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Crystal structure of a new ternary molybdate in the Rb2MoO4-Eu2(MoO4)3-Hf(MoO4)2 system

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Abstract

A ternary salt system Rb2MoO4-Eu2(MoO4)3-Hf(MoO4)2 was studied in the subsolidus area by X-ray phase analysis. A novel ternary molybdate, Rb4.98Eu0.86Hf1.11(MoO4)6, formed in the system. The Rb4.98Eu0.86Hf1.11(MoO4)6 rubidium-europium-hafnium molybdate crystals were grown by solution-melt crystallization under the spontaneous nucleation conditions. The structure and composition of this compound were refined by single crystal X-ray diffraction (X8 APEX automated diffractometer, MoK α radiation, 1753 F(hkl), R = 0.0183). The crystals are trigonal, a = b = 10.7264(1) Å, c = 38.6130(8) Å, V = 3847.44(9) Å3, Z = 6, space group R \(\bar 3\) c. The three-dimensional mixed framework of the structure comprises Mo tetrahedra and two types of octahedra, (Eu,Hf)O6 and HfO6. The large cavities of the framework include two types of the rubidium atom. The distribution of the Eu3+ and Hf4+ cations over two crystallographic positions was refined.

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References

  1. Zh. G. Bazarova, B. G. Bazarov, R. F. Klevtsova, et al., Zh. Strukt. Khim., 35, No. 6, 1007–1009 (1994).

    Google Scholar 

  2. R. F. Klevtsova, Zh. G. Bazarova, L. A. Glinskaya, et al., J. Struct. Chem., 35, No. 3, 286–290 (1994).

    Article  Google Scholar 

  3. R. F. Klevtsova, Zh. G. Bazarova, L. A. Glinskaya et al., ibid., 36, No. 5, 809–812 (1995).

    Article  Google Scholar 

  4. R. F. Klevtsova, Zh. G. Bazarova, L. A. Glinskaya et al., ibid., 813–817.

  5. G. M. Sheldrick, SHELXL-97, release 97-2, Univ. Göttingen, Germany (1998).

    Google Scholar 

  6. R. F. Klevtsova, L. A. Glinskaya, Dokl. Akad. Nauk SSSR, 230, No. 6, 1337–1340 (1976).

    CAS  Google Scholar 

  7. V. K. Rybakov, V. K. Trunov, and V. I. Spitsyn, ibid., 192, No. 2, 369–371 (1970).

    CAS  Google Scholar 

  8. P. V. Klevtsov, E. S. Zolotova, L. A. Glinskaya, R. F. Klevtsova, Zh. Neorg. Khim., 25, No. 7, 1844–1850 (1980).

    CAS  Google Scholar 

  9. Zh. G. Bazarova, E. Yu. Badmaeva, S. F. Solodovnikov, et al., ibid., 49, No. 2, 324–328 (2004).

    CAS  Google Scholar 

  10. V. K. Trunov, V. A. Efremov, and Yu. A. Velikodnyi, Crystal Chemistry and Properties of Binary Molybdates and Tungstates [in Russian], Nauka, Leningrad (1986).

    Google Scholar 

  11. B. G. Bazarov, R. F. Klevtsova, Ts. T. Bazarova, et al., Zh. Neorg. Khim., 50, No. 8, 1240–1243 (2005).

    CAS  Google Scholar 

  12. B. G. Bazarov, O. D. Chimitova, K. N. Fedorov, et al., ibid., 51, No. 5, 866–870 (2006).

    CAS  Google Scholar 

  13. R. D. Shannon, Acta Crystallogr., A32, 751–767 (1976).

    CAS  Google Scholar 

  14. S. F. Solodovnikov, L. V. Balsanova, B. G. Bazarov, et al., Zh. Neorg. Khim., 48, No. 7, 1197–1201 (2003).

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Ulan-Ude

    B. G. Bazarov, O. D. Chimitova, Yu. L. Tushinova & Zh. G. Bazarova

  2. A. V. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences Siberian Division, Novosibirsk

    R. F. Klevtsova & L. A. Glinskaya

Authors
  1. B. G. Bazarov
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  2. O. D. Chimitova
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  3. R. F. Klevtsova
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  4. Yu. L. Tushinova
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  5. L. A. Glinskaya
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  6. Zh. G. Bazarova
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Corresponding author

Correspondence to R. F. Klevtsova.

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Original Russian Text Copyright © 2008 by B. G. Bazarov, O. D. Chimitova, R. F. Klevtsova, Yu. L. Tushinova, L. A. Glinskaya, and Zh. G. Bazarova

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Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 1, pp. 58–62, January–February, 2008.

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Bazarov, B.G., Chimitova, O.D., Klevtsova, R.F. et al. Crystal structure of a new ternary molybdate in the Rb2MoO4-Eu2(MoO4)3-Hf(MoO4)2 system. J Struct Chem 49, 53–57 (2008). https://doi.org/10.1007/s10947-008-0008-5

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  • DOI: https://doi.org/10.1007/s10947-008-0008-5

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