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Gold in bimetallic catalysts

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Abstract

In spite of its low intrinsic catalytic activity, gold can influence the activity and selectivity of group VIII metals, such as palladium, platinum and ruthenium. Gold-containing bimetallic catalysts have found important industrial applications and represent an active research area for elucidating the correlation between surface structure and catalytic activity.

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References

  1. J. Schwank,Gold Bull., 1983,16, 103–110

    Article  CAS  Google Scholar 

  2. A. Couper and D.D. Eley,Disc. Faraday Soc., 1950,8, 172–184

    Article  Google Scholar 

  3. D.D. Eley and P. Luetic,Trans. Faraday Soc., 1957,53, 1483–1487

    Article  CAS  Google Scholar 

  4. A.G. Daglish and D.D. Eley, in ‘Actes 2ième Congr. Intern. de Catalyse’, Paris 1960, Vol. 2 (Technip, Paris, 1961), pp. 1615–1624

    Google Scholar 

  5. D.D. Eley and C.F. Knights,Proc. Roy. Soc. Ser. A, 1966,294, 1

    Article  CAS  Google Scholar 

  6. D.D. Eley,J. Res. Inst. Catalysis, Hokkaido Univ., 1968,16, 101

    CAS  Google Scholar 

  7. J.A. Nicholson, J.D. Riley, R.C.G. Leckey, J.G. Jenkin and J. Liesegang,J. Electron Spectrosc. Related Phenom., 1979,15, 95–99

    Article  CAS  Google Scholar 

  8. D.D. Eley and P.B. Moore,Surf. Sci., 1981,111, 325

    Article  CAS  Google Scholar 

  9. J.H. Sinfelt,J. Catal., 1973,29, 308–315

    Article  CAS  Google Scholar 

  10. J.B. Darby,Acta Met., 1966,14, 265

    Article  CAS  Google Scholar 

  11. F.L. Williams and D. Nason,Surf. Sci., 1974,45, 377

    Article  CAS  Google Scholar 

  12. B.J. Wood and H. Wise,Surf Sci., 1975,52, 151

    Article  CAS  Google Scholar 

  13. G. Maire, L. Hilaire, P. Legare, F.G. Gault and A. O’Cinneide,J. Catal., 1976,44, 293

    Article  CAS  Google Scholar 

  14. A. Jablonski, S.H. Overbury and G.A. Somorjai,Surf. Sci, 1977,65, 578

    Article  CAS  Google Scholar 

  15. D.D. Eley and P.B. Moore,J.C.S. Faraday I, 1980,76, 1388–1390

    Article  CAS  Google Scholar 

  16. K.M. Sancier and S.H. Inami,J. Catal., 1968,11, 135–142

    Article  CAS  Google Scholar 

  17. Y.L. Lam and M. Boudart,J. Catal., 1977,55, 530–540

    Article  Google Scholar 

  18. I.A. Zubovich and N.N. Migulina,Zb. Vses. Khim. O-va, 1979,24, 202–203

    CAS  Google Scholar 

  19. H.R. Gerberich and W.K. Hall,Nature, 1967,213, 1120

    Article  CAS  Google Scholar 

  20. H.R. Gerberich, N.W. Cant and W.K. Hall,J. Catal., 1970,16, 204–219

    Article  CAS  Google Scholar 

  21. D.M. McClain, C.A. Heller and I.L. Mador,Fr. Pat. 2,118,774 (1972)

  22. J.A. Scheben, J.A. Hinnenkamp and I.L. Mador,Ger. Offen 2 5 29 365 (1976)

    Google Scholar 

  23. H. Kinza and G. Alscher,Ger.(East) Pat. 106,557 (1974)

    Google Scholar 

  24. K. Sennewald, W. Vogt, H. Erpenbach and H. Glaser,S.Afr. Pat. 68 02,009 (1968)

  25. J. Schroeder, Z. Zabrzeski, J. Jarmakowicz, J. Terlecki and L. Wyrwa,Pol.PL 120,847 (1983)

  26. Y.L. Lam, J. Criado and M. Boudart,Nouv. J. Chim., 1977,1, 461–466

    CAS  Google Scholar 

  27. M. Boudart and Y.L. Lam,U.S. Pat. 4,136,062 (1979)

  28. D.L. Weissman-Wenocur and W.E. Spicer,Surf. Sci., 1983,133, 499–515

    Article  CAS  Google Scholar 

  29. E.L. Kugler and M. Boudart,J. Catal., 1979,59, 201–210

    Article  CAS  Google Scholar 

  30. M. Nakamura and H. Wise, in ‘Proceedings of the Sixth Inter. Congress on Catalysis, London 1976’, edited by G.C. Bond, P.B. Wells, F.C. Tompkins, Vol. 2, 881–893, The Chemical Society, London, 1977

    Google Scholar 

  31. A.A. Alchuzhdan and M.A. Mantikyan,Izvest. Akad. Nauk Armyan S.S.R., Khim. Nauki, 1959,12, 153–158

    Google Scholar 

  32. A.A. Alchuzhdan and E.T. Kristosturyan,Izvest. Akad, Nauk Armyan S.S.R., Khim. Nauki, 1959,12, 305–312

    Google Scholar 

  33. A.A. Alchuzhdan, M.A. Mantikyn and A.M. Aikazyan,Izvest. Akad. Nauk Armyan S.S.R., Khim. Nauki, 1964,17, 368–374

    Google Scholar 

  34. G. Aguilar, V.M. Gryaznov, L.F. Pavlova and V.D. Yagodovskii,React. Kinet. Catal. Lett., 1977,7, 181–186

    Article  CAS  Google Scholar 

  35. B.J. Wood and H. Wise,J. Catal., 1966,5, 135–145

    Article  CAS  Google Scholar 

  36. R.S. Yolles, B.J. Wood and H. Wise,J. Catal, 1971,21, 66–69

    Article  CAS  Google Scholar 

  37. S.H. Inami and H. Wise,J. Catal., 1972,26, 92–96

    Article  CAS  Google Scholar 

  38. A. O’Cinneide and J.K.A. Clarke,J. Catal., 1972,26, 233–241

    Article  Google Scholar 

  39. C. Horrex, R.B. Moyes and R.C. Squire, in ‘Proceedings of the fourth International Congress on Catalysis, Moscow, 1968’, Paper No. 25

  40. L.K. Frevel and L.J. Kressley,U.S. Pat. 2,802,889(1957);Ger. Offen. 10 52 979 (1959)

    Google Scholar 

  41. C. Visser, J.G.P. Zuidwijk and V. Ponec,J. Catal., 1974,35, 407–416

    Article  CAS  Google Scholar 

  42. H.G. Rushford and D.A. Whan,Faraday Trans., 1971,67, 3377

    Google Scholar 

  43. A. O’Cinneide and F.G. Gault,J. Catal., 1975,37, 311–323

    Article  Google Scholar 

  44. B.J. Joice, J.J. Rooney, P.B. Wells and G.R. Wilson,Disc. Faraday Soc., 1966,41, 223–236

    Article  Google Scholar 

  45. J.H. Sinfelt, A.E. Barnett and G.W. Dembinski,U.S. Pat. 3,442,973 (1969)

  46. J.H. Sinfelt, A.E. Barnett and J.L. Carter,U.S. Pat. 3,769,201 (1973)

  47. J.H. Sinfelt and J.L. Carter,Ger. Offen. 2 2 25 364 (1972)

  48. J.R. Kittrell,U.S. Pat. 3,576,736

  49. G.L. Kaiser,U.S. Pat. 3,974,102;U.S. Pat. 4,000,207

  50. R.L. Moss and L. Whalley,Adv. Catal., 1972,22, 115–189

    Article  CAS  Google Scholar 

  51. J.K.A. Clarke and E.A. Rafter,Z. Phys. Chem. Neue Folge, 1969,67, 169–177

    CAS  Google Scholar 

  52. D.D. Eley and D.M. Macmahon,J. Colloid Interface Sci., 1972,38, 502–510

    Article  CAS  Google Scholar 

  53. I.A. Zubovich,Zhur. Fiz. Khim., 1955,29, 917–929

    CAS  Google Scholar 

  54. I.A. Zubovich,Zhur. Fiz. Khim., 1957,31, 61–71

    CAS  Google Scholar 

  55. K. Sennewald, W. Vogt, H. Erpenbach, H. Glaser, G. Roscher and W. Riemenschneider,Ger. Offen. 1 2 27 249 (1968)

    Google Scholar 

  56. Fr. Pat. 1,554,729 (1969)

  57. K. Sennewald, W.Vogt, H. Erpenbach and H. Glaser,S.Afr. Pat. 68 02,010(1968)

  58. K. Sennewald, W. Vogt, H. Erpenbach and H. Glaser,S.Afr. Pat. 68 02,015 (1968)

  59. K. Sennewald, W. Vogt, H. Glaser and H. Erpenbach,Ger. Offen. 1 3 01 306 (1969)

  60. W. Kroenig, G. Roscher, W. Schwerdtel and K. Sennewald,S.Afr. Pat. 67 06,730 (1968)

  61. W. Kioenig and G. Scharfe,Ger. Offen. 1 2 83 226 (1968)

  62. C.W. Capp,Fr. Pat. 1,566,124 (1969)

  63. Fr. Demande 2,004,036 (1969) 10

  64. K. Sennewald, W. Vogt, H. Glaser and H. Erpenbach, A. Ohorodnik and H. Joest,Ger. Offen. 1 8 04 347 (1970)

  65. National Distillers and Chemical Corp.,Ger. Offen. 1 9 44 933 (1970)

  66. T. Saito, M. Takano, S. Moriyama and H. Murayama,Japan. Kokai 73–49,711 (1973)

  67. S. Nakamura, T. Tsumura and T. Yasui,Japan. Kokai 73–71,387 (1973)

  68. G.M. Severs, Jr.,Ger. Offen. 2 3 61 098 (1974)

  69. O.D. Frampton,Ger. Offen. 2 5 11 364 (1975)

  70. S. Nakamura, Y. Fujiwara and T. Yasui,Ger. Offen. 2 5 38 863 (1976)

  71. S. Nakamura, Y. Fujiwara and T. Yasui,Ger. Offen. 2 5 28 363 (1976)

  72. K. Kawai, Y. Fujiwara and M. Nakamura,Japan. Kokai 77–04,490 (1977)

  73. G. Scharfe,Ger. Offen. 2 6 01 154 (1977)

  74. T.C. Bisset,U.S. Pat. 4,048,096(1977)

  75. L.A. Sokolova, N.M. Popova, V.K. Eritsyan, B.S. Mukanova, V.K. Boyadzhyan and S.S. Khachatryan,Izv. Akad. Nauk Kaz. S.S.R., Ser. Khim., 1978,28, 57–60

    CAS  Google Scholar 

  76. F.D. Miller,Fr. Pat. 1,556,524 (1969)

  77. A.G. Knapsack,U.K. Pat. 1 107 495(1968)

  78. S. Schott, D.W. Lum and I.L. Mador,Ger. Offen. 2 4 20 374 (1974)

  79. M. Boldt, H.J. Arpe and L. Hornig,U.S. Pat. 3,651,101

  80. M. Martin, G. Scharfe and W. Swodenk,Ger. Offen. 2 1 07 913

  81. W. Vogt, H. Glaser and K. Sennewald,Ger. Offen. 1945 528 (1971)

  82. F. Wunder,Ger. Offen. 1 9 57 680 (1971)

  83. K. Sennewald, H. Erpenbach, W. Vogt and H. Joest,Ger. Offen. 1 2 70 543

  84. J.H. Murib,U.S. Pat. 4,107,204 (1978)

  85. G. Scharfe, J. Grolig, M. Martin, W. Swodenk and W. Dornfeldt,Ger. Offen. 19 59 780 (1971)

    Google Scholar 

  86. D. Freudenberger, F. Wunder and H. Fernholz,Ger. Offen. 2 5 53 761 (1977)

  87. D. Freudenberger and F. Wunder,Ger. Offen. 2 7 15 667 (1978)

  88. J. Petro, T. Mathe, S. Szoke, G. Lugosi and L. Feuer,Fr. Demande 2,232,539 (1975)

  89. I.A. Zubovitch,Zhur. Fiz. Khim., 1955,29, 1696–1705

    Google Scholar 

  90. I.A. Zubovitch,Zhur. Fix. Khim., 1957,31, 589–598

    Google Scholar 

  91. J.A. Scheben and I.L Mador, in ‘5th Conf. Catal. Org. Synth.’, 1975, pp. 181–201, edited by P.N. Rylander and H. Greenfield, Academic Press, New York, 1976

    Google Scholar 

  92. R.F. Vines, ‘The Platinum Metals and their Alloys’, The International Nickel Company, Inc., New York, 1941

    Google Scholar 

  93. M. Hansen and K. Anderko, ‘Constitution of Binary Alloys’, 2nd ed., McGraw Hill, New York, 1958

    Google Scholar 

  94. J.K.A. Clarke, I. Manninger and T. Baird,J. Catal., 1978,54, 230–242

    Article  CAS  Google Scholar 

  95. F.J. Kuijers, R.P. Dessing and W.M.H. Sachtler,J. Catal., 1974,33, 316–321

    Article  CAS  Google Scholar 

  96. H.C. DeJongste, F.J. Kuijers and V. Ponec, in ‘Preparation of Catalysts’, edited by B. Delmon, P.A. Jacobs and G. Poncelet, Elsevier, Amsterdam/New York, 1976, p. 207

    Google Scholar 

  97. S.M. Kulifay,J. Amer. Chem. Soc., 1961,82, 4916

    Article  Google Scholar 

  98. R.S. Miner, Jr., S. Namba and J. Turkevich,Stud. Surf. Sci. Catal., 1981,7, (Pt.A. New Horiz. Catal.), 160–172

    Article  CAS  Google Scholar 

  99. J. Turkevich, R.S. Miner, Jr., I. Okura, S. Naraba and N. Zacharina, in ‘Perspect. Catal., (Pxoc. 12th Swed. Symp. Catal.)’, 1979 (Pub. 1981), pp. 111–122

  100. S. Galvagno and G. Parravano,J. Catal., 1979,57, 272–286

    Article  CAS  Google Scholar 

  101. P.R. Norton, R.L Tapping and J.W. Goodale,J. Vac. Sci. Technol., 1977,14, 446–451

    Article  CAS  Google Scholar 

  102. K.M. Sancier and S.H. Inami,J. Catal., 1968,11, 135

    Article  CAS  Google Scholar 

  103. J.A. Schwan, R.S. Polizotti and J.J. Burton,J. Vac. Sci. Technol., 1977,14, 457

    Article  Google Scholar 

  104. D.S. Wang, A.J. Freeman and H. Krakauer,Phys. Rev. B: Condens. Matter, 1984,29, 1665–1673

    Article  CAS  Google Scholar 

  105. P. Biloen, R. Bouwman, R. A. VanSanten and H.H. Brongersma, in ‘Proceedings 7th International Vacuum Congress, and 3rd International Conference on Solid Surfaces’, edited by Dobrozemskyet al. Vienna 1977, Vol. 2, p. 1401

  106. J.R. Anderson, K. Foger and R.J. Breakspere,J. Catal., 1979,57, 458–475

    Article  CAS  Google Scholar 

  107. J.R. Anderson and R.J. Breakspere, in ‘Proceedings 7th International Vacuum Congress, and 3rd International Conference on Solid Surfaces’, edited by Dobrozemskyet al, Vienna 1977, Vol. 1, pp. 823–826

  108. R. Bouwman and W.M.H. Sachtler,J. Catal., 1970,19, 127–140

    Article  CAS  Google Scholar 

  109. D.W. Budworth, F.E. Hoare and J. Preston,Proc. Roy. Soc., 1960,257, 250

    Article  CAS  Google Scholar 

  110. A.S. Darling, P.A. Mintern and J.C. Chaston,J. Inst. Met., 1952,81, 125

    CAS  Google Scholar 

  111. G.H. Johansson and I.O. Linde,Ann. Phys., 1930,5, 762

    Article  CAS  Google Scholar 

  112. J.J. Stephan, V. Ponec and W.M.H. Sachtler,Surface Sci., 1975,47, 403

    Article  CAS  Google Scholar 

  113. K. Rager and J.R. Anderson,Appl. Surf. Sci., 1979,2, 335–351

    Article  Google Scholar 

  114. H.C. DeJongste and V. PonecJ. Catal., 1980,64, 228–231

    Article  CAS  Google Scholar 

  115. J.J. Stephan and V. Ponec,J. Catal., 1976,42, 1–9

    Article  CAS  Google Scholar 

  116. R.P. Dessing and V. Ponec,J. Catal., 1976,44, 494–497

    Article  CAS  Google Scholar 

  117. J.W.A. Sachtler,Preprints, A.C.S. Div. Petrol. Chem., 1983,28, 491–503

    CAS  Google Scholar 

  118. J.R.H. van Schaik, R.P. Dessing and V. Ponec,J. Catal., 1975,38, 273–282

    Article  Google Scholar 

  119. J.K.A. Clarke, A.F. Kane and T. Baird,J. Catal., 1980,64, 200–212

    Article  CAS  Google Scholar 

  120. R.P. Dessing and V. Ponec,Reaction Kinet. Catal. Lett., 1976,5, 251

    Article  CAS  Google Scholar 

  121. K. Foger and J.R. Anderson,J. Catal., 1980,61, 140–145

    Article  CAS  Google Scholar 

  122. R.P. Dessing, V. Ponec and W.M.H. Sachtler.J. Chem. Soc., Chem. Commun., 1972, (15), 880–881

  123. D.I. Hagen and G.A. Somorjai,J. Catal., 1976,41, 466–481

    Article  CAS  Google Scholar 

  124. J.W.A. Sachtler, M.A. Van Hove, J.P. Bibérian and G.A. Somorjai,Phys. Rev. Lett., 1980,45, 1601–1603

    Article  CAS  Google Scholar 

  125. A.A. Alchudzan and M.A. Indzhikyan,Zhur. Fiz. Khim., 1959,33, 983–987

    Google Scholar 

  126. P. Biloen, F.M. Dautzenberg and W.M.H. Sachtler,J. Catal., 1977,50, 77–86

    Article  CAS  Google Scholar 

  127. S. Galvagno and G. Parravano,Ber. Bunsenges. Phys. Chem., 1979,83, 894–899

    CAS  Google Scholar 

  128. L. Guczl,J. Molec. Catal., 1984,25, 13–29

    Article  Google Scholar 

  129. A. Van der Burg, J. Doornbos, N.J. Kos, W.J. Ultee and V. Ponec,J. Catal., 1978,54, 243–253

    Article  Google Scholar 

  130. A.A. Rudnitskii and O.A. Novikova,Russ. J. Inorg. Chem., 1959,4, 722

    Google Scholar 

  131. J. Schwank, G. Parravano and H.L Gruber,J. Catal., 1980,61, 19–28

    Article  CAS  Google Scholar 

  132. S. Galvagno, J. Schwank and G. Parravano,J. Catal., 1980,61, 223–231

    Article  CAS  Google Scholar 

  133. I.W. Bassi, F. Garbassi, G. Vlaic, A. Marzi, G.R. Tauszik, G. Cocco, S. Galvagno and G. Parravano,J. Catal., 1980,64, 405–416

    Article  CAS  Google Scholar 

  134. G.R. Tauszik, F. Garbassi and A. Marzi,Gazz. Chim. Ital., 1980,110, 443–448

    CAS  Google Scholar 

  135. S. Galvagno, J. Schwank, G. Parravano, F. Garbassi, A. Marziand, G.R. Tauszik,J. Catal., 1981,69, 283–291

    Article  CAS  Google Scholar 

  136. G. Leofanti, M. Solari, G.R. Tauszik, F. Garbassi, S. Galvagno and J. Schwank,Appl. Catal., 1982,3, 131–139

    Article  CAS  Google Scholar 

  137. G.R. Tauszik, G. Leofanti and S. Galvagno,J. Molec. Catal., 1984,25, 357–366

    Article  CAS  Google Scholar 

  138. A.K. Datye and J. Schwank, in ‘Proc., 8th Inter. Congress on Catalysis’, Berlin (West), Vol. 4, pp. 587–598, Verlag Chemie, Weinheim, West Germany, 1984

    Google Scholar 

  139. A.K. Datye, Ph.D. Thesis, The University of Michigan, 1984

  140. J.W.A. Sachtler and G.A. Somorjai,J. Catal., 1983,81, 77–94

    Article  CAS  Google Scholar 

  141. J.W.A. Sachtler and G.A. Somorjai,J. Catal., 1984,89, 35–43

    Article  CAS  Google Scholar 

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    Johannes Schwank

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Schwank, J. Gold in bimetallic catalysts. Gold Bull 18, 2–10 (1985). https://doi.org/10.1007/BF03214680

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