Skip to main content
SpringerLink
Log in

Crystal structure of binary molybdate Pr2Hf3(MoO4)9

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Crystals of binary praseodymium and hafnium molybdate of Pr2Hf3(MoO4)9 composition are grown by solution-melt crystallization under spontaneous nucleation conditions. By the X-ray diffraction data (X8 Apex automated diffractometer, MoK α radiation, 2262 F(hkl), R = 0.0170) its composition and crystal structure are determined. Parameters of the trigonal unit cell are: a = b = 9.8001(1) Å c = 58.7095(8) Å, V = 4883.15(10) Å3, Z = 6, space group R \( \bar 3 \) c. The crystal structure is composed of three types of polyhedra: MoO4 tetrahedra, HfO6 octahedra, and nine-vertex PrO9. All three types of polyhedra are bonded among themselves by common oxygen vertices of bridging MoO4 tetrahedra forming an openwork three-dimensional structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Zh. G. Bazarova, Yu. L. Tushinova, B. G. Bazarov, et al., Zh. Neorg. Khim., 46, No. 1, 146 (2001).

    CAS  Google Scholar 

  2. Zh. G. Bazarova, E. Yu. Badmaeva, S. F. Solodovnikov, et al., ibid., 49, No. 2, 324 (2004).

    CAS  Google Scholar 

  3. R. F. Klevtsova, S. F. Solodovnikov, Yu. L. Tushinova, et al., J. Struct. Chem., 41, No. 2, 280–284 (2000).

    Article  CAS  Google Scholar 

  4. G. M. Sheldrick, SHELXL-97. Programs for the Refinement of Crystal Structures, Univ. Göttingen, Germany (1997).

    Google Scholar 

  5. V. K. Trunov, V. A. Efremov, and Yu. A. Velikodnyi, Crystal Chemistry and Properties of Binary Molybdates and Tungstates [in Russian], Nauka, Leningrad (1986).

    Google Scholar 

  6. R. F. Klevtsova, A. A. Antonova, and L. A. Glinskaya, Kristallografiya, 25, No. 1, 161 (1980).

    CAS  Google Scholar 

  7. R. F. Klevtsova, L. A. Glinskaya, and N. P. Pasechnyuk, ibid., 22, No. 6, 1191 (1977).

    CAS  Google Scholar 

  8. B. G. Bazarov, R. F. Klevtsova, A. E. Sarapulova, et al., J. Struct. Chem., 46, No. 4, 756–760 (2005).

    Article  CAS  Google Scholar 

  9. H. b Naruke and T. Yamase, J. Solid State Chem., 178, No. 3, 702 (2005).

    Article  CAS  Google Scholar 

  10. V. A. Efremov, N. N. Davydova, and V. K. Trunov, Zh. Neorg. Khim., 33, No. 12, 3001 (1988).

    CAS  Google Scholar 

  11. S. V. Borisov and R. F. Klevtsova, Kristallografiya, 15, No. 1, 38 (1970).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Ulan-Ude, Russia

    B. G. Bazarov, V. G. Grossman, Yu. L. Tushinova, K. N. Fedorov & Zh. G. Bazarova

  2. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    R. F. Klevtsova & L. A. Glinskaya

  3. Institute of Chemistry and Chemical Technology, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Russia

    A. G. Anshits & T. A. Vereshchagina

Authors
  1. B. G. Bazarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Grossman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. F. Klevtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. G. Anshits
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. A. Vereshchagina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yu. L. Tushinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. K. N. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Zh. G. Bazarova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. G. Grossman.

Additional information

Original Russian Text Copyright © 2009 by B. G. Bazarov, V. G. Grossman, R. F. Klevtsova, A. G. Anshits, T. A. Vereshchagina, L. A. Glinskaya, Yu. L. Tushinova, K. N. Fedorov, and Zh. G. Bazarova

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 587–590, May–June, 2009.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bazarov, B.G., Grossman, V.G., Klevtsova, R.F. et al. Crystal structure of binary molybdate Pr2Hf3(MoO4)9 . J Struct Chem 50, 566–569 (2009). https://doi.org/10.1007/s10947-009-0086-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-009-0086-z

Keywords

Search

Navigation