Skip to main content
Log in

Pb and Co removal from paint industries effluent using wood ash

  • Published:
International Journal of Environmental Science & Technology Aims and scope Submit manuscript

Abstract

The release of heavy metals into the environment is a worldwide major concern. Different studies have demonstrated that natural agents have a high removal capacity for divalent heavy metal ions. Wood ash is a natural adsorbent and, in comparison with others, has a very low price. In this study, the removal of heavy metals (Pb and Co) from Binalood paint industry (Kerman, Iran) effluent was investigated in batch condition. Pb and Co measurement in samples were done with atomic absorption equipment and test methods were adapted from standard methods for the examination of water and wastewater. The effect of pH and the amount of adsorbent was determined and different adsorption isotherms were also obtained. This study shows that the adsorption process follows the adsorption Langmuir isotherm. The amount of wood ash has a great role in the adsorption rate and adsorption rate increased as wood ash increased. In the study, the reactions reached equilibrium in 3 h contact time. The maximum Pb removal efficiency was 96.1 % at pH 2 with a contact time of 3 h and 100 g/L wood ash and the maximum Co removal efficiency was 99 % at pH 2 with a contact time of 3 h and 100 g/L wood ash. According to the results, wood ash is recommended as a low cost and available adsorbent to remove Pb and Co from municipal and industrial wastewaters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Abdus-salam, N.; Adekola, F. A., (2005). The influence of pH and adsorbent concentration on adsorption of lead and zinc on a natural goethite. Afr. J. Sci. Tech., 6, 55–66.

    Google Scholar 

  • Abraham, L., (1982). American standard theoretical. New York, USA, McGraw-Hill.

    Google Scholar 

  • Ahalya, N.; Kanamadi, R. D.; Ramachandra, T. V., (2005). Biosorption of chromium (VI) from aqueous solutions by the husks of Bengal gram (Cicer arientinum). Ele. J. Biotech., 8, 258–264.

    Article  CAS  Google Scholar 

  • Alessia, S. M.; Ferrini, V., (2007). Cadmium removal from single and multi-metal solutions by sorption on hydroxyapatite. J. Colloid Interf. Sci., 317(2), 402–408.

    Google Scholar 

  • Amuda, O. S.; Alade, A., (2006). Coagulation/flocculation process in the treatment of abattoir wastewater. Desalination. 796, 22–31.

    Article  Google Scholar 

  • Amuda, O. S.; Amoo, I. A., (2006). Coagulation/flocculation process and sludge conditioning in beverage industrial wastewater treatment. J. Hazard. Mater. 747, 778–783.

    Google Scholar 

  • Amuda, O. S., Amoo, I. A.; Ajayi, O. O., (2006). Performance optimization of coagulation/flocculation process in the treatment of beverage industrial wastewater. J. Hazard. Mater. 129(1–3), 69–72.

    Article  CAS  Google Scholar 

  • Ayers, R. S.; Westcot, D. W., (1994). Water quality for agriculture. Rome, Italy, Food and Agriculture Organization of the United Nations Rome, FAO.

    Google Scholar 

  • Babel, S.; Kuraniwan, T. A., (2003). Low-cost adsorbents for heavy metals uptake from contaminated water. J. Hazard. Mater. B97(1), 219–243.

    Article  Google Scholar 

  • Brown, P. A.; Gill, S. A.; Allen, S. J., (2000). Metal Removal from wastewater using Peat. Water Res., 34(16), 3907–3916.

    Article  CAS  Google Scholar 

  • Chuah, T. G.; Jumasiah, A.; Azni, I.; Katayon, S.; Thomas Choong, S. Y., (2005). Rice husk as a potentially low-cost biosorbent for heavy metal and dye removal. Desalination, 175(3), 305–316.

    Article  CAS  Google Scholar 

  • Clark, P., (1972). Water analysis with atomic absorbtion. USA, Variani Techtron B, stuander Company.

    Google Scholar 

  • Dasa, B.; Hazarika, P.; Sailika, G.; Kalita, H.; Goswami, D. C.; Das, H. B..; Dube, S. N. & Dutta, R.K.,(2006) Removal of iron from groundwater by ash: A systematic study of a traditional method. J. Hazard. Mater., 141(3), 834–841.

    Article  Google Scholar 

  • Dastjerdi, V. M.; Shanbezade, S.; Zahabsaniei, A., (2003). Investigation of heavy metal concentration of Gavkhooni wetland and their ecological effects. Proceeding of 6th. national congress on environmental health. yazd, Iran Publication of Mazandaran University of Medical Sciences.

    Google Scholar 

  • Davis, J. B., (1973). Statistic and data analysis in geology. New York: Wiley International. 456–473.

    Google Scholar 

  • Eaton, A.; Closceril.; Greanberg, A., (1998). Standard Methods for the Examination of Water and Wastewater. USA, APHA, AWWA, WEF.

    Google Scholar 

  • Erdem, E.; Karapinar, N.; Donat, R., (2004). The removal of heavy metal cations by natural zeolites. Colloid Interf. Sci. 280(2), 309–314.

    Article  CAS  Google Scholar 

  • Gabriel, B., (1979). Extended abstracts of the international conference of the heavy metals in the environment. Canada, National research D.C. Health Company.

    Google Scholar 

  • Ganji, M.; Khosravi, M.; Rakhshaei, R., (2005). Biosorption of Pb, Cd, Cu and Zn from the wastewater by treated Azolla filiculides with H2O2/MgCl2. Int. J. Environ. Sci. Tech., 1(4), 265–271.

    Article  CAS  Google Scholar 

  • Georg Steinhauser, M. B., (2008). Adsorption of ions onto high silica volcanic glass. Appl. Rad. Iso., 66(1), 1–8.

    Article  Google Scholar 

  • Guo, X.; Zhang, S.; Shan, X. Q., (2008). Adsorption of metal ions on lignin. J. Hazard. Mater. 151(1), 134–142.

    Article  CAS  Google Scholar 

  • Hanzlik, J.; Jehlicka, J.; Sebek, O.; Weishauptova, Z.; Machovic, V., (2004) Multi-component adsorption of Ag(I), Cd(II) and Cu(II) by natural carbonaceous materials. Water Res. 38(8), 2178–2184.

    Article  CAS  Google Scholar 

  • Howard, H.; D, M.;H, M. P. & D, S.,(2002). Human Health and Heavy Meatals Exposure. MIT Publication.

  • Inglezaki, V. J.; Stylianou, M. A.; Gkantzou, D.; Loizidou, M. D., (2007). Removal of Pb(II) from aqueous solutions by using clinoptilolite and bentonite as adsorbents. Desalination. 210, 248–256.

    Article  Google Scholar 

  • ISIRI (1999). Physical and chemical characteristics of water and wastewater effluent. Industrial Standards Institute of Research of Iran, Standard. IN NO.1053 (Ed.) 1–5. Tehran. Iran.

  • Juang, R. S.; Shiau, R. C., (2000). Metal removal from aqueous solutions using chitosan-enhanced membrane filtrations. J. Membane. Sci. 765:159–167.

    Article  Google Scholar 

  • Lai, C. L.; Lin, S. H., (2003). Electrocoagulation of chemical mechanical polishing (CMP) wastewater from semiconductor fabrication. Chem. Eng., 95(1), 205–211.

    CAS  Google Scholar 

  • Matos, G. D.; Arruda, M. A. Z., (2003). Vermicompost as natural adsorbent for removing metal ions from laboratory effluents. Process Biochem. 39(1), 81–88.

    Article  CAS  Google Scholar 

  • Naseem, R.; Tahir, S. S., (2001) Removal of Pb(II) from Aqueous/Acidic Solutions by using Bentonite as an Adsorbent. Water Res. 35(16), 3982–3986.

    Article  CAS  Google Scholar 

  • Needlemana, H. L.; Bellingerc, D., (2001) Studies of lead exposure and the developing central nervous system: a reply to Kaufman. Arch. Clin. Neuropsych., 16(4), 359–374.

    Google Scholar 

  • Nergo, G., (1993). Organochlorine and heavy metal contamination in non-viable egges and it relation breeding succes. New York, USA, Park Ridge company.

    Google Scholar 

  • Quek, S. Y.; Wase, D. A. J.; Forster, C. F., (1998). The use of Sago Waste for the Sorption of lead and Copper. Water SA, July 24(3), 251–256.

    CAS  Google Scholar 

  • Reviewed by Staff and Experts in the Programme of Chemical Safety (PCS), A. W., Sanitation and Health Unit (WSH), World Health Organization (WHO), GENEVA., (2001) Water-related Diseases., Geneva.

  • Sirichote, O.; Innajitara, W.; Chuenchom, L; Chunchit, D; Naweekan, K., (2002). Adsorption of iron (III) ion on activated carbons obtained from bagasse, pericarp of rubber fruit and coconut shell. Songklanakarin J. Sci. Tech. 24, 235–242.

    CAS  Google Scholar 

  • Viraraghvan, T.; Dronamraju, M. M., (1993). Removal of copper, nickel and zinc from wastewater by adsorption using peat, J. Environ. Sci. Health A: Environ. Sci. Eng. 28, 1261–1276.

    Article  Google Scholar 

  • Viraraghvan, T.; Rao, G. A. K., (1991) Adsorption of Cadmium and Chromium from wastewater by Fly Ash. Environ. Sci. Health, A 26(5), 721–753. 217–222.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Almasi Ph.D..

Rights and permissions

Reprints and permissions

About this article

Cite this article

Malakootian, M., Almasi, A. & Hossaini, H. Pb and Co removal from paint industries effluent using wood ash. Int. J. Environ. Sci. Technol. 5, 217–222 (2008). https://doi.org/10.1007/BF03326015

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03326015

Keywords

Navigation