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Dy(III) sorption from water solutions by mesoporous silicas functionalized with phosphonic acid groups

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Abstract

The sorption properties towards dysprosium(III) ions of three samples of mesoporous silicas functionalized with phosphonic groups ≡ Si(CH2)2P(O)(OH)2 were studied. It was found that for the sample synthesized by spray-drying using OTAB as a template both sorption and desorption rate of Dy3+ ions is high, due to the defined porosity of the sorbent. Sorption of Dy3+ ions by bridged silsesquioxane xerogels with disordered structure is significantly hindered by diffusion processes, due to the chaotic packing of globules. Using a model for the chemical reactions, the composition of dysprosium(III) complexes with surface phosphonic groups were determined, and their formation constants were calculated. It was shown that xerogels with higher surface concentration of ligand groups (L), can form complexes DyL3 and DyL4 −. Meanwhile, the sample synthesized by spray-drying method forms only DyL2 + and DyL3 complexes. For this sample, complexes DyL3 are more stable than for xerogels. So, mesoporous silica derived by spray-drying method, with defined spatial porosity and relatively low surface concentration complexation groups, is characterized by the best sorption properties towards dysprosium(III) (adsorption and desorption kinetics, the value of the static sorption capacity).

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References

  1. K. Gupta, N. Krishnamurthy, Extractive Metallurgy of Rare Earths (CRC Press, Boca Raton, FL, 2004)

    Book  Google Scholar 

  2. V.S. Sastri, J.-C. Bunzli, V.R. Rao, G.V.S. Rayudu, J.R. Perumareddi, Modern Aspects of Rare Earths and Their Complexes (Elsevier, Amsterdam, 2003)

    Google Scholar 

  3. M. Fanciulli, G. Scarel (eds.), Rare Earth Oxide Thin Films (Springer, Berlin, 2007)

    Google Scholar 

  4. K. O’Donnell, V. Dierolf (eds.), Rare-Earth Doped III-Nitrides for Optoelectronic and Spintronic Applications (Springer, Berlin, 2010)

    Google Scholar 

  5. K.A. Gschneider, J.-C.G. Bunzli, V.K. Pecharsky (eds.), Handbook on the Physica and Chemistry of Rare Earths, vol. 37 (Elsevier/North Holland, Amsterdam, 2007)

  6. K. Binnemans, Rare-earth beta-diketonates, in Handbook on the Physics, Chemistry of Rare Earths, vol. 35, ed. by K. A. Gschneidner Jr., J.-C.G. Bunzli, V.K. Pecharsky (Elsevier, Amsterdam, 2005), pp. 107–272

    Google Scholar 

  7. C.S.S.R. Kumar (ed.), Nanomaterials for Cancer Diagnostics (Wiley-VCH, Winheim, 2007)

    Google Scholar 

  8. T. Nishioka, K. Fukui, K. Matsumoto, Lanthanide Chelates as Luminescent Labeles in Biomedical Analyses, in Handbook on the Physics, Chemistry of Rare Earths, ed. by K. A. Gschneidner Jr., J.-C.G. Bunzli, V.K. Pecharsky (Elsevier/North Holland, Amsterdam, 2005), pp. 171–216

    Google Scholar 

  9. K. A. Gschneidner, Le Roy Eyring, M. B. Maple (eds.), Handbook on the Physica and Chemistry of Rare Earths (Elsevier/North Holland, Amsterdam, 2000) 30 (2001) 31

  10. G. Liu, B. Jacquier (eds.), Spectroscopic Properties of Rare Earths in Optical Materials (Springer, Berlin, 2005)

    Google Scholar 

  11. K. Kuriki, Y. Koike, Y. Okamoto, Chem. Rev. 102, 2347 (2002)

    Article  CAS  Google Scholar 

  12. C.-H. Yan, Z.-G. Yan, Y.-P. Du, J. Shen, C. Zhang, W. Feng, Controlled Synthesis and Properties of Nanomaterials, in Handbook on the Physica, Chemistry of Rare Earths, vol. 41, ed. by K. A. Gschneidner Jr., J.-C.G. Bunzli, V.K. Pecharsky (Elsevier/North Holland, Amsterdam, 2011), pp. 275–472

    Google Scholar 

  13. G.V. Lisichkin (ed.), The Chemistry of Grafted Surface Compounds (Fizmatlit, Moscow, 2003). (in Russ.)

    Google Scholar 

  14. N. Zhang, B. Hu, C. Huang, Anal. Chim. Acta 597, 12 (2007)

    Article  CAS  Google Scholar 

  15. R.D. Voronina, G.V. Kudryavtsev, G.V. Lisichkin, V.K. Runov, Russ. J. Phys. Chem. (Engl. Trans.) 59, 294 (1985)

    Google Scholar 

  16. R. Garcia-Valls, A. Hrdiicka, J. Perulka, J. Havel, N.V. Deorkar, L.L. Tavlarides, M. Munoz, M. Valiente, Anal. Chim. Acta 439, 247 (2001)

    Article  CAS  Google Scholar 

  17. H. Rohwer, N. Collier, E. Hosten, Anal. Chim. Acta 314, 219 (1995)

    Article  CAS  Google Scholar 

  18. W. Yantaseea, G.E. Fryxell, R.S. Addlemana, R.J. Wiaceka, V. Koonsiripaiboona, K. Pattamakomsana, V. Sukwarotwat, J. Xub, K.N. Raymond, J. Hazard. Mater. 168, 1233 (2009)

    Article  Google Scholar 

  19. O.A. Dudarko, V.P. Goncharyk, V.Ya. Semenii, Yu.L. Zub, Prot. Met. 44, 193 (2008)

    Article  CAS  Google Scholar 

  20. I.V. Mel’nik, N.V. Stolyarchuk, O.A. Dudarko, Yu.L. Zub, A. Dabrowski, M. Barczak, B. Alonso, Phys. Surf. Prot. Met. 46, 206 (2010)

    Article  Google Scholar 

  21. B. Alonso, C. Clinard, D. Durand, E. Véron, D. Massiot (2005) Chem. Commun. 1746

  22. I.V. Melnyk, Yu.L. Zub, E. Véron, D. Massiot, T. Cacciaguerra, B. Alonso, J. Mater. Chem. 18, 1368 (2008)

    Article  CAS  Google Scholar 

  23. I.V. Melnyk, M. Fatnassi, T. Cacciaguerra, Yu.L. Zub, B. Alonso, Micropor. Mesopor. Mat. (2011)

  24. J.S. Brunauer, P.H. Emmet, E. Teller, J. Am. Chem. Soc. 60, 309 (1938)

    Article  CAS  Google Scholar 

  25. E.P. Barrett, L.G. Joyner, P.P. Halenda, J. Am. Chem. Soc. 73, 373 (1951)

    Article  CAS  Google Scholar 

  26. V.M. Gun’ko, S.V. Mikhalovsky, Carbon 42(4), 843 (2004)

    Article  Google Scholar 

  27. G. Schwarzenbach, G. Flaschka, Complexation Titration (Chemistry, Moscow, 1970). (in Russ.)

    Google Scholar 

  28. A.I. Busev, V.G. Tiptsova, V.M. Ivanov, A Practical Guide to Analytical Chemistry of Rare Elements (Chemistry, Moscow, 1966), pp. 103–105. (in Russ.)

    Google Scholar 

  29. B. Alonso, A. Douy, E. Véron, J. Perez, M.-N. Rager, D. Massiot, J. Mater. Chem. 14, 2006 (2004)

    Article  CAS  Google Scholar 

  30. B. Alonso, E. Véron, D. Durand, D. Massiot, C. Clinard, Microporous Mesoporous Mater. 106, 76 (2007)

    Article  CAS  Google Scholar 

  31. Yu.L. Zub, I.V. Melnyk, N.V. Stolyarchuk, O.D. Dudarko, G.I. Dobryanskaya, O.V. Kuchma, O.I. Gona, R.P. Pogorilyi, A.K. Korobeynik, G.R. Yurchenko, A.K. Matkovsky, V.P. Goncharyk, L.I. Kozhara, Chemistry, Physics and Technology of Surface, vol. 11–12 (Naukova Dumka, Kyiv, 2006), pp. 165–203. (in Russ.)

    Google Scholar 

  32. Yu. L. Zub. Functionalized organosilicas: synthesis, structure, physical and chemical properties. Thesis of Dr. Sc., Karazin Kharkov National University, 2010, 603 pp. (in Ukr.)

  33. G.I. Dobryanskaya, V.P. Goncharyk, L.I. Kozhara, Yu.L. Zub, A. Dabrowski, Russ. J. Coord. Chem. 35, 264 (2009)

    Article  CAS  Google Scholar 

  34. Yu. Kholin, V. Zaitsev, Pure Appl. Chem. 80, 1561 (2008)

    Article  CAS  Google Scholar 

  35. N.N. Vlasova, Surface (Chuiko Institute of Surface Chemistry), vol. 1 (16) (Naukova Dumka, Kyiv, 2009), pp. 4–13

    Google Scholar 

  36. http://www.home.tiscali.nl/cheaqs/download.html#bugs

  37. S.A. Merny, D.S. Konyaev, Yu.V. Kholin, Kharkov University Bull 420, 112 (1998)

    Google Scholar 

Download references

Acknowledgments

This work was done in the framework of Bilateral collaboration NASU-CNRS (no 23996). Also, I.V.M., V.P.G. and Y.L.Z. thanks State Target Scientific and Technical Program of NAS of Ukraine “Nanotechnologies and Nanomaterials” (project 6.22.5.42).

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Authors and Affiliations

  1. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17, General Naumov Street, Kyiv, 03164, Ukraine

    Inna V. Melnyk, Vasyl P. Goncharyk, Natalia V. Stolyarchuk, Lidia I. Kozhara, Anna S. Lunochkina & Yuriy L. Zub

  2. ICGM, UMR 5253 (CNRS/ENSCM/UM2/UM1), 8, rue de l’Ecole Normale, 34296, Montpellier cedex 5, France

    Bruno Alonso

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  1. Inna V. Melnyk
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  2. Vasyl P. Goncharyk
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  3. Natalia V. Stolyarchuk
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Correspondence to Inna V. Melnyk.

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Melnyk, I.V., Goncharyk, V.P., Stolyarchuk, N.V. et al. Dy(III) sorption from water solutions by mesoporous silicas functionalized with phosphonic acid groups. J Porous Mater 19, 579–585 (2012). https://doi.org/10.1007/s10934-011-9508-3

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  • DOI: https://doi.org/10.1007/s10934-011-9508-3

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