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Hydrothermal synthesis of size-controlled silicalite-1 crystals

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Abstract

The objective of this work was to evaluate the use of hydrothermal method for the synthesis of small and homogeneous silicalite-1 zeolite. The influences of crystallization time, crystallization temperature, different organic solvents and different TPAOH template concentrations were investigated. The results showed these parameters had played important roles in controlling particle size of silicalite-1 zeolite.

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References

  1. P.A. Jacobs, J.A. Martens, Stud. Surf. Sci. Catal. 58, 445 (1991)

    Article  CAS  Google Scholar 

  2. A. Corma, Chem. Rev. 97, 2373 (1997)

    Article  CAS  Google Scholar 

  3. J. Motuzas, A. Julbe, R.D. Noble, C. Guizard, Z.J. Beresnevicius, D. Cot, Micropor. Mesopor. Mater. 80, 73 (2005)

    Article  CAS  Google Scholar 

  4. Y.J. Lee, K.B. Yoon, Micropor. Mesopor. Mater. 88, 176 (2006)

    Article  CAS  Google Scholar 

  5. D.V. Cristiano-Torres, Y. Osorio-Pérez, L.A. Palomeque-Forero, L.E. Sandoval-Díaz, C.A. Trujillo, Appl. Catal. A Gen. 346, 104 (2008)

    Article  CAS  Google Scholar 

  6. Z.L. Lai, G. Bonilla, I. Diaz, J.G. Nery, K. Sujaoti, M.A. Amat, E. Kokkoli, O. Terasaki, R.W. Thompson, M. Tsapatsis, D.G. Vlachos, Science 300, 456 (2003)

    CAS  Google Scholar 

  7. G.J. Li, S. Kawi, Sens. Actuators B 59, 1 (1999)

    Article  Google Scholar 

  8. M. Luo, Z. Wang, Y. Wang, J. Liang, J.Z. Fang, J. Inorg. Mater. 24, 330 (2009)

    Article  Google Scholar 

  9. J. Andersson, J. Rosenholm, S. Areva, M. Lindén, Chem. Mater. 16, 4160 (2004)

    Article  CAS  Google Scholar 

  10. R.R. Xu, W.Q. Pang, J.H. Yu, Q.S. Huo, J.S. Chen, Chemistry-Zeolites and Porous Materials, 1st edn. (Science Press, Beijing, 2004), pp. 73–204

    Google Scholar 

  11. E.M. Flanigen, J.M. Bennett, R.W. Grose, J.P. Cohen, R.L. Patton, R.M. Kirchner, J.V. Smith, Nature 271, 512 (1978)

    Article  CAS  Google Scholar 

  12. O. Larlus, V. Valtchev, J. Patarin, A.C. Faust, B. Maquin, Micropor. Mesopor. Mater. 56, 175 (2002)

    Article  CAS  Google Scholar 

  13. S. Axnanda, D.F. Shantz, Micropor. Mesopor. Mater. 84, 236 (2005)

    Article  CAS  Google Scholar 

  14. S.J. Ahmadi, S. Sadjadi, M. Hosseinpour, M. Outokesh, R. Hekmatshoar, Catal. Commun. 10, 1423 (2009)

    Article  CAS  Google Scholar 

  15. D.P. Serrano, J. Aguado, G. Morales, J.M. Rodríguez, A. Peral, M. Thommes, J.D. Epping, B.F. Chmelka, Chem. Mater. 21, 641 (2009)

    Article  CAS  Google Scholar 

  16. S.P. Naik, A.S.T. Chiang, R.W. Thompson, F.C. Huang, Chem. Mater. 15, 787 (2003)

    Article  CAS  Google Scholar 

  17. S. Chinayon, O. Mekasuwandumrong, P. Praserthdam, J. Panpranot, Catal. Commun. 9, 2297 (2008)

    Article  CAS  Google Scholar 

  18. D.P. Serrano, J. Aguado, J.M. Escola, J.M. Rodríguez, A. Peral, Chem. Mater. 18, 2462 (2006)

    Article  CAS  Google Scholar 

  19. M. Rezaei, S.M. Alavi, S. Sahebdelfar, Z.F. Yan, J. Porous Mater. 15, 171 (2008)

    Article  CAS  Google Scholar 

  20. J.C. Groen, W.D. Zhu, S. Brouwer, S.J. Huynink, F. Kapteijn, J.A. Moulijn, J. Pérez-Ramírez, J. Am. Chem. Soc. 129, 355 (2007)

    Article  CAS  Google Scholar 

  21. T. Granato, A. Katovic, K. Maduna Valkaj, A. Tagarelli, G. Giordano, J. Porous Mater. 16, 227 (2009)

    Article  CAS  Google Scholar 

  22. Y.F. Bu, Y.Q. Wang, Y.J. Zhang, L. Wang, Z.T. Mi, W. Wu, E.Z. Min, S.B. Fu, Catal. Commun. 8, 16 (2007)

    Article  CAS  Google Scholar 

  23. B. Bonelli, L. Forni, A. Aloise, J.B. Nagy, G. Fornasari, E. Garrone, A. Gedeon, G. Giordano, F. Trifiro, Micropor. Mesopor. Mater. 101, 153 (2007)

    Article  CAS  Google Scholar 

  24. W. Xiao, J.H. Yang, J.M. Lu, J.Q. Wang, Sep. Purif. Technol. 67, 58 (2009)

    Article  CAS  Google Scholar 

  25. J. Lindmark, J. Hedlund, Stud. Surf. Sci. Catal. 170, 975 (2007)

    Article  Google Scholar 

  26. X.S. Li, S.H. Xiang, Stud. Surf. Sci. Catal. 135, 3225 (2001)

    CAS  Google Scholar 

  27. J. Lu, F. Xu, D.J. Wang, J. Huang, W.M. Cai, J. Hazard. Mater. 165, 120 (2009)

    Article  CAS  Google Scholar 

  28. J.M. van de Graaf, M. Zwiep, F. Kapteijn, J.A. Moulijn, Appl. Catal. A Gen. 178, 225 (1999)

    Article  Google Scholar 

  29. J.H. Clark, D.J. Macquarrie, Org. Process Res. Dev. 1, 149 (1997)

    Article  CAS  Google Scholar 

  30. C. Flego, L. Dalloro, Micropor. Mesopor. Mater. 60, 263 (2003)

    Google Scholar 

  31. V.R. Marthala, Y. Jiang, J. Huang, W. Wang, R. Gläser, M. Hunger, J. Am. Chem. Soc. 128, 14812 (2006)

    Article  CAS  Google Scholar 

  32. H. Kath, R. Glaser, J. Weitkamp, Chem. Eng. Technol. 24, 150 (2001)

    Article  CAS  Google Scholar 

  33. H. Sato, Catal. Rev. Sci. Eng. 39, 395 (1997)

    Article  CAS  Google Scholar 

  34. S.F. Yin, B.Q. Xu, Chem. J. Chin. Univ. 24, 1169 (2003)

    CAS  Google Scholar 

  35. Q. Hu, B.J. Dou, H. Tian, J.J. Li, P. Li, Z.P. Hao, Micropor. Mesopor. Mater. 129, 30 (2010)

    Article  CAS  Google Scholar 

  36. S. Vaudreuil, B. Echchahed, P. Reinert, M. Bousmina, S. Kaliaguine, L. Bonneviot, J. Porous Mater. 14, 173 (2007)

    Article  CAS  Google Scholar 

  37. T. Ban, H. Mitaku, C. Suzuki, T. Kume, Y. Ohya, Y. Takahashi, J. Porous Mater. 12, 255 (2005)

    Article  CAS  Google Scholar 

  38. N. Navascués, C. Téllez, J. Coronas, Micropor. Mesopor. Mater. 112, 561 (2008)

    Article  Google Scholar 

  39. C.S. Cundy, P.A. Cox, Micropor. Mesopor. Mater. 82, 1 (2005)

    Article  CAS  Google Scholar 

  40. L.F. Wang, G.S. Zhu, S.L. Qiu, Chem. J. Chin. Univer. 29, 1099 (2008)

    Google Scholar 

  41. Y.F. Yeong, A.Z. Abdullah, A.L. Ahmad, S. Bhatia, Micropor. Mesopor. Mater. 123, 129 (2009)

    Article  CAS  Google Scholar 

  42. J.H. Xu, J.F. Yao, C.F. Zeng, L.X. Zhang, N.P. Xu, J. Porous Mater. 17, 329 (2009)

    Article  Google Scholar 

  43. B. Adnadjevic, J. Vulkicevic, Z. Filipovic-Rojka, Zeolites 10, 699 (1999)

    Article  Google Scholar 

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Acknowledgment

This work was supported by the 973 plan item under Grants (2003CB615802).

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Authors and Affiliations

  1. The Institute for Chemical Physics, Beijing Institute of Technology, Beijing, 100081, People’s Republic of China

    Jian Qi, Tianbo Zhao & Xin Xu

  2. Department of Applied Chemistry, Beijing Institute of Petrochemical Technology, Beijing, 102617, People’s Republic of China

    Fengyan Li & Guida Sun

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  1. Jian Qi
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  2. Tianbo Zhao
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  3. Xin Xu
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  4. Fengyan Li
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  5. Guida Sun
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Correspondence to Tianbo Zhao.

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Qi, J., Zhao, T., Xu, X. et al. Hydrothermal synthesis of size-controlled silicalite-1 crystals. J Porous Mater 18, 509–515 (2011). https://doi.org/10.1007/s10934-010-9404-2

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