Skip to main content
Log in

The Si-Zr (Silicon-Zirconium) system

  • Published:
Journal of Phase Equilibria

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Cited references

  1. E. Wedekind, “Reduction of Zirconium Earth,”Ber. Dtsch. Chem. Ges., 35, 3929–3932 (1902) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  2. O. Honigschmid, “Zirconium Silicide ZrSi2 and Titanium Silicide TiSi2,”Compt. Rend., 143, 224–226 (1906) in French;Monatsh. Chem., 27, 1069 (1907) in German. (Equi Diagram; Experimental)

    Google Scholar 

  3. L. Baraduc-Muller, “Metallic Silicides. The Action of Silicon Carbide on some Metallic Oxides,”Rev. Metall., 7, 657–834 (1910) in French. (Equi Diagram; Review)

    Google Scholar 

  4. E. Wedekind, “Colloid of Zirconium Silicide,”Z. Chem. Ind. Kolloide, 7(5), 249–251 (1910) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  5. H. Seyfarth, “The Structure of Zirconium Silicide,”Z. Krist., 67, 295–328 (1928) in German. (Crys Structure; Experimental)

    Google Scholar 

  6. I. Naray-Szabo, “The Structure of Zirconium Silicide, ZrSi2,”Z. Krist, A97, 223–228 (1937). (Crys Structure; Experimental)

    Google Scholar 

  7. G. Brauer and A. Mitius, “The Crystal Structure of ThSi2,”Z. Anorg. Chem., 249, 325–339 (1942) in German. (Crys Structure; Experimental)

    Article  Google Scholar 

  8. S.M. Shelton, “Zirconium Alloys for High-Temperature Service,” USAEC, AF-TR-5932 (1949);Met. Abstr., 21, 869 (1954). (Equi Diagram; Experimental)

  9. C.T. Anderson, E.T. Hayes, A.H. Roberson, and W.J. Kroll, “A Preliminary Survey of Zirconium Alloys,” U.S. Bur. Mines, Rep. Invest. 4658, 48 p (1950). (Equi Diagram; Experimental)

  10. W.R. Johnson and M. Hansen, “An Appraisal of Silicon and Its Alloys,” USAF Tech. Rep. 6383 (1951);Met. Prog., 63(2), 105–109 (1953). (Equi Diagram; Experimental)

  11. A.H. Roberson and E.T. Hayes, discussion,Trans. ASM, 44, 536 (1952). (Equi Diagram; Experimental)

    Google Scholar 

  12. C.E. Lundin, D.J. McPherson, and M. Hansen, “The System Zirconium-Silicon,”Trans. ASM, 45, 901–914 (1953). (Equi Diagram, Crys Structure; Experimental; #)

    Google Scholar 

  13. H. Schachner, H. Nowotny, and R. Machenschalk, “Constitution of the System Zirconium-Silicon,”Monatsh. Chem., 84(4); 677–685 (1953) in German. (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  14. L. Brewer and O. Krikorian, USAEC, UCRL-2544 (1954). (Equi Diagram, Crys Structure; Experimental)

  15. R. Kieffer, F. Benesovsky, and R. Machenschalk, “Contribution to the System Zirconium-Silicon and on Some Mixed Silicide Systems,”Z. Metallkd., 45(8), 493–498 (1954) in German. (Equi Diagram, Crys Structure; Experimental;*)

    Google Scholar 

  16. P. Pietrokowsky, “The Intermediate Phase Zr2Si,”Acta Crystallogr., 7, 435–438 (1954). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  17. H. Schachner, H. Nowotny, and H. Kudielka, “The Crystal Structure of ZrSi and ZrSi2,”Monatsh. Chem., 85(5), 1140–1153 (1954) in German. (Crys Structure; Experimental)

    Article  Google Scholar 

  18. AG. Knapton, “The System Niobium-Silicon and the Effect of Carbon on the Structure of Certain Silicides,”Nature, 175, 730 (1955). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  19. D.A. Robins and I. Jenkins, “The Heat of Formation of Some Transition Metal Silicides,”Acta Metall., 3(11), 598–604 (1955). (Thermo; Experimental)

    Article  Google Scholar 

  20. PA Vaughan and A Bracuti, abstract of paper presented at meeting of the American Crystallographic Association, Pasadena, CA (1955); cited in [57Dau]. (Crys Structure; Experimental)

  21. L. Brewer and O. Krikorian, “Reactions of Refractory Silicides with Carbon and Nitrogen,”J. Electrochem. Soc., 103, 38–51 (1956). (Equi Diagram; Experimental)

    Article  Google Scholar 

  22. P.G. Cotter, J.A. Kohn, and RA Potter, “Physical and X-Ray Study of the Disilicides of Titanium, Zirconium, and Hafnium,”J. Am. Ceram. Soc., 39(1), 11–12 (1956). (Crys Structure; Experimental)

    Article  Google Scholar 

  23. H. Nowotny, B. Lux, and H. Kudielka, “The Properties of Metallic High-Melting Silicides of Boron, Carbon, Nitrogen, and Sulfur,”Monatsh. Chem., 87(3), 447–470 (1956). (Crys Structure; Experimental)

    Article  Google Scholar 

  24. C.H. Dauben, “Crystal Structures of Transition Metal Silicides,”J. Electrochem. Soc., 104(8), 521–523 (1957). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  25. E. Parthe, “Contributions to Nowotny Phases,”Powder Metall. Bull., 8, 23–24 (1957). (Equi Diagram; Experimental)

    Google Scholar 

  26. A.J.J. Bracuti, The Crystal Structure of ZrSi2:The Crystal Structure of ZrS2:The Crystal Structure of Zr1+XSi2:The Unit-Cell Determination of Piezotite,” Ph.D. thesis, Rutgers Univ., (1958);Dissertation Abstr., 19, 1217 (1958). (Crys Structure; Experimental)

  27. B. Aronsson, “Borides and Silicides of the Transition Metals,”Ark. Kem., 16, 379–423 (1960). (Equi Diagram; Theory)

    Google Scholar 

  28. M.S. Farkas, AA Bauer, and R.F. Dickerson, “The Solid-State Constitution of High-Uranium Alloys of the Uranium-Zirconium-Silicon System,”Trans. ASM., 53 511–521 (1961). (Equi Diagram; Experimental)

    Google Scholar 

  29. O. Schob, H. Nowotny, and F. Benesovsky, “Structure Determination of Some Phases in the Systems: Zr-Al-Si and Hf-Al-Si {ZrAl3(Si); ZrSi(Al); Hf(Si,Al); Zr3Si2; Hf3Si2},”Monatsh. Chem., 92(6), 1218–1226 (1961) in German. (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  30. S.V. Ermakov and B.M. Tsarev, “Thermoelectric Emission of Metal Silicides from the Transition Groups of the Periodic System of Elements,”Radiotekh. Elektron., 7, 2101–2104 (1962) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

  31. O. Schob, H. Nowotny, and F. Benesovsky, “The Ternary System (Titanium, Zirconium, Hafnium)-Aluminum-Silicon,”Planseeber. Pulvermetall., 10, 65–71 (1962) in German. (Equi Diagram; Experimental)

    Google Scholar 

  32. O.G. Karpinskii and B.A Evseev, “Crystal Structure of Zr5Si3,”Issled. Stalei Splavov, Akad. Nauk SSSR, Gos. Kom. Chern. Tsvetn. Met. Gosplane SSSR, Inst. Met., 54–56 (1964) in Russian;Chem. Abstr. 62, 4717–4718 (1965). (Crys Structure; Experimental)

  33. K Schubert, A Raman, and W. Rossteutscher, “Some Structure Data of Metallic Phases (11),”Naturwissenschaften, 51 (24), 506–507 (1964) in German. (Equi Diagram, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  34. Yu.M. Golutvin and E.G. Maslennikova, “Heats of Formation of Zr Silicides,”Zh. Fiz. Khim., 39(12), 3102–3105 (1965) in Russian; TR:Runs. J. Phys. Chem., 39(12), 1660–1662 (1965). (Thermo; Experimental)

    Google Scholar 

  35. O.G. Karpinskii and B A Evseev, “Crystal Structure of ZrSi,”Izv. Akad. Nauk SSSR, Neorg. Mater., 1(3), 337–339 (1965) in Russian; TR:Inorg. Mater, (USSR), 2(3), 312–314 (1965). (Crys Structure; Experimental)

    Google Scholar 

  36. A. Raman and K. Schubert, “Investigations in Some T-Al-Si and T4…6-In Systems,”Z. Metallkd., 56(1), 44–52 (1965) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  37. W. Rossteutscher and K. Schubert, “Structural Investigations in Some T4…5-B4…5 Systems,”Z. Metallkd., 56(11), 813–822 (1965) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  38. C.E. Brukl, “Ternary Phase Equilibria in Transition Metal-Boron-Carbon-Silicon Systems. Binary Systems. The Zr-Si and Hf-Si Systems,” Tech. Rep. AFML-TR-65-2, Part 2, Vol.X, Wright-Patterson Air Force Base, OH (1966). (Crys Structure; Experimental)

  39. O.G. Karpinskii and B.A. Evseev, “The Crystal Structure of the Compound Zr5Si4,”Acta Crystallogr., 21, Suppl. 7, A82-A83 (1966). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  40. H.U. Pfeifer and K. Schubert, “Crystal Structure of Zr5Si4,”Z. Metallkd., 57(12), 884–888 (1966) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  41. A.V.Tkachenko, “Conditions for Producing Zr Silicide Phases,” Trudy Nauchnoi Konferentsii Aspirantov Instituta Problem Materialovedeniya, Akad. Nauk Ukr. SSR: Proc. Conf., 1st, (1967), G.A Yasinskaya, Ed., Izd. Naukova Dumka, 3–10 (1968) in Russian. (Equi Diagram; Experimental)

  42. C.E. Brukl, “Ternary Phase Equilibria in Transition Metal-Boron-Carbon-Silicon Systems, Part 1. Binary Systems. Vol. XIII. The Zirconium-Silicon and HafniumSilicon Systems,” Tech. Rep. AFML-TR-65-2, Wright-Patterson Air Force Base, OH (1968). (Equi Diagram, Crys Structure; Experimental; #)

  43. Yu.M. Golutvin and E.G. Maslennikova, “The Thermochemistry of the Zirconium-Silicon System,”Izv. Akad. Nauk SSSR, Met., (2), 193–207 (1968) in Russian; TR:Russ. Metall., (2), 129–136 (1968). (Thermo; Experimental)

  44. AV. Tkachenko and T.Ya. Kosolapova, “The Conditions for Obtaining Zr Silicides,”Poroshk. Metall., 8(3), 23–27 (1968) in Russian; TR:Sov. Powder Metall. Met. Ceram., 8(3), 178–181 (1968). (Crys Structure; Experimental)

    Google Scholar 

  45. E. Rudy, “Ternary Phase Equilibria in Transition Metal-Boron-Carbon-Silicon Systems. Part V. Compendium of Phase Diagram Data,” Tech. Rep. AFML-TR-65-2, Part V, Wright-Patterson Air Force Base, OH (1969). (Equi Diagram; Compilation; #)

  46. E.E. Havinga, H. Damsma, and P. Hokkeling, “Compounds and Pseudo-Binary Alloys with the CuAl2(Cl6)-Type Structure,”J. Less-Common Met., 27, 169–186 (1972). (Crys Structure; Compilation)

    Article  Google Scholar 

  47. A.S. Bolgar, AG. Turganin, and V.V. Fesenko,Thermodynamic Properties of Carbides, Naukova Dumka, Kiev, USSR (1973) in Russian. (Thermo; Eperimental)

    Google Scholar 

  48. YuA Kocherzhinskii and O.G. Kulik, “Phase Equilibria in Alloys of Silicon with Zirconium and Molybdenum,” Tezisy Dokl. Vses. Konf. Kristallokhim. Intermet. Soedin., 2nd, R.M. Rykhal, Ed., 154–155 (1974) in Russian. (Equi Diagram; Experimental)

  49. C.B. Alcock, K.T. Jacob, S. Zador, O. von Goldbeck, H. Nowotny, K. Seifert, and O. Kubaschewski,Zirconium: Physico-Chemical Properties of Its Compounds and Alloys, O. Kubaschewski, Ed., Atomic Energy Review, Special Issue No. 6, IAEA, Vienna (1976). (Equi Diagram; Review)

    Google Scholar 

  50. Yu.A. Kocherzhinskii, O.G. Kulik, and E.A Shiskin, “Phase Diagram of the Zr-Si System,”Akad. Nauk Ukr. SSR, Metallofiz., 64, 48–52 (1976) in Russian. (Equi Diagram, Crys Structure; Experimental; #)

    Google Scholar 

  51. V.M. Maslov, AS. Neganov, I.P. Borovinskaya, and AG. Merzhanov, “Self-Propagating High-Temperature Synthesis as a Method for Determination of the Heat of Formation of Refractory Compounds,”Fiz. Goreniya Vzryva, 14(6), 73–82 (1978) in Russian; TR:Combust. Explos. Shock Waves, 14(6), 759–767 (1979) (Crys Structure, Thermo; Experimental)

    Google Scholar 

  52. Yu.D. Seropegin, LA Panteleimonov, I.A Guseva, and L.V. Osipova, “Study of Zirconium-Silicon System Alloys,”Vestn. Mosk. Univ., Khim., 21(4), 400 (1980) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

  53. L.K. Savitskaya, L.S. Derevyagina, L.M. Butkevich, and T.N. Safonova, “X-Ray Study of Fine Structure of Si-ZrSi2 Eutectic Obtained by Oriented Crystallization,”Izv. Akad. Nauk SSSR, Neorg. Mater., 18(7), 1143–1147 (1982) in Russian; TR:Russ. J. Inorg. Mater, 18(7), 965–968 (1982). (Crys Structure; Experimental)

    Google Scholar 

  54. J.H. Maas, G.F. Bastin, F.J.J. Van Loo, and R. Metselaar, “On the Texture in Diffusion-Grown Layers of Silicides and Germanides with the FeB Structure,MeX(Me = Ti, Zr;X = Si, Ge) or the ZrSi2 Structure (ZrSi2, HfSi2, ZrGe2),”J. Appl. Crystallogr., 17(2), 103–110 (1984). (Crys Structure; Experimental)

    Article  Google Scholar 

  55. V.N. Safonov, P.V. Gel’d, N.I. Sychev, and G.I. Kalishevich, “Thermodynamic Characteristics of the Compounds M5X3 (M=Y, Zr; Z= Si, Ge),”ZA. Fiz. Khim., 59(9), 2141–2144 (1985) in Russian; TR:Russ. J. Phys. Chem., 59(9), 1273–1275 (1985). (Crys Structure, Thermo; Experimental)

    Google Scholar 

  56. V.S. Sudavtsova, G.I. Batalin, and VS. Tutevich, “Thermodynamic Properties of Alloys of the Si-Ti(Zr) Systems,”Izv. Akad. Nauk SSSR, Neorg. Mater., 21(5), 779–782 (1985) in Russian;TR: Inorg. Mater. (USSR), 21(5), 676–679 (1985). (Thermo; Experimental)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This work was supported by ASM International. Literature searched through early 1987. Dr. Okamoto is the ASM/NIST Data Program Category Editor for miscellaneous binary alloys.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Okamoto, H. The Si-Zr (Silicon-Zirconium) system. Bulletin of Alloy Phase Diagrams 11, 513–519 (1990). https://doi.org/10.1007/BF02898272

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02898272

Keywords

Navigation