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Polymer Protected and Gel Immobilized Gold and Silver Nanoparticles in Catalysis

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Abstract

This mini-review is focused on preparation of polymer protected gold (AuNPs) and silver (AgNPs) nanoparticles that are immobilized on the surface of inorganic supporters and within hydrogel and/or cryogel matrices. A series of water soluble polymers such as poly(N-vinylpyrrolidone), poly(acrylic acid), branched polyethyleneimine, and amphoteric cryogel based on the copolymer of N,N-dimethylaminoethylmethacrylate and methacrylic acid poly(DMAEM-MAA) were used for reduction and stabilization of metal nanoparticles. The catalytic properties of polymer protected AuNPs and AgNPs were evaluated with respect to hydrogen peroxide decomposition, hydrogenation of 4-nitrophenol and oxidation of cyclohexane.

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Abbreviations

AgNPs:

Silver nanoparticles

AuNPs:

Gold nanoparticles

4-AP:

4-Aminophenol

BPEI:

Branched poly(ethyleneimine)

CH:

Cyclohexane

CH-ol:

Cyclohexanol

CH-one:

Cyclohexanone

CuNPs:

Copper nanoparticles

DLS:

Dynamic light scattering

DMAEM:

N,N-Dimethylaminoethylmethacrylate

HPEI-IBAM:

Hyperbranched poly(ethylenimine) with isobutyramide groups

IL:

Ionic liquid

kD:

kiloDalton

MAA:

Methacrylic acid

MBAA:

N,N-Methylenebisacrylamide

Mn :

The number-average molecular weight

4-NA:

4-Nitroaniline

NIPAM:

N-Isopropylacrylamide

2-NP:

2-Nitrophenol

4-NP:

4-Nitrophenol

NPs:

Nanoparticles

PAA:

Poly(acrylic acid)

PAAH:

Poly(acrylamide) hydrogel

PAMAM:

Poly(amidoamine)

PD1-2:

Dendrimer based on poly(ethylenimine) as a shell and 2,2-bis(palmytyloxymethyl) propionic acid as a dendrone

PdNPs:

Palladium nanoparticles

PEC:

Polyelectrolyte complex

PEI:

Poly(ethyleneimine)

poly(DMAEM-MAA):

Amphoteric cryogel based on copolymer of N,N-dimethylaminoethylmethacrylate and methacrylic acid

Poly(DMAEM-MAA)/AuNPs:

Gold nanoparticles immobilized within poly(DMAEM-MAA) cryogel matrix

PVP:

Poly(N-vinylpyrrolidone)

PVP-AgNPs:

Silver nanoparticles protected by PVP

PVP-AgNPs/PAAH:

Silver nanoparticles protected by PVP and supported onto PAAH

PVP-AgNPs/ZnO:

Silver nanoparticles protected by PVP and supported onto ZnO

PVP-AuNPs:

Gold nanoparticles protected by PVP

PVP-AuNPs/PAAH:

Gold nanoparticles protected by PVP and supported onto PAAH

PVP-AuNPs/ZnO:

Gold nanoparticles protected by PVP and supported onto ZnO

SEM:

Scanning electron microscope

SOD:

Superoxide dismutase

TEM:

Transmission electron microscope

TOF:

Turnover frequency

TON:

Turnover number

UV–Vis:

Ultraviolet–Visible spectra

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Acknowledgments

Financial support from the Ministry of Education and Science of the Republic of Kazakhstan in the frame of the Grant No. 1004/GF4 2015–2017 is greatly acknowledged.

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Authors and Affiliations

  1. Laboratory of Engineering Profile, K.I. Satpayev Kazakh National Research Technical University, Almaty, 050013, Kazakhstan

    Sarkyt E. Kudaibergenov & Gulnur S. Tatykhanova

  2. Institute of Polymer Materials and Technology, Almaty, 050013, Kazakhstan

    Sarkyt E. Kudaibergenov & Gulnur S. Tatykhanova

  3. Department of Chemical Technology, K. I. Satpayev Kazakh National Research Technical University, Almaty, 050013, Kazakhstan

    Bagadat S. Selenova

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  1. Sarkyt E. Kudaibergenov
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Correspondence to Sarkyt E. Kudaibergenov.

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Kudaibergenov, S.E., Tatykhanova, G.S. & Selenova, B.S. Polymer Protected and Gel Immobilized Gold and Silver Nanoparticles in Catalysis. J Inorg Organomet Polym 26, 1198–1211 (2016). https://doi.org/10.1007/s10904-016-0373-z

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