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Preparation and chemical reduction of laurylamine-intercalated graphite oxide

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Abstract

Laurylamine-intercalated graphite oxide (GO) is prepared by ultrasonic in the presence of a small amount of hexane and then chemically reduced by hydrazine. The interlayer spacing of laurylamine-intercalated GO reaches a maximum when the molar ratio of laurylamine and GO is 1.384. Three types of laurylamine in GO are identified in the intercalated compounds: hydrogen-bonded neutral amines, hydrogen-bonded protonated amines, and ionically bound protonated amines. Modified graphene colloidal suspension is obtained by chemical reduction of laurylamine-intercalated GO in dimethyl formamide (DMF). Furthermore, a possible chemical reduction mechanism is put forward to explain the hydrazine reduction process.

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Acknowledgements

The authors are grateful for the financial support from the 863 program. The program No. is 2009AA04Z142.

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Authors and Affiliations

  1. School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai, 200237, People’s Republic of China

    Yanyun Wang, Linsheng Xie, Jin Sha, Yulu Ma, Jingjie Han, Shumei Dong, Hu Liu, Cheng Fang, Shuyun Gong & Zhangqi Wu

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  1. Yanyun Wang
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  2. Linsheng Xie
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  3. Jin Sha
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Correspondence to Linsheng Xie.

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Wang, Y., Xie, L., Sha, J. et al. Preparation and chemical reduction of laurylamine-intercalated graphite oxide. J Mater Sci 46, 3611–3621 (2011). https://doi.org/10.1007/s10853-011-5277-2

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  • DOI: https://doi.org/10.1007/s10853-011-5277-2

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