Abstract
We investigated the magnetic and chemical properties of the roadside soil samples collected from five European and Asian countries. Spots in which cars slowed down and/or accelerated due to the traffic organization (speed limits, junctions, and traffic lights) were selected for sampling. Apart from the Zabrze site (Poland), the magnetic susceptibility and heavy metal contents decreased with increasing distance from the road edge. The highest mass-specific magnetic susceptibility values (χ) were observed in the samples collected from Mumbai (India) and Zabrze (Poland). Moreover, the high contents of Fe, Ni, Mn, and Co were observed in Mumbai, whereas in Zabrze, all the examined elements demonstrated high contents, except for Co. Analyses revealed that magnetite was the main magnetic mineral in the roadside soil samples. The high correlation coefficients (r = 0.87) between the magnetic susceptibility values and the total Fe content demonstrated that Fe occurred mainly as ferrimagnetic particles of technogenic origin resulting from traffic emissions. The traffic origin of the pollutants was also confirmed by the increased contents of the typically anthropogenic metals (Pb, Zn, Cd, and Cu) and a good correlation (r = 0.83) between the Ti and Mo contents, which do not occur in natural associations. The ratio between particular polycyclic aromatic hydrocarbons (PAHs) and high content of PAHs typical for car exhaust also implied traffic as their main source.
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Adachi, K., & Tainosho, Y. (2004). Characterization of heavy metal particles embedded in tire dust. Environmental International, 30(8), 1009–1017.
Bäckström, M., Nilsson, U., Håkansson, K., Allard, B., & Karlsson, S. (2003). Speciation of heavy metals in road runoff and roadside total deposition. Water Air and Soil Pollution, 147, 343–366.
Beckwith, P. R., Ellis, J. B., Revitt, D. M., & Oldfield, F. (1986). Heavy metal and magnetic relationships for urban source sediments. Physics of the Earth and Planetary Interiors, 42, 67–75.
Bhupander, K., Gargi, G., Richa, G., Dev, P., Sanjay, K., & Shekhar, S. C. (2012). Distribution, composition profiles and source identification of polycyclic aromatic hydrocarbons in roadside soil of Delhi, India. Journal of Environment and Earth Science, 2(1), 10–22.
Blume, H. P. (1989). Classification of soils in urban agglomerations. Catena, 16, 268–275.
Bućko, M. S., Magiera, T., Pesonen, L. J., & Janus, B. (2010). Magnetic, geochemical, and microstructural characteristics of road dust on roadsides with different traffic volumes case study from Finland. Water, Air, and Soil Pollution, 209, 295–306.
Bućko, M. S., Magiera, T., Johanson, B., Petrovský, E., & Pesonen, L. J. (2011). Identification of magnetic particulates in road dust accumulated on roadside snow using magnetic, geochemical and micro-morphological analyses. Environmental Pollution, 159, 1266–1276.
Budzinski, H., Jones, I., Bellocq, J., Piérard, C., & Garrigues, P. (1997). Evaluation of sediment contamination by polycyclic aromatic hydrocarbons in the Gironde estuary. Marine Chemistry, 58, 85–97.
Chaparro, M. A. E., Marie, D. C., Gogorza, C. S. G., Navas, A., & Sinito, A. M. (2010). Magnetic studies and scanning electron microscopy-X-ray energy dispersive spectroscopy analyses of road sediments, soils and vehicle-derived emissions. Studia Geophysica et Geodeatica., 54, 633–650.
Chen, X., Xia, X., Zhao, Y., & Zhang, P. (2010). Heavy metal concentrations in roadside soils and correlation with urban traffic in Beijing, China. Journal of Hazardous Materials, 181, 640–646.
D’Emilio, M., Caggiano, R., Macchiato, M., Ragosta, M., & Sabia, S. (2012). Soil heavy metal contamination in an industrial area: analysis of the data collected during a decade. Environmental Monitoring and Assessment, 185(7), 5951–5964.
Davis, A. P., Shokouhian, M., & Shubei, N. S. (2001). Loading estimates of lead, copper, cadmium, and zinc in urban runoff from specific sources. Chemosphere, 44, 997–1009.
Day, R., Fuller, M., & Schmidt, V. A. (1977). Hysteresis properties of titanomagnetites: grain size and compositional dependence. Physics of the Earth and Planetary Interiors, 13, 260–267.
Dearing, J., Dann, R., Hay, K., Lees, J., Loveland, P., Maher, B., & O’Grady, K. (1996). Frequency-dependent susceptibility measurements of environmental materials. Geophysical Journal International, 124, 228–240.
Dunlop, D. J. (2002). Theory and application of the Day plot (Mrs/Ms versus Hcr/Hc) 1. Theoretical curves and tests using titanomagnetite data. Journal of geophysical Research, 107(B3), 1–22.
Duong, T. T. T., & Lee, B.-K. (2011). Determining contamination level of heavy metals in road dust from busy traffic areas with different characteristics. Journal of Environmental Management, 92, 554–562.
Duval, M.M., & Friedlander, S.K., (1981). Source resolution of polycyclic aromatic hydrocarbons in Los Angeles atmosphere. Washington DC: US Environmental Protection Agency, [EPA-600/2-81-161].
Fergusson, J. E. (1986). Lead: petrol lead in the environment and its contribution to human blood lead levels. Science of the Total Environment, 50, 1–54.
Flanders, P. J. (1994). Collection, measurement, and analysis of airborne magnetic particulates from pollution in the environment. Journal of Applied Physics, 75, 5931–5936.
Fromme, H., Oddoy, A., Piloty, M., Krause, M., & Lahrz, T. (1998). Polycyclic aromatic hydrocarbons (PAH) and diesel engine emission (elemental carbon) inside a car and subway train. Science of the Total Environment, 217(1–2), 165–173.
Gautam, P., Blaha, U., & Appel, E. (2005). Magnetic susceptibility of dust-loaded leaves as a proxy of traffic related heavy metal pollution in Kathmandu city, Nepal. Atmospheric Environment, 39(12), 2201–2211.
Goddu, S. R., Appel, E., Jordanova, D., & Wehland, R. (2004). Magnetic properties of road dust from Visakhapatnam (India)—relationship to industrial pollution and road traffic. Physics and Chemistry of the Earth, 29(13,14), 985–995.
Halsall, C. J., Maher, B. A., Karloukovski, V. V., Shah, P., & Watkins, S. J. (2008). A novel approach to investigating indoor/outdoor pollution links: combined magnetic and PAH measurements. Atmospheric Environment, 42, 8902–8909.
Hildemann, L. M., Markowski, G. R., & Cass, G. R. (1991). Chemical-composition of emissions from urban sources of fine organic aerosol. Environmental Science and Technology, 25, 744–759.
Ho, Y. B., & Tai, K. M. (1988). Elevated levels of lead and other metals in roadside soil and grass and their use to monitor aerial metal depositions in Hong Kong. Environmental Pollution, 49, 37–51.
Hoffmann, V., Knab, M., & Appel, E. (1999). Magnetic susceptibility mapping of roadside pollution. Journal of Geochemical Exploration, 66, 313–326.
Hunt, A., Jones, J. M., & Oldfield, F. (1984). Magnetic measurements and heavy metals in atmospheric particulates of anthropogenic origin. Science of the Total Environment, 33, 129–139.
Iijima, A., Sato, K., Yano, K., Tago, H., Kato, M., Kimura, H., & Furuta, N. (2007). Particle size and composition distribution analysis of automotive brake abrasion dusts for the evaluation of antimony sources of airborne particulate matter. Atmospheric Environment, 41, 4908–4919.
Jordanova, N., Jordanova, D., & Tsacheva, T. (2008). Application of magnetometry for delineation of anthropogenic pollution in areas covered by various soil types. Geoderma, 144, 557–571.
Jordanova, D., Petrosv, P., Hoffmann, V., Gocht, T., Panaiotu, C., Tsacheva, T., & Jordanova, N. (2010). Magnetic signature of different vegetation species in polluted environment. Studia Geophysica et Geodetica, 54(3), 417–442.
Jordanova, D., Jordanova, N., Lanos, P., Petrov, P., & Tsacheva, T. (2012). Magnetism of outdoor and indoor settled dust and its utilization as a tool for revealing the effect of elevated particulate air pollution on cardiovascular mortality. Geochemistry Geophysicists Geosystems, 13, Q08Z49. doi:10.1029/2012GC004160.
Jordanova, D., Jordanova, N., & Petrov, P. (2014). Magnetic susceptibility of road deposited sediments at a national scale—relation to population size and urban pollution. Environmental Pollution, 189, 239–251.
Kavouras, I., Lawrence, J., Koutrakis, P., Stephanou, E., & Oyola, P. (1999). Measurements of particulate aliphatic and polynuclear aromatic hydrocarbons in Santiago de Chile: source reconciliation and evaluation of sampling artifacts. Atmospheric Environment, 33, 4977–4986.
Kavouras, I. G., Koutrakis, P., Tsapakis, M., Lagoudaki, E., Stephanou, E. G., Von Baer, D., & Oyola, P. (2001). Source apportionment of urban particulate aliphatic and polynuclear aromatic hydrocarbons (PAHs) using multivariate methods. Environmental Science and Technology, 35, 2288–2294.
Kennedy, P., & Gadd, J. (2003). Preliminary examination of trace elements in tires, brake pads, and road bitumen in New Zealand. New Zealand: Prepared for Ministry of Transport.
Khaiwal, R., Bencs, L., Wauters, E., Hoog, J. D., Deutsch, F., Roekens, E., Bleux, N., Berghmans, P., & Grieken, R. V. (2006). Seasonal and site-specific variation in vapour and aerosol phase PAHs over Flanders (Belgium) and their relation with anthropogenic activities. Atmospheric Environment, 40, 771–785.
Khalili, N. R., Scheff, P. A., & Holsen, T. M. (1995). PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels, and wood combustion emissions. Atmospheric Environment, 29, 533–542.
Khan, A., Ishaq, M., & Khan, M. A. (2008). Effect of vehicle exhaust on the quantity of polycyclic aromatic hydrocarbons (PAHs) in soil. Environmental Monitoring and Assessment, 137(1–3), 363–369.
Khan, M. N., Wasim, A. A., Sarwar, A., & Rasheed, M. F. (2011). Assessment of heavy metal toxicants in the roadside soil along the N-5, National Highway, Pakistan. Environmental Monitoring and Assessment, 182(1–4), 587–595.
Kim, W., Doh, S.-J., & Yu, Y. (2009). Anthropogenic contribution of magnetic particulates in urban roadside dust. Atmospheric Environment, 43, 3137–3144.
Lin, C.-C., Chen, S.-J., & Huang, K. L. (2005). Characteristics of metals in nano/ultrafine/fine/coarse particles collected beside a heavily trafficked road. Environmental Science and Technology, 39, 8113–8122.
Long, Y., Chi, G., Qing, H., Dai, T., & Wu, Q. (2011). Sources of polycyclic aromatic hydrocarbons in street dust from the Chang-Zhu-Tan Region, Hunan, China. Journal of Environmental Protection, 2(10), 1331–1340.
Lu, S. G., Wang, H. Y., & Guo, J. L. (2011). Magnetic enhancement of urban roadside soils as a proxy of degree of pollution by traffic-related activities. Environmental Earth Sciences, 64(2), 359–371.
Magiera, T., Strzyszcz, Z., & Rachwał, M. (2007). Mapping particulate pollution loads using soil magnetometry in urban forests in Upper Silesia Industrial Region. Poland, Forest Ecology and Management, 248, 36–42.
Maher, B. A. (1998). Magnetic properties of modern soils and loessic paleosols: implications for paleoclimate. Paleogeography, Paleoclimatology, Paleoecology, 137, 25–54.
Maher, B. A., Moore, C., & Matzka, J. (2008). Spatial variation in vehicle-derived metal pollution identified by magnetic and elemental analysis of roadside tree leaves. Atmospheric Environment, 33, 2967–2977.
Marie, D. C., Chaparro, M. A. E., Gogorza, C. S. G., Navas, A., & Sinito, A. M. (2010). Vehicle-derived emissions and pollution on the road Autovia2 investigated by rock-magnetic parameters: a case of study from Argentina. Studia Geophysica et Geodeatica, 54, 135–152.
Marr, L. C., Kirchstetter, T. W., Harley, R. A., Miguel, A. H., Herring, S. V., & Hammond, S. K. (1999). Characterization of polycyclic aromatic hydrocarbons in motor vehicle fuels and exhaust emissions. Environmental Science and Technology, 33, 3091–3099.
Mastral, A., & Callen, M. S. (2000). A review on PAH emissions from energy generation. Environmental Science and Technology, 34, 3051–3057.
Miguel, A. H., Kirchstetter, T. W., & Harley, R. A. (1998). On-road emissions of particulate polycyclic aromatic hydrocarbons and black carbon from gasoline and diesel vehicles. Environmental Science and Technology, 32, 450–455.
Neilson, A. H. (1998). The handbook of environmental chemistry 3 J: PAHs and related compounds biology (pp. 312–350). Berlin: Springer.
Nguyen, T. C., Loganathan, P., Nguyen, T. V., Vigneswaran, S., Kandasamy, J., Slee, D., Stevenson, G., & Naidu, R. (2014). Polycyclic aromatic hydrocarbons in road-deposited sediments, water sediments, and soils in Sydney, Australia: comparisons of concentration distribution, sources and potential toxicity. Ecotoxicology and Environmental Safety, 104, 339–348.
Olson, K. W., & Skogerboe, R. K. (1975). Identification of soil lead compounds from automotive sources. Environmental Science and Technology, 9, 227–230.
Pio, C. A., Alves, C. A., & Duarte, A. C. (2001). Identification, abundance and origin of atmospheric organic particulate matter in a Portuguese rural area. Atmospheric Environment, 35, 1365–1375.
Qiao, M., Cai, C., Huang, Y., Liu, Y., Lin, A., & Zheng, Y. (2011). Characterization of soil heavy metal contamination and potential health risk in metropolitan region of northern China. Environmental Monitoring and Assessment, 172(1–4), 353–365.
Sagnotti, L., Macrì, P., Egli, R., & Mondino, M. (2006). Magnetic properties of atmospheric particulate matter from automatic air sampler stations in Latium (Italy): toward a definition of magnetic fingerprints for natural and anthropogenic PM10 sources. Journal of Geophysical Research, 111, B12S22.
Sagnotti, L., Taddeucci, J., Winkler, A., & Cavallo, A. (2009). Compositional, morphological, and hysteresis characterization of magnetic airborne particulate matter in Rome, Italy. Geochemistry, Geophysics, Geosystems, 10(8).
Strzyszcz, Z. (1993). Magnetic susceptibility of soils in the areas influenced by industrial emissions. In R. Schulin (Ed.), Soil monitoring (pp. 255–269). Monte Verita: BirkhäuserVerlag Basel.
Strzyszcz, Z., Magiera, T., & Heller, F. (1996). The influence of industrial immisions on the magnetic susceptibility of soils in Upper Silesia. Studia Geophysica et Geodetica, 40, 276–286.
Takada, H., Onda, T., & Ogura, T. (1990). Determination of polycyclic aromatic hydrocarbons in urban street dusts and their source materials by gas chromatography. Environmental Science and Technology, 24, 1179–1186.
Thorpe, A., & Harrison, R. M. (2008). Sources and properties of non-exhaust particulate matter from road traffic: a review. Science of the Total Environment, 400, 270–282.
Wahlin, P., Berkowicz, R., & Palmgren, F. (2006). Characterization of traffic generated particulate matter in Copenhagen. Atmospheric Environment, 40, 2151–2159.
Wang, D. G., Tian, F. L., Yang, M., Liu, C. L., & Li, Y. F. (2009). Application of positive matrix factorization to identify potential sources of PAHs in soil of Dalian, China. Environmental Pollution, 157(5), 1559–1564.
Ward, N.I., Brooks, R.R., Roberts, E., & Boswell, C.R. (1977). Heavy-metal pollution from automotive emissions and its effect on roadside soils and pasture species in New Zealand, Environmental Science Technology, Vol/Issue: 11:9.
Wawer, M., Magiera, T., Ojha, G., Appel, E., Busoils, A. S., & Kusza, G. (2015). Characteristics of current roadside pollution using test-monitoring plots. Science of the Total Environment, 505, 759–804.
Westerlund K.-G. (2001). Metal emissions from Stockholm traffic—wear of brake lining. Report from SLB-Analys, p. 3.
White, P. A., Rasmussen, J. B., & Blaise, C. (1998). Genotoxic substances in the St. Lawrence system I: industrial genotoxins sorbed to particulate matter in the St. Lawrence, St. Maurice and Saguenay Rivers, Canada. Environmental Toxicological Chemistry, 17, 286–303.
Yunker, M. B., Macdonald, R. W., Vingarzan, R., Mitchell, R. H., Goyette, D., & Sylvestre, S. (2002). PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition. Organic Geochemistry, 33, 489–515.
Zhang, X. Y., Lin, F. F., Wong Mike, T. F., Feng, X. L., & Wang, K. (2009). Identification of soil heavy metal sources from anthropogenic activities and pollution assessment of Fuyang County, China. Environmental Monitoring and Assessment, 154, 439–449.
Acknowledgments
This research was financially supported by the Ministry of Science and Higher Education and National Science Centre in collaboration with the German Research Foundation under scientific project no. 676/N-DFG/2010/0 entitled “Characteristics of current roadside pollution under different environmental conditions – fundamentals for the development of a new roadside pollution monitoring concept”. The authors thank the professional ProofreadingServices.com for language corrections. We appreciate the constructive comments by an anonymous reviewer.
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Wawer, M., Magiera, T., Ojha, G. et al. Traffic-Related Pollutants in Roadside Soils of Different Countries in Europe and Asia. Water Air Soil Pollut 226, 216 (2015). https://doi.org/10.1007/s11270-015-2483-6
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DOI: https://doi.org/10.1007/s11270-015-2483-6