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Sources and Assessment of Mercury and Other Heavy Metal Contamination in Soils Surrounding the Wuda Underground Coal Fire Area, Inner Mongolia, China

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Abstract

Concentrations of mercury and other heavy metals were measured in soils surrounding the Wuda Coalfield, Inner Mongolia where underground coal fires are regarded as an important contamination source. Soil samples at the downwind direction were nearly all enriched mercury in surface layers, with their concentrations ~ 10 times higher than those from upwind soils. Mercury concentrations generally increased along soil profiles upward, indicative of increasing atmospheric mercury deposition in recent decades. We suggest that underground coal fire emissions were the potential mercury contamination source and the key factor controlling mercury enrichment in soils. Other heavy metals showed no clear spatial and vertical trends, suggesting that underground coal fire emissions may not the main factor for their enrichment in soils. Antimony showed the highest enrichment followed by tin, while chromium, mercury and cadmium only exhibited slight enrichment. Risk evaluation indicated that heavy metals in the studied soils pose no ecological threats.

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References

  • CNEMC (1990) China National Environmental Monitoring Center. Background concentrations of elements in soils of China. Beijing (in Chinese)

  • Dai S, Ren D, Chou C-L, Finkelman RB, Seredin VV, Zhou Y (2012) Geochemistry of trace elements in Chinese coals: a review of abundances, genetic types, impacts on human health, and industrial utilization. Int J Coal Geol 94:3–21

    Article  CAS  Google Scholar 

  • Frandsen F, Dam-Johansen K, Rasmussen P (1994) Trace elements from combustion and gasification of coal—an equilibrium approach. Prog Energy Combust Sci 20:115–138

    Article  CAS  Google Scholar 

  • GB/T-15618 (2018) Soil Environmental quality-risk control standard for soil contamination of agricultural land (in Chinese)

  • Hong X, Liang H, Lv S, Jia Y, Zhao T, Liang W (2017) Mercury emissions from dynamic monitoring holes of underground coal fires in the Wuda Coalfield, Inner Mongolia, China. Int J Coal Geol 181:78–86

    Article  CAS  Google Scholar 

  • Ketris MP, Yudovich YE (2009) Estimations of Clarkes for Carbonaceous biolithes: world averages for trace element contents in black shales and coals. Int J Coal Geol 78:135–148

    Article  CAS  Google Scholar 

  • Kuenzer C, Stracher GB (2012) Geomorphology of coal seam fires. Geomorphology 138:209–222

    Article  Google Scholar 

  • Kuenzer C, Zhang J, Tetzlaff A, van Dijk P, Voigt S, Mehl H, Wagner W (2007) Uncontrolled coal fires and their environmental impacts: investigating two arid mining regions in north-central China. Appl Geogr 27:42–62

    Article  Google Scholar 

  • Li C, Liang H, Chen Y, Bai J, Cui Y (2018a) Distribution of surface soil mercury of Wuda old mining area, Inner Mongolia, China. Hum Ecol Risk Assess 24:1421–1439

    Article  CAS  Google Scholar 

  • Li C, Liang H, Liang M, Chen Y, Zhou Y (2018b) Soil surface Hg emission flux in coalfield in Wuda, Inner Mongolia, China. Environ Sci Pollut Res 25:16652–16663

    Article  CAS  Google Scholar 

  • Liang Y, Liang H, Zhu S (2014) Mercury emission from coal seam fire at Wuda, Inner Mongolia, China. Atmos Environ 83:176–184

    Article  CAS  Google Scholar 

  • Liang Y, Zhu S, Liang H (2018) Mercury enrichment in coal fire sponge in Wuda coalfield, Inner Mongolia of China. Int J Coal Geol 192:51–55

    Article  CAS  Google Scholar 

  • Shan B, Wang G, Cao F, Wu D, Liang W, Sun R (2019) Mercury emission from underground coal fires in the mining goaf of the Wuda Coalfield, China. Ecotox Environ Safe 182:109409

    Article  CAS  Google Scholar 

  • Stracher GB (2004) Coal fires burning around the world: a Global Catastrophe. Int J Coal Geol 59:1–6

    Article  CAS  Google Scholar 

  • Stracher GB (2007) Coal fires burning around the world: opportunity for innovative and interdisciplinary research. GSA Today 17:36–37

    Article  Google Scholar 

  • Stracher GB, Taylor TP (2004) Coal fires burning out of control around the world: thermodynamic recipe for environmental catastrophe. Int J Coal Geol 59:7–17

    Article  CAS  Google Scholar 

  • Sun R, Enrico M, Heimbürger L-E, Scott C, Sonke JE (2013) A double-stage tube furnace—acid-trapping protocol for the pre-concentration of mercury from solid samples for isotopic analysis. Anal Bioanal Chem 405:6771–6781

    Article  CAS  Google Scholar 

  • Wang H, Dlugogorski BZ, Kennedy EM (2003) Coal oxidation at low temperatures: oxygen consumption, oxidation products, reaction mechanism and kinetic modelling. Prog Energy Combust Sci 29:487–513

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (41773104; 41602167) and the National Key Research and Development Plan (2017YFC0212700; 2016YFC0201600).

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Correspondence to Ruoyu Sun.

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Wang, G., Cao, F., Shan, B. et al. Sources and Assessment of Mercury and Other Heavy Metal Contamination in Soils Surrounding the Wuda Underground Coal Fire Area, Inner Mongolia, China. Bull Environ Contam Toxicol 103, 828–833 (2019). https://doi.org/10.1007/s00128-019-02734-7

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  • DOI: https://doi.org/10.1007/s00128-019-02734-7

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