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Increase in Pb and Cd Adsorption by the Application of Peat in a Tropical Soil

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Abstract

Clayey soils have been used as liners at the base of waste deposits due to their geotechnical characteristics and capacity to adsorb metallic cations. However, a number of soils may not possess all required properties to ensure contaminant retention and therefore require additives. This study investigated whether the addition of commercial peat to a tropical residual soil (from the Ribeira Valley, Brazil) could improve its lead (Pb) and cadmium (Cd) adsorption capacity for its use as a liner in mining waste disposal. Pure soil and 10 and 20% soil-peat mixtures were compared. The application of peat increased the organic matter (OM) content (from 9 g kg−1 in soil to 58 g kg−1 in the 20% soil-peat mixture) and the cationic exchange capacity (CEC) (from 41.4 mmolc dm−3 in soil to 143.1 mmolc dm−3 in the 20% soil-peat mixture). Batch equilibrium test results revealed that the maximum Pb adsorption capacity of 623.6 μg g−1 also increased (to 1089.1 and 1270.0 μg g−1 in the 10 and 20% soil-peat mixtures, respectively). The soil Cd adsorption capacity of 261.2 μg g−1 increased to 304.0 and 631.3 μg g−1, respectively, with increasing peat proportions. The results suggest that peat can improve soil liner performance in waste deposits. Soil-peat mixtures are alternatives for minimizing potentially toxic metal contamination with available and low-cost materials.

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The authors thank the São Paulo Research Foundation (FAPESP) for the provided Master’s degree grants (2016/17894-2 and 2015/02529-4) and research grant (2014/07180-7) and the National Council for Scientific and Technological Development (CNPq) for the offered research productivity grant (305096/2015-0).

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  1. Department of Geotechnical Engineering, São Carlos School of Engineering, University of São Paulo, 400 Trabalhador Sãocarlense Ave., São Carlos, 13566-590, Brazil

    Jéssica Pelinsom Marques, Valéria Guimarães Silvestre Rodrigues, Isabela Monici Raimondi & Jacqueline Zanin Lima

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  1. Jéssica Pelinsom Marques
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Pelinsom Marques, J., Silvestre Rodrigues, V.G., Monici Raimondi, I. et al. Increase in Pb and Cd Adsorption by the Application of Peat in a Tropical Soil. Water Air Soil Pollut 231, 136 (2020). https://doi.org/10.1007/s11270-020-04507-z

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