Skip to main content
SpringerLink
Log in

Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

The Sc(III)-containing monomers and their (co)polymers has been first prepared and characterized. The composition and structure of the synthesized metal-containing monomers and (co)polymers examined by elemental analysis, IR and 13C-NMR spectroscopy. The thermal behavior of Sc(III)—containing monomers and (co)polymers was explored by DSC, DTA, TGA and mass spectrometry. It is shown that the obtained crosslinked copolymers exhibit a high thermal stability, have a porous structure with a developed system of micro- and mesopores, which may be of interest for their template-based customized sorbents for concentration and extraction of scandium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. O.V. Tiunova, O.Yu. Zadorozhnaya, Yu.K. Nepochatov, I.N. Burmistrov, I.E. Kuritsyna, S.I. Bredikhin, Electrochemistry 50, 801 (2014)

    Google Scholar 

  2. S.A. Cotton, Scandium, yttrium, the lantanides, and the actinides, Annual Reports on the Progress of Chemistry. Section A, 93, 269 (1997)

  3. N.J. Hill, W. Levason, M.C. Popham, G. Reid, M. Webster, Polyhedron 21, 1579 (2002)

    Article  CAS  Google Scholar 

  4. S.P. Yatsenko, L.A. Pasechnik, V.M. Skachkov, Novosti materialovedeniya. Nauka I tekhnika. 3(15), 32 (2015)

    Google Scholar 

  5. S.A. Aleksandrovskii, V.V. Chizhikov, Tsvetnaya metalurgiya 2–3, 29 (1997)

    Google Scholar 

  6. V.A. Kabanov, D.D. Orudzhev, A.A. Edendiev, Vysokomolek. soed., A, 21, 589 (1979)

  7. A.A. Edendiev, D.D. Orudzhev, V.A. Kabanov, Эфeндиeв A.A. Dokl. Akad. Nauk 255, 1393 (1980)

    Google Scholar 

  8. A.D. Pomogailo, N.P. Arkhipov, T.S. Meshalkin, G.I. Dzhardimalieva, A.M. Bochkin, N.M. Bravaya, N.A. Bakunov, Dokl. Akad. Nauk 335, 749 (1994)

    CAS  Google Scholar 

  9. G.I. Dzhardimalieva, A.D. Pomogailo, Izv. AN USSR, Ser. Khim., 352 (1991)

  10. S. Lowell, J.E. Shields, M.A. Thomas, M. Thommes, Characterization of porous solids and powders: surface area, pore size, and density (Springer, Dordrecht, 2006)

    Google Scholar 

  11. A.D. Pomogailo, G.I. Dzhardimalieva, Polym. Sci. Ser. A 46, 250 (2004)

  12. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, 2009)

    Google Scholar 

  13. G.B. Deacon, R.J. Phillips, Coord. Chem. Rev. 33, 227 (1980)

    Article  CAS  Google Scholar 

  14. A. C. Co, The Aldrich Library of FT-IR Spectra, vol 1 (Aldrich, Milwaukee, 1997)

  15. Y.J. Jeong, T.K. An, D.-J. Yun, L.H. Kim, S. Park, Y. Kim, S. Nam, K.H. Lee, S.H. Kim, J. Jang, C.E. Park, ACS Appl. Mater. Interfaces 8, 5499 (2016)

    Article  CAS  Google Scholar 

  16. A.D. Pomogailo, G.I. Dzhardimalieva, A.S. Rozenberg, D.N. Muraviev, J. Nanoparticle Res. 5, 497 (2003)

    Article  CAS  Google Scholar 

  17. B.G. Korshunov, A.M. Reznik, S.A. Semenov, Scandium (Metallurgiya, Moscow, 1987)

    Google Scholar 

  18. L.N. Komissarova, Inorganic and Analutic Chemistry of Scandium (Editorial UPCC, Moscow, 2001)

    Google Scholar 

  19. B.P. Nikol’skii (ed.), Chemistry Handbook, vol 1 (Khimiya, Moscow, Leningrad, 1982), p. 381

Download references

Acknowledgments

This work was partially supported by RFBR (Project № 14-43-03580, 14-03-00675, № 16-03-00148). The authors thank K.S. Kalinina for assistance in running the experiments.

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka Moscow Region., Pr. Akad. Semenova, 1, Moscow, Russian Federation, 142432

    G. I. Dzhardimalieva, E. I. Knerelman & G. I. Davydova

  2. Institute of Fine Chemical Technologies, Moscow Technological University, Moscow, Prospect Vernadskogo, 86, Moscow, Russian Federation, 119571

    S. A. Semenov

  3. Institute of Chemistry and Chemical Technology, NAS KR, Bishkek, Kyrgyzstan

    K. A. Kydralieva

Authors
  1. G. I. Dzhardimalieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Semenov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. I. Knerelman
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. I. Davydova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. A. Kydralieva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. I. Dzhardimalieva.

Additional information

This series was initiated by Professor A.D.Pomogailo in the 1980s. The part 77 see in [Kinetics and catalysis, 57, 362 (2016)].

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dzhardimalieva, G.I., Semenov, S.A., Knerelman, E.I. et al. Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties. J Inorg Organomet Polym 26, 1441–1451 (2016). https://doi.org/10.1007/s10904-016-0421-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-016-0421-8

Keywords

Search

Navigation