Skip to main content
Log in

Continuous cooling transformations and microstructures in a low-carbon, high-strength low-alloy plate steel

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

A continuous-cooling-transformation (CCT) diagram was determined for a high-strength low-alloy plate steel containing (in weight percent) 0.06 C, 1.45 Mn, 1.25 Cu, 0.97 Ni, 0.72 Cr, and 0.42 Mo. Dilatometric measurements were supplemented by microhardness testing, light microscopy, and transmission electron microscopy. The CCT diagram showed significant suppression of polygonal ferrite formation and a prominent transformation region, normally attributed to bainite formation, at temperatures intermediate to those of polygonal ferrite and martensite formation. In the intermediate region, ferrite formation in groups of similarly oriented crystals about 1 μm in size and containing a high density of dislocations dominated the transformation of austenite during continuous cooling. The ferrite grains assumed two morphologies, elongated or acicular and equiaxed or granular, leading to the terms “acicular ferrite” and “granular ferrite,” respectively, to describe these structures. Austenite regions, some transformed to martensite, were enriched in carbon and retained at interfaces between ferrite grains. Coarse interfacial ledges and the nonacicular morphology of the granular ferrite grains provided evidence for a phase transformation mechanism involving reconstructive diffusion of substitutional atoms. At slow cooling rates, polygonal ferrite and Widmanstätten ferrite formed. These latter structures contained low dislocation densities and e-copper precipitates formed by an interphase transformation mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T.W. Montemarano, B.P. Sack, J.P. Gudas, M.G. Vassilaros, and H.H. Vanderveldt:J. Ship Production, 1986, vol. 2, pp. 145–62.

    Google Scholar 

  2. J.C. West:J. Ship Production, 1987, vol. 3, pp. 111–18.

    Google Scholar 

  3. R.J. Jesseman and G.J. Murphy:J. Heat Treat., 1984, vol. 3, pp. 228–36.

    CAS  Google Scholar 

  4. G.E. Hicho, C.H. Brady, L.C. Smith, and R.J. Fields:J. Heat Treat., 1987, vol. 5, pp. 7–19.

    CAS  Google Scholar 

  5. G.R. Speich and T.M. Scoonover: inProcessing, Microstructure and Properties of HSLA Steels, A.J. De Ardo, ed., TMS, Warrendale, PA, 1988, pp. 263–86.

    Google Scholar 

  6. M.T. Miglin, J.P. Hirth, A.R. Rosenfield, and W.A.T. Clark:Metall. Trans. A, 1986, vol. 17A, pp. 791–98.

    CAS  Google Scholar 

  7. A.D. Wilson, E.G. Hamburg, D.J. Colvin, S.W. Thompson, and G. Krauss:Microalloyed HSLA Steels, ASM INTERNATIONAL, Metals Park, OH, 1988, pp. 259–75.

    Google Scholar 

  8. C.S. Smith and E.W. Palmer:Trans. AIME, 1933, vol. 105, pp. 133–68.

    Google Scholar 

  9. E. Hornbogen:Trans. ASM, 1964, vol. 57, pp. 120–32.

    Google Scholar 

  10. R.A. DePaul and A.L. Kitchin:Metall. Trans., 1970, vol. 1, pp. 389–93.

    CAS  Google Scholar 

  11. First Progress Report of Subcommittee XI, ASTM Committee E-4:Proc. ASTM, 1950, vol. 50, pp. 444–92.

    Google Scholar 

  12. Second Progress Report of Subcommittee XI, ASTM Committee E-4:Proc. ASTM, 1952, vol. 52, pp. 543–96.

    Google Scholar 

  13. R.F. Hehemann:Metals Handbook, 8th ed., ASM, Metals Park, OH, 1972, vol. 8, pp. 194–96.

    Google Scholar 

  14. H.I. Aaronson:The Mechanism of Phase Transformations in Crystalline Solids, Monograph and Report Series No. 33, The Institute of Metals, London, 1969, pp. 270–81.

    Google Scholar 

  15. R.F. Hehemann, K.R. Kinsman, and H.I. Aaronson:Metall. Trans., 1972, vol. 3, pp. 1077–94.

    Article  CAS  Google Scholar 

  16. H.I. Aaronson and H.J. Lee:Scripta Metall., 1987, vol. 21, pp. 1011–16.

    Article  CAS  Google Scholar 

  17. J.W. Christian and D.V. Edmonds: inPhase Transformations in Ferrous Alloys, A.R. Marder and J.I. Goldstein, eds., TMS-AIME, Warrendale, PA, 1984, pp. 293–325.

    Google Scholar 

  18. G.B. Olson, H.K.D.H. Bhadeshia, and M. Cohen:Acta Metall., 1989, vol. 37, pp. 381–90.

    Article  CAS  Google Scholar 

  19. S.W. Thompson, D.J. Colvin, and G. Krauss:Scripta Metall, 1988, vol. 22, pp. 1069–74.

    Article  CAS  Google Scholar 

  20. B.L. Bramfitt and J.G. Speer:Metall. Trans. A, 1990, vol. 21A, pp. 817–29.

    CAS  Google Scholar 

  21. L.J. Habraken and M. Economopoulos:Transformation and Hardenability in Steels, Climax Molybdenum Company, Ann Arbor, MI, 1967, pp. 69–108.

    Google Scholar 

  22. Y.E. Smith, A.P. Coldren, and R.L. Cryderman:Toward Improved Ductility and Toughness, Climax Molybdenum Company, Ann Arbor, MI, 1971, pp. 119–42.

    Google Scholar 

  23. V. Biss and R.L. Cryderman:Metall. Trans., 1971, vol. 2, pp. 2267–76.

    CAS  Google Scholar 

  24. M.E. Bush and P.M. Kelly:Acta Metall., 1971, vol. 19, pp. 1363–71.

    Article  CAS  Google Scholar 

  25. Z. Bojarski and T. Bold:Acta Metall., 1974, vol. 22, pp. 1223–34.

    Article  CAS  Google Scholar 

  26. A. Brownrigg:Met. Sci., 1975, vol. 9, pp. 313–18.

    Article  CAS  Google Scholar 

  27. E.C. Hamre and A.M. Gilroy-Scott:Proc. Microalloying '75, Union Carbide Corporation, New York, NY, 1977, pp. 375–81.

    Google Scholar 

  28. N.A. McPherson and T.N. Baker:Met. Sci., 1976, vol. 10, pp. 140–47.

    Article  CAS  Google Scholar 

  29. P.L. Mangonon:Metall. Trans. A, 1976, vol. 7A, pp. 1389–1400.

    CAS  Google Scholar 

  30. H. Fang, Y. Zheng, and B. Bai: inHSLA Steels: Metallurgy and Applications, J.M. Gray, T. Ko, S. Zhang, B. Wu, and X. Xie, eds., ASM INTERNATIONAL, Metals Park, OH, 1986, pp. 359–67.

    Google Scholar 

  31. T. Araki, K. Shibata, and M. Enomoto:ICOMAT '89, in press.

  32. 1990 Annual Book of ASTM Standards, ASTM Designation A710, ASTM, Philadelphia, PA, 1990, vol. 01.04, pp. 500–02.

  33. D.J. Colvin: M.S. Thesis, Colorado School of Mines, Golden, CO, 1988.

    Google Scholar 

  34. K.W. Andrews:J. Iron Steel Inst., 1965, vol. 203, pp. 721–27.

    CAS  Google Scholar 

  35. W. Steven and A.G. Haynes:J. Iron Steel Inst., 1956, vol. 183, pp. 349–59.

    CAS  Google Scholar 

  36. C.F. ZurLippe and J.D. Grozier: inAtlas of Isothermal Transformation and Cooling Transformation Diagrams, ASM, Metals Park, OH, 1977, pp. 416–17.

    Google Scholar 

  37. G. Krauss: inHardenability Concepts with Applications to Steel, D.V. Doane and J.S. Kirkaldy, eds., TMS-AIME, Warrendale, PA, 1978, pp. 229–48.

    Google Scholar 

  38. R. Blondeau, Ph. Maynier, J. Dollet, and B. Vieillard-Baron:Heat Treatment '76, The Metals Society, London, 1976, pp. 189–200.

    Google Scholar 

  39. H.K.D.H. Bhadeshia and J.W. Christian:Metall. Trans. A, 1990, vol. 21A, pp. 767–97.

    CAS  Google Scholar 

  40. A.R. Marder and G. Krauss:Trans. ASM, 1967, vol. 60, pp. 651–60.

    CAS  Google Scholar 

  41. H.I. Aaronson and W.T. Reynolds, Jr.:Scripta Metall., 1988, vol. 22, pp. 567–72.

    Article  Google Scholar 

  42. R.N. Caron and G. Krauss:Metall. Trans., 1972, vol. 3, pp. 2381–89.

    Article  CAS  Google Scholar 

  43. H.I. Aaronson and C. Wells:Trans. AIME, 1956, vol. 206, pp. 1216–23.

    Google Scholar 

  44. J.M. Oblak and R.F. Hehemann:Transformation and Hardenability in Steels, Climax Molybdenum Company, Ann Arbor, MI, 1967, pp. 15–38.

    Google Scholar 

  45. E.S.K. Menon and H.I. Aaronson:Acta Metall., 1987, vol. 35, pp. 549–63.

    Article  CAS  Google Scholar 

  46. V. Raghavan and A.R. Entwisle:Physical Properties of Martensite and Bainite, ISI Special Report No. 93, 1965, pp. 30–37.

  47. G. Kurdjumov and G. Sachs:Z.Phys., 1930, vol. 64, pp. 325–43.

    Article  Google Scholar 

  48. Z. Nishiyama:Sci. Rep. Tohoku Univ., 1934, vol. 23, pp. 637–64.

    CAS  Google Scholar 

  49. G. Wassermann:Arch. Eisenhüttenwes., 1933, vol. 16, pp. 647–54.

    Google Scholar 

  50. P.G. Boswell, K.R. Kinsman, G.J. Shiflet, and H.I. Aaronson: inMechanical Properties and Phase Transformations in Engineering Materials, S.D. Antolovich, R.O. Ritchie, and W.W. Gerberich, eds., TMS-AIME, Wanendale, PA, 1986, pp. 445–66.

    Google Scholar 

  51. H. Tsubakino and H.I. Aaronson:Metall. Trans. A, 1987, vol. 18A, pp. 2047–60.

    CAS  Google Scholar 

  52. H.I. Aaronson: inDecomposition of Austenite by Diffusional Processes, V.F. Zackay and H.I. Aaronson, eds., Interscience, New York, NY, 1962, pp. 387–548.

    Google Scholar 

  53. R.W.K. Honeycombe:Metall. Trans. A, 1976, vol. 7A, pp. 915–36.

    CAS  Google Scholar 

  54. R.A. Ricks, P.R. Howell, and R.W.K. Honeycombe:Met. Sci., 1980, vol. 14, pp. 562–68.

    Article  CAS  Google Scholar 

  55. M. Cohen, G.B. Olson, and P.C. Clapp:ICOMAT '79, MIT, Cambridge, MA, 1979, pp. 1–11.

  56. H.K.D.H. Bhadeshia:Scripta Metall., 1987, vol. 21, pp. 1017–22.

    Article  CAS  Google Scholar 

  57. J.W. Christian:Acta Metall., 1958, vol. 6, pp. 377–79.

    Article  Google Scholar 

  58. H.K.D.H. Bhadeshia:Worked Examples in the Geometry of Crystals, Institute of Metals, Brookfield, VT, 1987, p. 57.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Formerly Graduate Student, Department of Metallurgical and Materials Engineering, Colorado School of Mines.

This paper is based on a presentation made in the symposium “International Conference on Bainite” presented at the 1988 World Materials Congress in Chicago, IL, on September 26 and 27, 1988, under the auspices of the ASM INTERNATIONAL Phase Transformations Committee and the TMS Ferrous Metallurgy Committee.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Thompson, S.W., Vin Col, D.J. & Krauss, G. Continuous cooling transformations and microstructures in a low-carbon, high-strength low-alloy plate steel. Metall Trans A 21, 1493–1507 (1990). https://doi.org/10.1007/BF02672564

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02672564

Keywords

Navigation