Abstract
A hybrid polymeric coating (PDMS–CNPrTEOS) with sorbent properties was prepared by the sol–gel method from hydroxyl-terminated poly(dimethylsiloxane) (OH-PDMS), and cyanopropyltriethoxysilane (CNPrTEOS) as an inorganic precursor, using trifluoroacetic acid (TFA) as a catalyst. A coating with the sol–gel solution was prepared on glass plates using the dip-coating method and subsequently characterized. Characterization by FTIR shows that cyano groups are present on the surface coating and contact angle tests show that the coating presents hydrophilic characteristics. The organic–inorganic polymer was stable up to 400 °C with a weight loss of 8 wt % and showed good stability after immersion for 60 min in vortex and 45 min in ultrasonic bath, in various solvents: water, methanol (MeOH), acetone, isooctane, ethyl acetate (AcOEt) and acetonitrile (ACN), and solutions at different pH (1–12) for 48 h (h). The PDMS–CNPrTEOS hybrid polymer was evaluated and was found to have the ability to extract simultaneously furanic compounds in aqueous solution when it is employed as a sorbent for stir bar sorptive extraction (SBSE).
Similar content being viewed by others
References
Alcázar A, Jurado JM, Pablos F, González G, Martín M (2006) HPLC determination of 2-furaldehyde and 5-hydroxymethyl-2-furaldehyde in alcoholic beverages. Microchem J 82:22–28. doi:10.1016/j.microc.2005.06.005
Almeida CN (2006) Determination of steroid sex hormones in water and urine matrices by stir bar sorptive extraction and liquid chromatography with diode array detection. J Pharm Biomed Anal 41:1303–1311. doi:10.1016/j.jpba.2006.02.037
Attia SM, Wang J, Wu GM, Shen J, Ma JH (2002) Review on sol–gel derived coatings: process, techniques and optical applications. J Mater Sci Technol 18:211–217
Ballistreri A, Garozzo D, Montaudo G (1984) Mass spectral characterization and thermal descomposition mechanism of poly(dimethylsiloxane). Macromolecules 7:1312–1315. doi:10.1021/ma00137a003
Bange JP, Patil LS, Gautam DK (2008) Growth and characterization of sio2 films deposited by flame hydrolysis deposition system for photonic device application. Prog Electromagn Res 3:165–175. doi:10.2528/PIERM0806040
Caruso R, Díaz-Parralejo A, Miranda P, Guiberteau F (2001) Controlled preparation and characterization of multilayer sol–gel zirconia dip-coatings. J Mater Res 16:2391–2398. doi:10.1557/JMR.2001.0328
Dimitriev Y, Ivanova Y, Iordanova R (2008) History of sol–gel science and technology (review). J Univ Chem Technol Metall 43:181–192. doi:10.1002/chin.200912249
Duraibabu D, Ganeshbabu T, Saravanan P, Anandar AS (2014) Development and characterization of novel organic-inorganic hybrid sol–gel films. High Perform Polymer 26:725–733. doi:10.1177/0954008314528225
Durán Guerrero R, Castro Mejías R, García Barroso C (2006) Optimisation of stir bar sorptive extraction applied to the determination of volatile compounds in vinegars. J Chromatogr A 1104:47–53. doi:10.1016/j.chroma.2007.07.058
El Hadad AA, Carbonell D, Barranco V, Jiménez-Morales A, Casal B, Galván JC (2011) Preparation of sol–gel hybrid materials from γ-methacryloxypropyltrimethoxysilane and tetramethyl orthosilicate: study of the hydrolysis and condensation reactions. Colloid Polym Sci 289:1875–1883. doi:10.1007/s00396-011-2504-y
Frank D, Pat S (2007) Stir bar sorptive extraction for trace analysis. J Chromatogr A 1152:54–69. doi:10.1016/j.chroma.2007.01.032
Giordano A, Fernández-Franzón M, Ruiz MJ, Font G, Picó Y (2009) Pesticide residue determination in Surface waters by stir bar sorptive extraction and liquid chromatography/tandem mass spectrometry. Anal Bioanal Chem 393:1733–1743. doi:10.1007/s00216-009-2627-x
Hu Y, Zheng Y, Zhu F, Li G (2007) Sol–gel coated polydimtehylsoloxane/β-cyclodextrin as novel stationary phase for stir bar sorptive extraction and its application to analysis of estrogens and bisphenol A. J Chromatogr A 1148:16–22. doi:10.1016/j.chroma.2007.02.101
Kawaguchi M, Ito R, Saito K, Nakazawa H (2006) Novel Stir bar sorptive extraction methods for environmental and biomedical analysis. J Pharm Biomed Anal 40:500–508. doi:10.1016/j.jpba.2005.08.029
Kloskowski A, Pilarczyk MI, Chrzanowski W, Namiesnik J (2010) Sol–gel technique-A versatile tool for adsorbent preparation. Crit Rev Anal Chem 40:172–186. doi:10.1080/10408347.2010.490486
Lan B, Yu C (2010) pH-resistant titania hybrid organic–inorganic coating for stir bar sorptive extraction of drugs of abuse in urine samples followed by high performance liquid chromatography–ultraviolet visible detection. J Chromatogr A 1217:7003–7009. doi:10.1016/j.chroma.2010.09.006
Liu L, Sheardown H (2005) Glucose permeable poly (dimethyl siloxane) poly (N-isopropyl acrylamide) interpenetrating networks as ophthalmic biomaterials. Biomaterials 26:233–244. doi:10.1016/j.biomaterials.2004.02.025
Liu W, Wang H, Guan Y (2004) Preparation of stir bars for sorptive extraction using sol–gel technology. J Chromatogr A 1045:15–22. doi:10.1016/j.chroma.2004.06.036
Montero H, Poppa P (2005) Determination of phenols in lake and ground water samples by stir bar sorptive extraction-thermal desorption-gas chromatography-mass spectrometry. J Chromatogr A 1071:163–169. doi:10.1016/j.chroma.2005.01.097
Neng NR, Pinto MP, Pires J, Marcos MP, Nogueira JMF (2007) Development, optimisation and application of polyurethane foams as new polymeric phases for stir bar sorptive extraction. J Chromatogr A 1171:8–14. doi:10.1016/j.chroma.2007.09.033
Nie S, Huang G, Zhang Y, Hua J, Wang S, Shen M, Li C, Mancorte M, Xie M (2013) Analysis of furan in heat-processed foods in China by automated headspace gas chromatography-mass spectrometry (HS–GC–MS). Food Control 30:62–68. doi:10.1016/j.foodcont.2012.07.020
Park JT, Seo JA, Ahn SH, Kim JH, Kang SW (2010) Surface modification of silica nanoparticles with hydrophilic polymers. J Ind Eng Chem 17:517–522. doi:10.4038/jnsfsr.v42i4.7734
Prieto A, Rodil R, Usobiaga A, Fernández LA, Etxebarria N, Zuloaga O (2010) Stir-bar sorptive extraction: a view on method optimisation, novel applications, limitations and potential solutions. J Chromatogr A 1217:2642–2666. doi:10.1016/j.chroma.2009.12.051
Rao AV, Gurav AB, Latthe SS, Vhatkar RS, Imai H, Kappenstein C, Wagh PB, Gupta SC (2010) Water repellent porous silica films by sol–gel dip coating method. J Colloid Interface Sci 352:30–35. doi:10.1016/j.jcis.2010.08.003
Ridgwaya K, Lalljie S, Smith RM (2010) The use of stir bar sorptive extraction—a potential alternative method for the determination of furan, evaluated using two example food matrices. Anal Chim Acta 657:169–174. doi:10.1016/j.aca.2009.10.046
Rodil R, Moeder M (2008) Development of a method for the determination of UV filters in water samples using stir bar sorptive extraction and thermal desorption-gas chromatography-mass spectrometr. J Chromatogr A 1179:81–88. doi:10.1016/j.chroma.2007.11.090
Sánchez-Rojas FB, Bosch-Ojeda JM, Cano-Pavón J (2009) A review of stir bar sorptive extraction. Chromatographia 69:79–94. doi:10.1365/s10337-008-0687-2-2008
Vera-Graciano R, Hernández-Sanchez F, Cauich-Rodríguez JV (1995) Study of crosslinking density in polydimethylsiloxane networks by DSC. J Appl Polym Sci 55:1317–1327. doi:10.1002/app.1995.070550905
Wan Ibrahim WA, Wan Ismail WN, Abdul Keyon AS, Marsin Sanagi M (2011a) Preparation and characterization of a new sol–gel hybrid based tetraethoxysilane-polydimethylsiloxane as a stir bar extraction sorbent materials. J Sol–Gel Sci Technol 58:602–611. doi:10.1007/s10971-011-2434-7
Wan Ibrahim WA, Abdul Keyon AS, Prastomo N, Matsuda A (2011b) Synthesis and characterization of polydimethylsiloxane-cyanopropyltriethoxysilane-derived hybrid coating for stir barsorptive extraction. J Sol–Gel Sci Technol 59:128–134. doi:10.1007/s10971-011-2470-3
Acknowledgements
This work was supported by the Consejo Nacional de Ciencia y Tecnología, CONACyT (CB-167800). The authors are grateful to M. en C. Alejandra Núñez Pineda for her technical support in TGA measurements.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Burgos-Tan, M.J., Pérez-Padilla, Y., Avila-Ortega, A. et al. Preparation, characterization and evaluation of a hybrid polymeric coating with sorbent properties. Chem. Pap. 71, 1205–1215 (2017). https://doi.org/10.1007/s11696-016-0113-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11696-016-0113-4