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Thermal stability of new complexes bearing both acrylate and aliphatic amine as ligands

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Abstract

This paper reports the investigation of the thermal stability of a series of new complexes with mixed ligands of the type [M(en)(C3H3O2)2]·nH2O ((1) M=Ni, n=2; (2) M=Cu, n=0; (3) M=Zn, n=2; en=ethylenediamine and (C3H3O2)=acrylate anion). The thermal behaviour steps were investigated in a nitrogen flow. The thermal transformations are complex processes according to TG and DTA curves including dehydration, ethylenediamine elimination as well as acrylate thermolysis. The final products of decomposition are the most stable metal oxides except for complex (2) that generates metallic copper.

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Authors and Affiliations

  1. Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania

    Mihaela Badea, Rodica Olar & Dana Marinescu

  2. Department of Agrochemistry, University of Agronomical Sciences and Veterinary Medicine, Bd. Marasti 59, Bucharest, Romania

    Gina Vasile

Authors
  1. Mihaela Badea
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  2. Rodica Olar
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  3. Dana Marinescu
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  4. Gina Vasile
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Correspondence to Mihaela Badea.

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Badea, M., Olar, R., Marinescu, D. et al. Thermal stability of new complexes bearing both acrylate and aliphatic amine as ligands. J Therm Anal Calorim 92, 205–208 (2008). https://doi.org/10.1007/s10973-007-8765-5

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  • DOI: https://doi.org/10.1007/s10973-007-8765-5

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