Abstract
Cd and Fe co-doped nano ZnS samples (Zn0.75−xFexCd0.25S) are prepared by thermolysis method. The effect of Fe doping content on the structural parameters, infrared absorption bands and the energy gap of Zn0.75Cd0.25S are investigated using Rietveld analysis for synchrotron X-ray diffraction data, Fourier transform infrared and UV–Vis spectroscopy. The energy gap first decreases upon doping then it increases with further Fe-doping. The photoluminescence spectroscopy reveals that the emitted colors for Zn0.75−xFexCd0.25S are dependent on the excitation wavelengths and the amount of Fe-doping. Magnetization measurements indicate that Zn0.75Cd0.25S possess a diamagnetic behavior while Zn0.55Fe0.2Cd0.25S exhibits a weak ferromagnetic nature with small coercivity and saturation magnetization obtain from the law of approach to saturation.
Similar content being viewed by others
References
Z.K. Heiba, M.B. Mohamed, Appl. Phys. A Mater. Sci. Process. 124(6), 446 (2018)
Z.K. Heiba, N.Y. Mostafa, M.B. Mohamed, H. Al-Harthi, Mater. Lett. 93, 115 (2013)
M. Husain, B.P. Singh, S. Kumar, T.P. Sharma, P.J. Sebastian, Sol. Energy Mater. Sol. Cells 76, 399 (2003)
Z.K. Heiba, M.B. Mohamed, N.Y. Mostafa, Appl. Phys. A Mater. Sci. Process. 125(2), 132 (2019)
Z.K. Heiba, M.B. Mohamed, N.G. Imam, Ceram. Int. 41(10), 12930 (2015)
Z.K. Heiba, M.B. Mohamed, N.G. Imam, J. Alloys Compd. 618, 280 (2015)
O. Baytar, O. Sahin, H. Kilicvuran, S. Horoz, J. Mater. Sci. 29, 4564 (2018)
I. Devadossa, P. Sakthivelb, S. Muthukumaranc, N. Sudhakar, Ceram. Int. 45, 3833 (2019)
I. Devadoss, S. Muthukumaran, Mater. Sci. Semicond. Process. 41, 282 (2016)
I. Devadoss, S. Muthukumaran, Physica E 72, 111 (2015)
K. Liua, J.Y. Zhanga, X. Wua, B. Lia, B. Lia, Y. Lua, X. Fana, D. Shen, Phys. B 389, 248 (2007)
M. Mall, L. Kumar, J. Lumin. 130, 660 (2010)
A. Yakoubi, M. Mrad, T.B. Chaabane, H. Rinnert, L. Balan, G. Medjahdi, R. Schneider, J. Alloys Compd. 764, 591 (2018)
D. Han, J. Cao, S. Yang, J. Yang, B. Wang, L. Fan, Q. Liu, T. Wang, H. Niu, Dalton Trans. 43, 11019 (2014)
S. Kumar, N.K. Verma, J. Mater. Sci. 26(5), 2754 (2015)
N. Eryong, L. Donglai, Z. Yunsen, B. Xue, Y. Liang, J. Yong, J. Zhifeng, S. Xiaosong, Appl. Surf. Sci. 257, 8762 (2011)
B. Poornaprakash, D.A. Reddy, G. Murali, R.P. Vijayalakshmi, B.K. Reddy, Physica E 73, 63 (2015)
D. Saikia, R.D. Raland, J.P. Borah, Physica E 83, 56 (2016)
L. Lutterotti, Nucl. Inst. Methods Phys. Res. B. 268, 334 (2010)
Y. Li, C. Cao, Z. Chen, Chem. Phys. Lett. 517, 55 (2011)
G. Murugadoss, B. Rajamannan, V. Ramasamy, J. Lumin. 130, 2032 (2010)
P. Kumar, N. Saxena, F. Singh, A. Agarwal, Phys. B 407, 3347 (2012)
B.S. Remadevi, R. Raveendran, A.V. Vaidyan, Pramana J. Phys. 68, 679 (2007)
M. Cross, Z. Xiao, E.M. Maes, R.S. Czernuszewicz, S.C. Drew, J.R. Pilbrow, G.N. George, A.G. Wedd, J. Biol. Inorg. Chem. 7, 81 (2002)
J. Tauc, in The Optical Properties of Solid, ed. by A. Abeles (North Holland, Amsterdam, 1972), p. 277
I. Devadoss, S. Muthukumaran, J. Mater. Sci. 27(7), 7389 (2016)
P.C. Patel, P.C. Srivastava, J. Mater. Sci. 49(17), 6012 (2014)
M.B. Mohamed, Z.K. Heiba, N.G. Imam, J. Mol. Struct. 1163, 442 (2018)
A.O. Awodugba, A.A. Ibiyemi, J.O. Ajayi, Int. J. Sci. Res. Manag. Stud. 1(7), 234 (2014)
J. Lahnemann, U. Jahn, O. Brandt, T. Flissikowski, P. Dogan, H.T. Grahn, J. Phys. D Appl. Phys. 47(42), 423001 (2014)
R. Heitz, A. Hoffmann, I. Broser, Phys. Rev. B 48, 8672 (1993)
C. Rosiles-Perez, J. Lambert, A. Alatorre-Ordaz, J.A. Gutierrez, T. López-Luke, R. Ramirez-Fuentes, T. Kobayashi, J. Lumin. 184, 123 (2017)
S.S. Pedro, O. Nakamura, R.B. Barthem, L.P. Sosman, J. Fluoresc. 19, 211 (2009)
M.M.L. Sonia, S. Anand, V.M. Vinosel, M.A. Janifer, S. Pauline, A. Manikandan, J. Magn. Magn. Mater. 466, 238 (2018)
P.C. Patel, P.C. Srivastava, J. Mater. Sci. 49, 6012 (2014)
S. Bhattacharya, D.C. Chakravorty, Chem. Phys. Lett. 444, 319 (2007)
S. Sambasivam, D. Paul Joseph, D. Raja Reddy, B.K. Reddy, Mater. Sci. Eng. B 150, 125 (2008)
Y. Li, C. Cao, Z. Chen, Phys. Lett. 517, 55 (2011)
P.K. Sharma, R.K. Dutta, A.C. Pandey, J. Colloid Interface Sci. 345, 149 (2010)
Acknowledgements
The authors would like to gratitude the MCX staff members for helping with the SR-XRPD measurements carried out at the MCX beam line of Elettra synchrotron, Trieste, Italy.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Heiba, Z.K., Mohamed, M.B. Structural, Optical and Magnetic Properties of ZnS Co-doped with Cd and Fe. J Inorg Organomet Polym 30, 879–888 (2020). https://doi.org/10.1007/s10904-019-01226-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-019-01226-9