Abstract
Corona discharge treatment (CDT) was implemented to attempt to graft a modified β-cyclodextrin (β-CD) onto cellulose. The occurrence of grafting was indirectly proven by gravimetric analyses, X-ray Photoelectron Spectroscopy (XPS) and Scanning Electron Microscopy (SEM). Besides, the effect of CDT onto cellulosic substrate was studied using SEM and XPS. It appeared that surface roughness increased with the treatment time as a consequence of an etching effect and that surface oxidation took place as evidenced by the creation of hydroxyl and carboxyl groups. These functional groups are not responsible for chemical link between modified β-CD and substrate. It was assumed that the grafting results from the reaction of double-bonds of modified β-CD and radicals formed on treated surface, these ones being evidenced by DPPH radical trapping. Moreover the inclusion of a guest molecule is still possible in grafted modified β-CD giving a new proof of grafting.
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References
Heinze, T., Ficher, K.: Cellulose and cellulose derivatives. Wiley-VCH, Weinheim (2005)
Hatakeyama, T., Hatakeyama, H.: Thermal properties of green polymers and biocomposites. Kluwer academic publishers, Dordrecht (2004)
Heinze, T., Petzold, K.: In: Belgacem, M.N., Gandini, A. (eds.) Cellulose chemistry: novel products and synthesis paths. Monomers, polymers and composites from renewable resources, pp. 343–368. Elsevier Ltd, Oxford, UK (2008)
Dorn, S., Pfeifer, A., Schlufter, K., Heinze, T.: Synthesis of water-soluble cellulose esters applying carboxylic acid imidazolides. Polym. Bull 64, 845–854 (2010)
Kasai, W., Tsutsumi, K., Morita, M., Kondo, T.: Orientation of the alkyl side chains and glucopyranose rings in Langmuir–Blodgett films of a regioselectively substituted cellulose ether. Colloid Polym. Sci. 286, 707–712 (2008)
Lei, J., Shi, M., Zhang, J.: Surface graft copolymerisation of hydrogen silicone fluid onto fabrics through Corona discharge and water repellency of grafted fabrics. Eur. Polym. J. 36, 1277–1281 (2000)
Mercx, F.P.M.: Improved adhesive properties of high modulus polyethylene structures: 2. Corona grafting of acrylic acid. Polymer 34, 1891–1897 (1993)
Iwata, H., Kishida, A., Suzuki, M., Hata, Y., Ikada, Y.: Oxidation of polyethylene surface by Corona discharge and subsequent graft polymerization. J. Polym. Sci. Part A 26, 3309–3322 (1988)
Bataille, P., Dufourd, M., Sapieha, S.: Copolymerization of styrene onto cellulose activated by Corona. Polym. Int. 34, 387–391 (1994)
Bataille, P., Dufourd, M., Sapieha, S.: Graft polymerization of styrene onto cellulose by Corona discharge. Polym. Preprints 32, 559–560 (1991)
Tu, X., Young, R.A., Denes, F.: Improvement of bonding between cellulose and polypropylene by plasma treatment. Cellulose 1, 87–106 (1994)
Ooi, S.K.; Vanderhoek, N.; Morrison, R.; Bauer, A.: Atmospheric plasma treatment (APT), Understanding the basics. Appita annual conference 407–412 (2004)
Dong, S., Sapieha, S., Schreiber, H.P.: Mechanical properties of Corona-modified cellulose/polyethylene composites. Polym. Eng. Sci. 33, 343–346 (1993)
Belgacem, M.N., Bataille, P., Sapieha, S.: Effect of Corona modification on the mechanical properties of polypropylene/cellulose composites. J. Appl. Polym. Sci. 53, 379–385 (1994)
Seto, F., Muraoka, Y., Akagi, T., Kishida, A., Akashi, M.: Surface grafting of poly(vinylamine) onto poly(ethylene) film by Corona discharge-induced grafting. J. Appl. Polym. Sci. 72, 1583–1587 (1999)
Yuhai, G., Jianchun, Z., Meiwu, S.: Surface graft of acrylic acid onto Corona-treated poly(ethylene terephtalate) fabric. J. Appl. Polym. Sci. 73, 1161–1164 (1999)
Martel, B., Morcellet, M., Ruffin, D., Vinet, F., Weltrowski, M.: Capture and controlled release of fragrances by CD finished textiles. J. Incl. Phenom. Macrocycl. Chem. 44, 439–442 (2002)
Szejtli, J.: Introduction and general overview of cyclodextrin chemistry. Chem. Rev. 98, 1743–1753 (1998)
de Bergamasco, R.C., Zanin, G.M., de Moraes, F.F.: Grafting of cyclodextrin onto filter paper. J. Incl. Phenom. Macrocycl. Chem. 57, 75–78 (2007)
Bergeron, R.J., Meeley, M.P., Machida, Y.: Selective alkylation of cycloheptaamylose. Bioorg. Chem. 5, 121–126 (1975)
Fulton, D.A., Stoddart, J.F.: Synthesis of cyclodextrins-based carbohydrate clusters by photoaddition reactions. J. Org. Chem. 66, 8309–8319 (2001)
Belgacem, M.N., Czeremuszkin, G., Sapieha, S., Gandini, A.: Surface characterization of cellulose fibres by XPS and inverse gas chromatography. Cellulose 11, 145–157 (1995)
Zhang, D., Sun, Q., Wadsworth, L.C.: Mechanism of Corona treatment on polyolefin films. Polym. Eng. Sci. 38, 965–970 (1998)
Zheng, Z., Tang, X., Shi, M., Zhou, G.: A study of the influence of controlled Corona treatment on UHMWPE fibres in reinforced vinylester composites. Polym. Int. 52, 1833–1838 (2003)
Ward, T.L., Jung, H.Z., Hinojosa, O., Benerito, R.R.: Characterization and use of radio frequency plasma-activated natural polymers. J. Appl. Polym. Sci. 23, 1987–2003 (1979)
Gaiolas, C., Costa, A.P., Nunes, M., Silva, M.J.S., Belgacem, M.N.: Grafting of paper by silane coupling agents using cold-plasma discharges. Plasma Process. Polym. 5, 444–452 (2008)
Gassan, J., Gutowski, V.S.: Effects of Corona discharge and UV treatment on the properties of jute-fibre epoxy composites. Compos. Sci. Technol. 60, 2857–2863 (2000)
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The authors would like to thank Jacques Lambert from LCPME, CNRS UMR 7564, Nancy for XPS experiments.
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Benhadi, S., Ragoubi, M., Joly, JP. et al. Corona discharge treatment route for the grafting of modified β-cyclodextrin molecules onto cellulose. J Incl Phenom Macrocycl Chem 70, 143–152 (2011). https://doi.org/10.1007/s10847-010-9879-0
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DOI: https://doi.org/10.1007/s10847-010-9879-0