Abstract
In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer season.
Similar content being viewed by others
References
Davis JC (1986) Statistics and data analysis in geology. 2nd edn. Wiley Inc, NY
Demirel Z (2004) The history and evaluation of saltwater intrusion into a coastal aquifer in Mersin, Turkey. J Environ Man 70:275–282
Güler C, Thyne G, McCray JE, Turner AK (2002) Evaluation of graphical and multivariate statistical methods for classification of water chemistry data. Hydrogeol J 10:455–474
Helena B, Pardo R, Vega M, Barrado E, Fernandez JM, Fernandez L (2000) Temporal evolution of ground water composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Res 34:807–816
Hidalgo MC, Cruz-Sanjulian J (2001) Ground water composition, hydrochemical evolution and mass transfer in a regional detrital aquifer (Baza basin, southern Spain). Appl Geochem 16:745–758
Judd AG (1980) The use of cluster analysis in the derivation of geotechnical classifications. Bull Assoc Eng Geol 17:193–211
Kaiser HF (1960) The application of electronic computers to factor analysis. Educ Psychol Meas 20:141–151
Kuells C, Adar EM, Udluft P (2000) Resolving patterns of ground water flow by inverse hydrochemical modeling in a semiarid Kalahari basin. Tracers Model Hydrogeol 262:447–451
Meng SX, Maynard JB (2001) Use of statistical analysis to formulate conceptual models of geochemical behavior: water chemical data from the Botucatu aquifer in São Paulo state, Brazil. J Hydrol 250:78–97
Ochsenküehn KM, Kontoyannakos J, Ochsenküehn PM (1997) A new approach to a hydrochemical study of ground water flow. J Hydrol 194:64–75
Parkhurst DL, Appelo CAJ (1999) User’s guide to PHREEQC (Version 2)–A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. USGS Water Res Invest Rep 99–4259
Plummer LN, Back WW (1980) The mass balance approach-application to interpreting the chemical evolution of hydrological systems. Am J Sci 280:130–142
Plummer LN, Parkhurst DL, Thorstenson DC (1983) Development of reaction models for ground-water systems. Geochim Cosmochim Acta 47:665–686
Pulido-Leboeuf P (2004) Seawater intrusion and associated processes in a small coastal complex aquifer (Castell de Ferro, Spain). Appl Geochem 19:1517–1527
Qian G, Gabor G, Gupta RP (1994) Principal components selection by the criterion of the minimum mean difference of complexity. J Multivariate Anal 49:55–75
Reeve AS, Siegel DI, Glaser PH (1996) Geochemical controls on peatland pore water from the Hudson Bay Lowland; a multivariate statistical approach. J Hydrol 181:285–304
Şenol M (1998) The geological investigation of Mersin region. General Directorate of Mineral Research and Exploration of Turkey, Ankara (in Turkish)
StatSoft Inc (1997) Electronic Statistics Textbook, Tulsa, OK http://www.statsoft.com/textbook/stathome.html
StatSoft Inc (2000) STATISTICA for Windows [Computer program manual]. Tulsa, OK
Swanson SK, Bahr JM, Schwar MT, Potter KW (2001) Two-way cluster analysis of geochemical data to constrain spring source waters. Chem Geol 179:73–91
Thomas JM, Welch AH, Preissler AM (1989) Geochemical evolution of ground water in Smith Creek Valley-a hydrologically closed basin in central Nevada, USA. Appl Geochem 4:493–510
Ward JH (1963) Hierarchical grouping to optimize an objective function. J Am Stat Assoc 69:236–244
Yaman S (1991) Mersin ofiyolitinin jeolojisi ve metallojenisi. Ahmet Acar Jeoloji Sempozyumu Bildirileri. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi: 255–268 (in Turkish)
Acknowledgments
The authors are pleased to acknowledge the cooperation and support of the General Directorate of Mineral Research and Exploration (MTA), Ankara, Turkey. The authors also thank MTA staff for their support with field operations and assistance with sample collection.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Demirel, Z., Güler, C. Hydrogeochemical evolution of groundwater in a Mediterranean coastal aquifer, Mersin-Erdemli basin (Turkey). Environ Geol 49, 477–487 (2006). https://doi.org/10.1007/s00254-005-0114-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00254-005-0114-z