Skip to main content
Log in

Three-step extraction procedure for determination of heavy metals availability to vegetables

  • Original Paper
  • Published:
Analytical and Bioanalytical Chemistry Aims and scope Submit manuscript

Abstract

A three-step sequential extraction procedure was used to determine the concentration of heavy metal speciation forms in soil. The procedure allows one to identify the pool of heavy metals that can be potentially mobilised under changes in soil pH value or redox potential. It has been shown that similar portions of heavy metals are present in reducible, oxidisable and residual fractions. It was found that soil chemical properties significantly affected the distribution of heavy metals among different fractions and their uptake by vegetables. Cadmium was a dominant element which occurred in the exchangeable fraction—the most bioavailable and potentially toxic.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Similar content being viewed by others

References

  1. Adriano DC (1986) Trace elements in the terrestrial environment. Springer, Berlin Heidelberg New York

    Google Scholar 

  2. Fergusson JE (1990) Chemistry of environmental impact and health effect. The heavy elements. Pergamon Press, Oxford

    Google Scholar 

  3. Vágó I, Györi Z, Loch J (1996) Fresenius J Anal Chem 354:714–717

    Google Scholar 

  4. Fytianos K, Katsianis G, Triantafyllou P, Zachariadis G (2001) Bull Environ Contam Toxicol 67:423–430

    CAS  PubMed  Google Scholar 

  5. Tlustoš P, Balik J, Pavlikova D, Szakova J (1997) Zesz Probl Post Nauk Roln 448b:325–331

    Google Scholar 

  6. Römkens PFAM, Bouwman LA, Boon GT (1999) Environ Pollut 106:315–321

    Article  PubMed  Google Scholar 

  7. Rauret G (1998) Talanta 46:449–455

    Article  CAS  Google Scholar 

  8. Singh SP, Tack FM, Verloo G (1998) Water Air Soil Pollut 102:313–328

    Article  CAS  Google Scholar 

  9. Cornelis R (2002) Anal Bioanal Chem 373:123–124

    Article  CAS  PubMed  Google Scholar 

  10. Tessier A, Campbell PGC, Bisson M (1979) Anal Chem 51:844–851

    CAS  Google Scholar 

  11. Davidson ChM, Ferreira PCS, Ure AM (1999) Fresenius J Anal Chem 363:446–451

    Article  CAS  Google Scholar 

  12. Davidson ChM, Duncan AL, Littlejohn D, Ure AM, Garden LM (1998) Anal Chim Acta 363:45–55

    Article  CAS  Google Scholar 

  13. Szàková J, Tlustoš P, Balik J, Pavlikova D, Vaněk V (1999) Fresenius J Anal Chem 363:594–395

    Article  Google Scholar 

  14. Wacławek W, Moćko A (2002) Chem Dydakt Ekol Metrol 7(1–2):99–102

    Google Scholar 

  15. Ostrowska A, Gawliński S, Szczubiałka Z (1991) Methods of analysis and assessment of soil and plant properties (in Polish). Katalog IOŚ, Warszawa

  16. Dąbkowska-Naskręt H (1997) Polish J Soil Science 30(2):29–33

    Google Scholar 

  17. Kabata-Pendias A, Pendias H (1999) Biogeochemistry of trace elements. PWN, Warszawa

    Google Scholar 

  18. Dziennik Ustaw (Polish Journal of Law) (2003) Nr 37 poz 326, 13 February 2003

  19. Stan środowiska w województwie Opolskim w roku 2003 (2004). In: Polish, report on state of environment in Opole Province in 2003, Poland. Bibl Monitor Środow, WIOŚ Opole

  20. Lipińska J (2000) ZN AP in Siedlce 57:151–158

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Agnieszka Moćko.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Moćko, A., Wacławek, W. Three-step extraction procedure for determination of heavy metals availability to vegetables. Anal Bioanal Chem 380, 813–817 (2004). https://doi.org/10.1007/s00216-004-2832-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00216-004-2832-6

Keywords

Navigation