Skip to main content
Log in

Investigation of the physical properties and gamma-ray shielding capability of borate glasses containing PbO, Al2O3 and Na2O

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Six glass samples of new lead borate with chemical formula 5Al2O3–5Na2O–(90-x)B2O3xPbO, where 0 ≤ x ≤ 50 mol% have been synthesized using the melt quenching technique. The prepared glasses distinguished by codes as x = 0 (ANBP00)—x = 50 (ANBP50) mol%. The physical properties and gamma-ray shielding capability of the glasses have been investigated. To achieve these aims, the amorphous structure of all glasses was examined using X-ray diffraction (XRD) measurements. The density and molar volume have been calculated. Density of the glasses increases from 2.133 (g/cm3) for ANBP00 glass sample to 5.010 (g/cm3) for ANBP50 sample. The XMuDat and XCOM programs were used to calculate the mass attenuation coefficient (μ/ρ) in the photon energy range of 0.015–10 MeV for all glasses. The difference between the obtained values of XMuDat and XCOM is found to be less than 1%. Half value layer (HVL), effective atomic number (Zeff), and mean free path (MFP) as γ-ray shielding features have been evaluated using values of the (μ/ρ) for all proposed glasses. Results reveal that ANBP50 and ANBP00 samples possess a maximum Zeff and a minimum Zeff, respectively. Indeed, ANBP50 glass has lowest values of (HVL) and (MFP). Therefore, addition of PbO content in the prepared glasses has a considerable effect to improve the shielding effectiveness for these glasses. Finally, ANBP50 glass can be considered as a promising candidate for gamma-ray protection applications among different types of concretes, commercial glasses, and HMO glasses.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. E.I. Kamitsos, M.A. Kasakassides, Effect of melt temperature on glass structure. Phys. Chem. Glasses 30, 235 (1989)

    Google Scholar 

  2. S.G. Motke, S.P. Yawale, S.S. Yawale, Infrared spectra of zinc doped lead borate glasses. Bull. Mater. Sci. 25, 75–78 (2002)

    Article  Google Scholar 

  3. V. Rajendaran, N. Palanivelu, H.A. El-Batal, F.A. Khalifa, N.A. Shafi, Effect of Al2O3 addition on the acoustical properties of lithium borate glasses. Acoust. Lett. 23, 113–121 (1999)

    Google Scholar 

  4. H. Hirashima, D. Arari, T. Yoshida, Electrical conductivity of PbO–P2O5–V2O5 glasses. J. Am. Ceram. Soc. 68, 486 (1985)

    Article  Google Scholar 

  5. A. Terczynska-Madej, K. Cholewa-Kowalska, M. Łączka, Coordination and valence state of transition metal ions in alkali-borate glasses. Opt. Mater. 33(12), 1984–1988 (2011)

    Article  ADS  Google Scholar 

  6. H. Doweidar, Consideration of the boron oxide anomaly. J. Mater. Sci. 25(1), 253–258 (1990)

    Article  ADS  Google Scholar 

  7. R.S. Kaundal, S. Kaur, N. Singh, K.J. Singh, Investigation of structural properties of lead strontium borate glasses for gamma-ray shielding applications. J. Phys. Chem. Solids 71(9), 1191–1195 (2010)

    Article  ADS  Google Scholar 

  8. Ashok Kumar, Gamma ray shielding properties of PbO–Li2O–B2O3 glasses. Radiat. Phys. Chem. 136, 50–53 (2017)

    Article  ADS  Google Scholar 

  9. D.K. Gaikwad, S.S. Obaid, M.I. Sayyed, R.R. Bhosale, V.V. Awasarmol, A. Kumar, M.D. Shirsat, P.P. Pawar, Comparative study of gamma ray shielding competence of WO3–TeO2–PbO glass system to different glasses and concretes. Mater. Chem. Phys. 213, 508–517 (2018)

    Article  Google Scholar 

  10. A. Saeed, R.M. El Shazly, Y.H. Elbashar, A.M. Abou El-azm, M.M. El-Okr, M.N.H. Comsan, A.M. Osman, A.M. Abdal-monem, A.R. El-Sersy, Gamma ray attenuation in a developed borate glassy system. Radiat. Phys. Chem. 102, 167–170 (2014)

    Article  ADS  Google Scholar 

  11. K.J. Singh, S. Kaur, R.S. Kaundal, Comparative study of gamma ray shielding and some properties of PbO–SiO2–Al2O3 and Bi2O3–SiO2–Al2O3 glass systems. Radiat. Phys. Chem. 96, 153–157 (2014)

    Article  ADS  Google Scholar 

  12. R. El-Mallawany, M.I. Sayyed, M.G. Dong, Y.S. Rammah, Simulation of radiation shielding properties of glasses contain PbO. Radiat. Phys. Chem. 151, 239–252 (2018)

    Article  ADS  Google Scholar 

  13. M.I. Sayyed, Investigations of gamma ray and fast neutron shielding properties of tellurite glasses with different oxide compositions. Can. J. Phys. 94, 1133–1137 (2016)

    Article  ADS  Google Scholar 

  14. N. Singh, K.J. Singh, K. Singh, H. Singh, Comparative study of lead borate and bismuth lead borate glass systems as gamma-radiation shielding materials. Nucl. Instrum. Methods Phys. Res. B 225, 305–309 (2004)

    Article  ADS  Google Scholar 

  15. M.I. Sayyed, G. Lakshminarayana, I.V. Kityk, M.A. Mahdi, Evaluation of shielding parameters for heavy metal fluoride based tellurite-rich glasses for gamma ray shielding applications. Radiat. Phys. Chem. 139, 33–39 (2017)

    Article  ADS  Google Scholar 

  16. G. Lakshminarayana, S.O. Baki, M.I. Sayyed, M.G. Dong, A. Lira, A.S.M. Noor, I.V. Kityk, M.A. Mahdi, Vibrational, thermal features, and photon attenuation coefficients evaluation for TeO2–B2O3–BaO–ZnO–Na2O–Er2O3–Pr6O11 glasses as gamma rays shielding materials. J. Non Cryst. Solids 481, 568–578 (2018)

    Article  ADS  Google Scholar 

  17. M.I. Sayyed, G. Lakshminarayana, M.G. Dong, M.Ç. Ersundu, A.E. Ersundu, I.V. Kityk, Investigation on gamma and neutron radiation shielding parameters for BaO/SrO–Bi2O3–B2O3 glasses. Radiat. Phys. Chem. 145, 26–33 (2018)

    Article  ADS  Google Scholar 

  18. Y.S. Rammah, M.I. Sayyed, A.S. Abohaswa, H.O. Tekin, FTIR, electronic polarizability and shielding parameters of B2O3 glasses doped with SnO2. Appl. Phys. A 124, 650 (2018)

    Article  ADS  Google Scholar 

  19. Y.S. Rammah, M.I. Sayyed, A.A. Ali, H.O. Tekin, R. El-Mallawany, Optical properties and gamma-shielding features of bismuth borate glasses. Appl. Phys. A 124, 832 (2018)

    Article  ADS  Google Scholar 

  20. Y.S. Rammah, A. Askin, A.S. Abouhaswa, F.I. El-Agawany, M.I. Sayyed, Synthesis, physical, structural and shielding properties of newly developed B2O3–ZnO–PbO–Fe2O3 glasses using Geant4 code and WinXCOM program. Appl. Phys. A 125, 523 (2019)

    Article  ADS  Google Scholar 

  21. M.I. Sayyed, I.A. El-Mesady, A.S. Abouhaswa, A. Askin, Y.S. Rammah, Comprehensive study on the structural, optical, physical and gamma photon shielding features of B2O3–Bi2O3–PbO–TiO2 glasses using WinXCOM and Geant4 code. J. Mol. Struct. 1197, 656–665 (2019)

    Article  ADS  Google Scholar 

  22. M.S. Al-Buriahi, H. Arslan, B.T. Tonguç, Mass attenuation coefficients, water and tissue equivalence properties of some tissues by Geant4, XCOM and experimental data. Indian J. Pure Appl. Phys. (IJPAP) 57(6), 433–437 (2019)

    Google Scholar 

  23. M.I. Sayyed, Y.S. Rammah, A.S. Abouhaswa, H.O. Tekin, B.O. Elbashir, ZnO–B2O3–PbO glasses: synthesis and radiation shielding characterization. Phys. B 548, 20–26 (2018)

    Article  ADS  Google Scholar 

  24. A. Khanna, A. Saini, B. Chen, F. Gonzalez, B. Ortiz, Structural characterization of PbO–B2O3–SiO2 glasses. Phys. Chem. Glasses Eur. J. Glass Sci. Technol. Part B 55(2), 65–73 (2014)

    Google Scholar 

  25. R. Nowotny, XMuDat: Photon Attenuation Data on PC (IAEA-NDS-195, Vienna, 1998)

    Google Scholar 

  26. M.J. Berger, J.H. Hubbell, XCOM: Photon Cross Sections Database. National Institute of Stan and Technology, Gaithersburg, MD 20899, USA, 1987–1999. Web version 1.2. http://physics.nist.gov/xcom (Originally published as NBSIR 87–3597 “XCOM: Photon Cross Section on a Personal Computer”)

  27. L. Gerward, N. Guilbert, K.B. Jensen, H. Lerving, WinXCom—a program for calculating X-ray attenuation coefficients. Radiat. Phys. Chem. 74, 653–654 (2004)

    Article  ADS  Google Scholar 

  28. F. Akman, M.R. Kacal, M.I. Sayyed, H.A. Karataş, Study of gamma radiation attenuation properties of some selected ternary alloys. J. Alloys Compd. 782, 315–322 (2019)

    Article  Google Scholar 

  29. M.I. Sayyed, F. Akman, I.H. Gecibesler, H.O. Tekin, Measurement of mass attenuation coefficients, effective atomic numbers, and electron densities for different parts of medicinal aromatic plants in low-energy region. Nucl. Sci. Tech. 29, 144 (2018)

    Article  Google Scholar 

  30. O. Agar, M.I. Sayyed, F. Akman, H.O. Tekin, M.R. Kacal, An extensive investigation on gamma ray shielding features of Pd/Ag-based alloys. Nucl. Eng. Technol. 51, 853–859 (2019)

    Article  Google Scholar 

  31. I. Bashter, Calculation of radiation attenuation coefficients for shielding concretes. Ann. Nucl. Energy 24, 1389–1401 (1997)

    Article  Google Scholar 

  32. I. Akkurt, R. Altindag, K. Gunoglu, H. Sarikaya, Photon attenuation coefficients of concrete including marble aggregates. Ann. Nucl. Energy 43, 56 (2012)

    Article  Google Scholar 

  33. http://www.schott.com/advanced_optics/english/products/optical-materials/special-materials/radiation-shielding-glasses/index.html

  34. V.P. Singh, N.M. Badiger, J. Kaewkhao, Radiation shielding competence of silicate and borate heavy metal oxide glasses: comparative study. J. Non Cryst. Solids 404, 167–173 (2014)

    Article  ADS  Google Scholar 

  35. Y.S. Rammah, A.S. Abouhaswa, M.I. Sayyed, H.O. Tekin, R. El-Mallawany, Structural, UV and shielding properties of ZBPC glasses. J. Non Cryst. Solids 509, 99–105 (2019)

    Article  ADS  Google Scholar 

  36. R. El-Mallawany, M.I. Sayyed, M.G. Dong, Comparative shielding properties of some tellurite glasses: part 2. J. Non Cryst. Solids 474, 16–23 (2017)

    Article  ADS  Google Scholar 

  37. R. El-Mallawany, M.I. Sayyed, Comparative shielding properties of some tellurite glasses: part 1. Phys. B 539, 133–140 (2018)

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to express his deep thanks appreciation to Prof. B. T. Tonguc, vice rector of Sakarya University, Turkey and Prof. R. El-Mallawany, Physics Department, Faculty of Science, Menoufia University, Egypt for their great support providing and all facilities necessary during this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Y. S. Rammah.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Al-Buriahi, M.S., Rammah, Y.S. Investigation of the physical properties and gamma-ray shielding capability of borate glasses containing PbO, Al2O3 and Na2O. Appl. Phys. A 125, 717 (2019). https://doi.org/10.1007/s00339-019-3020-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00339-019-3020-z

Navigation