Skip to main content
Log in

Effect of Mo on mechanical properties of modified ultrahigh carbon steels after heat-treatment

  • Published:
Journal of Central South University Aims and scope Submit manuscript

Abstract

Microstructure and mechanical properties of modified ultrahigh carbon (1.6%C) steels with different Mo additions (0, 0.3%, 0.5%, and 0.8%, mass fraction) were studied in their as-cast and quenched then tempered conditions by optical microscopy, scanning electronic microscopy, X-ray diffraction and hardness and toughness tests, respectively. The results show that the continuous eutectic carbide network structure has been broken down and changed to partial isolated and finer particles embedded in matrix of as-cast alloy by modification. Carbides in both quenched and tempered specimens have been refined effectively after the addition of Mo. Specimen containing 0.5% Mo shows the finest microstructures with carbides dispersed homogeneously in martensite matrix and demonstrates highest impact toughness of 18.4 J/cm2 and hardness of 50 HRC.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. VICTORIA-HERNÁNDEZ J, HERNÁNDEZ-SILVA D, VITE-TORRES M. Microstructural characterization and sliding wear behavior of ultra high carbon steels processed by mechanical alloying [J]. Wear, 2009, 267(1/2/3/4): 340–344.

    Article  Google Scholar 

  2. WADSWORTH J, LESUER D R. Ancient and modern laminated composites from the great pyramid of gizeh to Y2K [J]. Materials Characterization, 2000, 45(4/5): 289–313.

    Article  Google Scholar 

  3. LESUER D R, SYN C K, GOLDBERG A, WADSWORTH J, SHERBY O D. The case for ultrahigh carbon steels as structural materials [J]. Journal of the Minerals, Metals and Materials Society, 1993, 45(8): 40–46.

    Article  Google Scholar 

  4. OYAMA T, SHERBY O D, WADSWORTH J, WALSER B. Application of the divorced eutectoid transformation to the development of fine-grained, spheroidized structures in ultrahigh carbon steels [J]. Scripta Metallurgica, 1984, 18(8): 799–804.

    Article  Google Scholar 

  5. MA Q, LIU B C, WANG Z C. Breakup of eutectic carbide network of white cast irons at high temperatures [J]. Journal of Materials Science, 1995, 30(13): 3383–3386.

    Article  Google Scholar 

  6. ZHANG Z L, LIU Y N, ZHU J W, YU G. Processing and properties of ultrahigh-carbon (1.6%C) steel [J]. Materials Science and Engineering A, 2008, 483–484: 64–66.

    Article  Google Scholar 

  7. POWELL G L F, CARLSON R A, RANDLE V. The morphology and microtexture of M7C3 carbides in Fe-Cr-C and Fe-Cr-C-Si alloys of near eutectic composition [J]. Journal of Materials Science, 1994, 29(18): 4889–4896.

    Article  Google Scholar 

  8. PENG H F, SONG X Y, GAO A G, MA X L. Microstructure and mechanical properties of the Al-added ultrahigh carbon steel [J]. Materials Letters, 2005, 59(26): 3330–3332.

    Article  Google Scholar 

  9. LIU K P, DUN X L, LAI J P, LIU H S. Effects of modification on microstructure and properties of ultrahigh carbon (1.9% C) steel [J]. Materials Science and Engineering A, 2011, 528: 8263–8268.

    Article  Google Scholar 

  10. WAN R C, SUN F, ZHANG L T, SHAN A D. Effect of Mo on high-temperature strength of fire-resistant steel [J]. Materials and Design, 2012, 35: 335–341.

    Article  Google Scholar 

  11. BHOLE S D, NEMADE J B, COLLINS L, LIU C. Effect of nickel and molybdenum additions on weld metal toughness in a submerged arc welded HSLA line-pipe steel [J]. Journal of Materials Processing Technology, 2006, 173(1): 92–100.

    Article  Google Scholar 

  12. PINEDA E, BRUNA P, SERRANO J, TORRENS-SERRA J, CRESPO D. Roll of Mo in the local configuration and structure stabilization of amorphous steels, a synchrotron X-ray diffraction and Mossbauer study [J]. Journal of Alloys and Compounds, 2011, 509S: 56–59.

    Article  Google Scholar 

  13. WEI W, SHAN Y Y, YANG K, WANG Y Q. Effects of combined addition of Mo-B on transformed microstructure of ultrahigh-strength pipeline steels [J]. Acta Metallurgica Sinica, 2007, 43: 943–948. (In Chinese)

    Google Scholar 

  14. SHAERI M H, SAGHAFIAN H, SHABESTARI S G. Effects of austempering and martempering processes on amount of retained austenite in Cr-Mo steels (FMU-226) used in mill liner [J]. Journal of Iron and Steel Research International, 2010, 17(2): 53–58.

    Article  Google Scholar 

  15. ZHU Y Z, ZHU Z, YIN Z M, XIANG Z D. Evolution of carbides and carbon content in matrix of an ultra-high carbon sintered steel during heat treatment process [J]. International Journal of Minerals, Metallurgy and Materials, 2009, 16(3): 299–303.

    Article  Google Scholar 

  16. PARK S G, KIM M C, LEE B S, WEE D M. Correlation of the thermodynamic calculation and the experimental observation of Ni-Mo-Cr low alloy steel changing Ni, Mo, and Cr contents [J]. Journal of Nuclear Materials, 2010, 407(2): 126–135.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hua-shan Liu  (刘华山).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, L., Hu, B., Liu, Sg. et al. Effect of Mo on mechanical properties of modified ultrahigh carbon steels after heat-treatment. J. Cent. South Univ. 21, 1683–1688 (2014). https://doi.org/10.1007/s11771-014-2110-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-014-2110-5

Key words

Navigation