977, p. 437.

    Google Scholar 

  50. G.R. Caskey, Jr.:Fractography and Materials Science, ASTM STP 733, L.N. Gilbertson and R.D. Zipp, eds., ASTM, Philadelphia, PA, 1981, p. 86.

    Google Scholar 

  51. J.A. Peterson, R. Gibala, and A.R. Troiano:J. Iron Steel Inst., 1969, vol. 1, p. 86.

    Google Scholar 

  52. A.W. Thompson and I.M. Bernstein:Adv. Corros. Sci. Technol., 1980, vol. 7, p. 53.

    CAS  Google Scholar 

  53. V. Gerold and H.P. Karnthaler:Acta Metall, 1989, vol. 37, p. 2177.

    Article  CAS  Google Scholar 

  54. S.I. Hong and C. Laird:Acta Metall, 1990, vol. 38, p. 1581.

    Article  CAS  Google Scholar 

  55. S. Jani, M. Marek, R.F. Hochman, and E.I. Meletis:Metall. Trans. A, 1991, vol. 22A, pp. 1453–61.

    CAS  Google Scholar 

  56. J.P. Hirth and J. Lothe:Theory of Dislocations, Wiley Publishing Co., New York, NY, 1982.

    Google Scholar 

  57. L. Remy, A. Pineau, and B. Thomas:Mater. Sci. Eng., 1978, vol. 36, p. 47.

    Article  CAS  Google Scholar 

  58. R.M. Latanision and A.W. Ruff, Jr.:Metall. Trans., 1971, vol. 2, pp. 505–09.

    CAS  Google Scholar 

  59. C.J. Novak: inHandbook of Stainless Steels, D. Peckner andI.M. Bernstein, eds., McGraw-Hill Publishing Co., New York, NY, 1977, p. 4–1.

    Google Scholar 

  60. C.B. Carter and S.M. Holmes:Phil. Mag. A, 1977, vol. 35, p. 1161.

    Article  CAS  Google Scholar 

  61. H.K. Birnbaum: University of Illinois at Urbana-Champaign, Urbana, IL, private communication, 1992.

  62. G.E. Dieter:Mechanical Metallurgy, McGraw-Hill Publishing Co., New York, NY, 1976, p. 351.

    Google Scholar 

  63. K. Oda, N. Kondo, and K. Shibata:Iron Steel Inst. Jpn. Int., 1990, vol. 30, p. 625.

    CAS  Google Scholar 

  64. J. Pielaszek: inHydrogen Degradation of Ferrous Alloys, R.A. Oriani, J.P. Hirth, and M. Smialowski, eds., Noyes Publications, Park Ridge, NJ, 1985, p. 167.

    Google Scholar 

  65. T. Kimura, H. Matsui and H. Kimura: inStrength of Metals and Alloys, Proc. Conf., P.O. Kettunen, T.K. Lepisto, and M.H. Lehtonen, eds., Pergamon Press, Oxford, United Kingdom, 1988, vol. 2, p. 541.

    Google Scholar 

  66. K. Oguri, S. Takaki, and H. Kimura:Mater. Sci. Eng., 1982, vol. 53, p. 223.

    Article  CAS  Google Scholar 

  67. O. Yoshinari, K. Sanpei, and K. Tanaka:Acta Metall. Mater., 1991, vol. 39, p. 2657.

    Article  CAS  Google Scholar 

  68. J.J. Gilman:J. Appl. Phys., 1961, vol. 32, p. 738.

    Article  CAS  Google Scholar 

  69. S. Wiederhorn:J. Appl. Phys., 1962, vol. 33, p. 3233.

    Article  CAS  Google Scholar 

  70. S. Wiederhorn:J. Appl. Phys., 1963, vol. 34, p. 2125.

    Article  CAS  Google Scholar 

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Formerly Graduate Student, Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign.

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Abraham, D.P., Altstetter, C.J. Hydrogen-enhanced localization of plasticity in an austenitic stainless steel. Metall Mater Trans A 26, 2859–2871 (1995). https://doi.org/10.1007/BF02669644

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