Skip to main content
Log in

Novel natural phenolic compound-based oxygen scavenging system for active packaging applications

  • Original Paper
  • Published:
Journal of Food Measurement and Characterization Aims and scope Submit manuscript

ABSTRACT

An oxygen scavenging system containing a natural phenolic compound, pyrogallol with sodium carbonate, was developed and analyzed as a possible oxygen scavenger. The effect of several parameters, including the amount of pyrogallol and sodium carbonate, relative humidity and storage temperature, on the oxygen scavenging capability were investigated. The initial, glass vial headspace oxygen content (%) of 21.1 % (v/v) decreased to 0.26 % after 8 days of storage at room temperature when the oxygen scavenging system used a 1:1 (w/w) ratio of pyrogallol (250 mg) and sodium carbonate (250 mg). Both pyrogallol and sodium carbonate were required for optimum oxygen scavenging, otherwise the oxygen scavenging ability decreased. The oxygen content (%) decreased further to 6.55 % (v/v) when the amount of sodium carbonate decreased from 250 to 166 mg, which yielded a 2:1 ratio. In the present study, pyrogallol (250 mg) and sodium carbonate (250 mg) had highest oxygen scavenging capacity of 51.81 mL O2/g and an oxygen scavenging rate of 6.48 mL O2/g day. The oxygen absorption kinetics rate of pyrogallol and sodium carbonate confirmed that the material has good efficiency for use as an oxygen scavenger. Results indicated that the pyrogallol based oxygen scavenging system with moisture activation can be used as an effective oxygen scavenger for low water activity food packaging applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. M. Zhang, X. Meng, B. Bhandari, Z. Fang, Recent developments in film and gas research in modified atmosphere packaging of fresh foods. Crc. Cr. Rev. Food. Sci. (2015). doi:10.1080/10408398.2013.819794

    Google Scholar 

  2. G. S. Tucker (2008) Food biodeterioration and preservation. Wiley

  3. Z. Damaj, C. Joly, E. Guillon, Toward new polymeric oxygen scavenging systems: Formation of poly (vinyl alcohol) oxygen scavenger film. Packag. Technol. Sci. 28(4), 293–302 (2015)

    Article  CAS  Google Scholar 

  4. K.K. Gaikwad, J.Y. Lee, Y.S. Lee, Development of polyvinyl alcohol and apple pomace bio-composite film with antioxidant properties for active food packaging application. J. Food. Sci. Tech. Mys. (2015). doi:10.1007/s13197-015-2104-9

    Google Scholar 

  5. J. Gilman, L. Jacxsens, B. De Meulenaer, F. Devlieghere, Modified atmosphere packaging and irradiation to preserve contemporary food-based art: An experimental study. J. Cult. Herit. 16(3), 391–397 (2015)

    Article  Google Scholar 

  6. Y. Byun, D. Darby, K. Cooksey, P. Dawson, S. Whiteside, Development of oxygen scavenging system containing a natural free radical scavenger and a transition metal. Food. Chem. 124(2), 615–619 (2011)

    Article  CAS  Google Scholar 

  7. S.E. Solovyov, Oxygen scavengers. Kirk-Othmer encyclopedia of chemical technology (Wiley, Hoboken, 2014)

    Google Scholar 

  8. L. Vermeiren, L. Heirlings, F. Devlieghere, J. Debevere, Oxygen, ethylene and other scavengers (Elsevier, Novel. food. packaging. techniques., 2003), pp. 22–49

    Google Scholar 

  9. M.L. Roony, Active food packaging (Blackie Academic and professional, In active food packaging. New York, 1995)

    Book  Google Scholar 

  10. I.S. Arvanitoyannis, A.C. Stratakos, Application of modified atmosphere packaging and active/smart technologies to red meat and poultry: a review. Food. Bioprocess. Tech. 5(5), 1423–1446 (2012)

    Article  CAS  Google Scholar 

  11. T. Cecchi, P. Passamonti, P. Cecchi, Study of the quality of extra virgin olive oil stored in PET bottles with or without an oxygen scavenger. Food. Chem. 120(3), 730–735 (2010)

    Article  CAS  Google Scholar 

  12. R. Joven, A. Garcia, A. Arias, J. Medina, Development of an Active thermoplastic film with oxygen scavengers made of activated carbon and sodium erythorbate. Packag. Technol. Sci. 28(2), 113–121 (2015)

    Article  CAS  Google Scholar 

  13. J. Camo, J.A. Beltrán, P. Roncalés, Extension of the display life of lamb with an antioxidant active packaging. Meat. Sci. 80(4), 1086–1091 (2008)

    Article  CAS  Google Scholar 

  14. D.V. Speer, C.R. Morgan, W.P. Roberts, A.W. Vanputte, Patent 5,350,622 1994

  15. B. Cemeroglu, S. Velioglu, S. Isik, Degradation kinetics of anthocyanins in sour cherry juice and concentrate. J. Food. Sci. 59(6), 1216–1218 (1994)

    Article  CAS  Google Scholar 

  16. E. Maccarone, V. Ferrigno, M.L. Longo, P. Rapisarda, Effects of light on anthocyanins-kinetics and photo degradation products in acidic aqueous-solutions. Ann. Chim.-Rome. 77(5–6), 499–508 (1987)

    CAS  Google Scholar 

  17. G. Jing, H. Huang, B. Yang, J. Li, X. Zheng, Y. Jiang, Effect of pyrogallol on the physiology and biochemistry of litchi fruit during storage. Chem. Cent. J. 7(1), 19 (2013)

    Article  CAS  Google Scholar 

  18. Y. Matsuo, F. Tadakuma, T. Shii, Y. Saito, T. Tanaka, Selective oxidation of pyrogallol-type catechins with unripe fruit homogenate of Citrus unshiu and structural revision of oolongtheanins. Tetrahedron 71(17), 2540–2548 (2015)

    Article  CAS  Google Scholar 

  19. P.B. Messersmith, T.S. Sileika, R. Zhang, Barrett DG (2014) U.S. Patent Application No. 14/187,741

  20. T.S. Sileika, D.G. Barrett, R. Zhang, K.H.A. Lau, P.B. Messersmith, Colorless multifunctional coatings inspired by polyphenols found in tea, chocolate, and wine. Angew. Chem. Int. Edit. 52(41), 10766–10770 (2013)

    Article  CAS  Google Scholar 

  21. H.I. Abrash, The air oxidation of 4, 6-di (2-phenyl-2-propyl) pyrogallol. Spectroscopic and kinetic studies of the intermediates. Carlsberg. Res. Commun. 42(1), 11–25 (1977)

    Article  CAS  Google Scholar 

  22. K. Johansson, S. Winestrand, C. Johansson, L. Järnström, L.J. Jönsson, Oxygen-scavenging coatings and films based on lignosulfonates and laccase. J. Biotechnol. 161(1), 14–18 (2012)

    Article  CAS  Google Scholar 

  23. M.R. Galdi, Design and production of active films for food packaging application (Universita Degali studi di salerno, PhD Course in Chemical Engineering, 2006)

    Google Scholar 

  24. F. Charles, J. Sanchez, N. Gontard, Absorption kinetics of oxygen and carbon dioxide scavengers as part of active modified atmosphere packaging. J. Food. Eng. 72(1), 1–7 (2006)

    Article  CAS  Google Scholar 

  25. G.D. Jerdee, J.P. Leonard, T.Y. Ching, J.L. Goodrich, B.D. Rodgers, R.P. Schmidt, US patent 6,569,506 (2003)

  26. E.D. Cardona, M.P. Noriega, J.D. Sierra, Oxygen scavengers impregnated in porous activated carbon matrix for food and beverage packaging applications. J. Plast. Film. Sheet. 28(1), 63–78 (2011)

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to thanks One Jung Can (OJC) Manufacturing Co., Ltd. Seoul, South Korea. This research study is a part of project title “Development of oxygen scavenging package for fish cake” (Project number: 2015-51-0311).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Youn Suk Lee.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gaikwad, K.K., Lee, Y.S. Novel natural phenolic compound-based oxygen scavenging system for active packaging applications. Food Measure 10, 533–538 (2016). https://doi.org/10.1007/s11694-016-9332-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11694-016-9332-1

Keywords

Navigation