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Three-Dimensional Silver(I)-Thiodiglycolate Coordination Polymer with Weak Ag–Ag Bond

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Abstract

Reaction of thiodiglycolic acid and silver nitrate under ultrasonic condition forms a 3D supramolecular framework of silver with composition [Ag2(tdga)] n (1). X-ray single crystal structure analysis reveals repetition of paddle wheel units in the network. A weak Ag–Ag bond is present in the complex. A new μ8-coordination mode of the thiodiglycolate ligand is identified. Photoluminescence and thermal characterization of the complex was examined.

Graphical Abstract

Novel 3D silver coordination polymer with Ag–Ag bond is synthesized using thiodiglycolic acid ligand and characterized by X-ray diffraction, IR, photoluminescence and TG analysis. The ligand displays a unique type of coordination.

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Acknowledgments

This project was financially supported by UGC, New Delhi, India [F. No. 39-1027/2010 (SR)]. S. K. J. is thankful to UGC for providing research fellowship.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore, 721102, West Bengal, India

    Madhusudan Bera, Abhinandan Rana, Durga Sankar Chowdhuri, Debdoot Hazari, Swapan Kumar Jana & Sudipta Dalai

  2. Department of Chemistry, Durham University, Durham, DH1 3LE, UK

    Horst Puschmann

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  1. Madhusudan Bera
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  2. Abhinandan Rana
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  3. Durga Sankar Chowdhuri
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  7. Sudipta Dalai
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Correspondence to Sudipta Dalai.

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Bera, M., Rana, A., Chowdhuri, D.S. et al. Three-Dimensional Silver(I)-Thiodiglycolate Coordination Polymer with Weak Ag–Ag Bond. J Inorg Organomet Polym 22, 897–902 (2012). https://doi.org/10.1007/s10904-012-9664-1

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