Abstract
A short retrospection is given on the development of Mössbauer spectroscopy and on the early period of its application to heterogeneous catalysis in Hungary. Besides the historical view, we present results of recent studies of a latest application on a nanosystem. Namely, catalytic centres in Fe-ZSM-5 are studied by in situ spectroscopy, the results are correlated with parallel activity measurements in the decomposition of N2O. Changes in paramagnetic relaxation features are interpreted as the effects of Fe2+/Fe3+ interconversions. From the analysis, the dominance of the mononuclear species is suggested at lower temperature (620 K). The dinuclear Fe(3+) framework-O-Fe(2+) extra-framework species play probably more expressed role at higher temperatures (∼ 770 K) in the decompositon of nitrous oxide.
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J.A. Dumesic, H. Topsoe: in: Advances in Catalysis, Vol. 26, p. 55. (Eds D.D. Eley, H. Pines, P.B. Weisz) Academic Press, New York (1980).
I. Dézsi, D.L. Nagy, M. Eszterle, L. Guczi: J. de Physique, 40, 76 (1979).
L. Guczi, K. Matusek, I. Manninger, J. Király, M. Eszterle: Preparation of Catalysts II., p. 391. Elsevier, Amsterdam 1979.
L. Guczi, K. Matusek, M. Eszterle: J. Catal., 60, 121 (1979).
L. Guczi: Catal. Rev. Sci. and Eng., 23, 329 (1981).
L. Guczi, Z. Schay, K. Lázár, A. Vizi, L. Markó: Surf. Sci., 106, 516 (1981).
K. Lázár, Z. Schay, L. Guczi: J. Mol. Catal., 17, 205 (1982).
K. Lázár, K. Matusek, J. Mink, S. Dobos, L. Guczi, A. Vizi-Orosz, L. Markó: J. Catal., 87, 163 (1984)
Z. Schay, K. Lázár, J. Mink, L. Guczi: J. Catal., 87, 179 (1984)
K. Lázár, W. M. Reiff, W. Mörke, L. Guczi: J. Catal., 100, 118 (1986).
B.M. Choudary, K. Matusek, K. Lázár, L. Guczi: J. Chem. Soc. Chem. Comm., 592 (1988).
K. Lázár, B.M. Choudary, L. Guczi: Solid State Ionics, 32/33, 1000 (1989).
Z. Schay, K. Lázár, I. Bogyay, L. Guczi: Appl. Catal., 51, 33 (1989)
Z. Schay, K. Lázár, K. Matusek, I. Bogyay, L. Guczi: Appl. Catal., 51, 49 (1989).
Mössbauer Effect Reference and Data Journal, Newsletter sections, a) 26, 116 (2003), b) 31 147 (2008).
M. Blume: Phys. Rev. Lett., 14, 96 (1965)
A. Vértes, L. Korecz, K. Burger: Mössbauer Spectroscopy, Akadémiai Kiadó, p.46. Budapest 1979.
S. Mørup: in: Mössbauer Spectroscopy of Frozen Solutions, (Eds A. Vértes, D. L. Nagy), Akadémiai Kiadó, p. 71. Budapest, 1990.
A. Meagher, V. Nair, R. Sostak: Zeolites, 8, 3 (1988).
R. Kumar, S.K. Date, E. Bill, A. Trautwein: Zeolites, 11, 211 (1991).
G.I. Panov, A.S. Kharitonov, V.I. Sobolev: Appl. Catal., 98, 1 (1993).
A. Heyden, B. Peters, A.T. Bell, F.J. Keil: J. Phys. Chem. B, 109, 1857 (2005).
A.L. Yakovlev, G.M. Zhidomirov, R.A. van Santen: J. Phys. Chem. B, 105, 12297 (2001).
K.A. Dubkov, N.S. Ovanesyan, A.A. Shteinman, E.V. Starokon, G.I. Panov: J. Catal., 207, 341 (2002)
J.B. Taboada, A.R. Overweg, P.J. Koyman, I.W.C.E, Arends, G. Mul: J. Catal., 231, 56 (2005).
M. Schwarze, Z. Sobalik, E.G. Caspary, D. Niznansky: Czechoslovak Journal of Physics, 56, E147 (2006).
K. Lázár, G. Lejeune, R.K. Ahedi, S.S. Shevade, A.N. Kotasthane: J. Phys. Chem. B, 102, 4865 (1998)
K. Lázár, A.N. Kotasthane, P. Fejes: Catalysis Letters, 57, 171 (1999).
K. Lázár, O. Pozdnyakova, A. Wootsch, P. Fejes: Hyperfine Interactions, 167, 779 (2006).
R.G. Burns: Hyperfine Interactions, 91, 739 (1994).
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Guczi, L., Lázár, K. Mössbauer spectroscopy in heterogeneous catalysis: A brief overview and recent study on paramagnetic features detected in catalytic centres of Fe-ZSM-5. React Kinet Catal Lett 96, 335–343 (2009). https://doi.org/10.1007/s11144-009-5506-8
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DOI: https://doi.org/10.1007/s11144-009-5506-8