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Effect of modified humic acid binder on pelletisation of specularite concentrates

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Abstract

A modified humic acid (MHA) binder was tested as a substitute for bentonite to prepare qualified specularite pellets. The results show that there is stronger chemisorption between organic functional groups in MHA binder molecular and specularite particles, improving the green pellet strength. MHA binder has obvious effect on the strength and microstructure of preheated pellets due to the thermal decomposition of organic matters in MHA binder. Appropriately increasing preheating temperature or time can eliminate the adverse impact of organic matters on the preheated pellet strength. Compared with the bentonite pellets, the roasted pellets with MHA binder have a more compact microstructure, and the recrystallization of the Fe2O3 crystal grains is better. Consequently, under optimal conditions, 0.75% (mass fraction) MHA binder pellets have equal or better pellet strengths and contain 1.06% more total iron than 2 % bentonite pellets. The testing results indicate that MHA binder is a promising and effective alternative to bentonite for the specularite pellets.

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References

  1. JIANG Tao, ZHANG Yuan-bo, HUANG Zhu-cheng, LI Guang-hui, FAN Xiao-hui. Preheating and roasting characteristics of hematite-magnetite (H-M) concentrate pellets [J]. Ironmaking & Steelmaking, 2008, 35(1):21–26.

    Article  Google Scholar 

  2. ZHU Deng-qing, TANG Yan-yun, MENDERS V, PAN Jian, ZHAI Yong. Improvement in pelletization of Brazilian specularite by high-pressure roller grinding [J]. Journal of University of Science and Technology Beijing, 2009, 31(1):30–35. (in Chinese)

    Google Scholar 

  3. VIERA C B, SESHADR V, ROSIERE C A. Microstructural characterization of Brazilian iron ores for quality control in iron making-A geometallurgical approach [R]. San Antonio: Henry B Gonzales Convention Center, 2006.

    Google Scholar 

  4. SASTRY K V S, FUERSTENAU D W. Role of binders during pelletization of iron ore concentrate-pellet growth and strength aspects [C]// Proceedings of the 4th International Symposium on Agglomeration. USA: Iron and Steel Society Inc, 1985:41.

    Google Scholar 

  5. ALLEN A P. Role of binders in the agglomeration of minerals [C]// Proceedings of the 5th International Symposium on Agglomeration. USA: Iron and Steel Society Inc, 1989:215.

    Google Scholar 

  6. FU Ju-ying, JIANG Tao, ZHU De-qing. Sintering and pelletizing of iron ores [M]. Changsha: Central South University Press, 2006:256–259. (in Chinese)

    Google Scholar 

  7. EISELE T C, KAWATRA S K. A review of binders in iron ore pelletization [J]. Mineral Processing & Extractive Metall Rev, 2003, 24(1):1–90.

    Article  Google Scholar 

  8. SOUZA R P, MENDONCA C F, KATER T. Production of acid iron ore pellet for direct reduction using an organic binder [J]. Mineral Engineering, 1984, 36(10):1437–1441.

    Google Scholar 

  9. KATER T, STEEGHS H R G. Organic binders for iron ore pelletization [C]// 57th Annual Meeting of the Minnesota Section of AIME. Duluth: AIME, 1984:1–29.

    Google Scholar 

  10. LYONS R G, KUNDRAT D M, MYERS J C, WISE D. Evaluation of taconite pellets made with an organic binder [C]// Ironmaking Proccdings. USA: Iron & Steel Society of AIME, 1986:31–36.

    Google Scholar 

  11. CHEN Xu-lin, GAN Min, FAN Xiao-hui, JIANG Tao, WANG Yi, ZHAO Gai-ge. Concretion properties of organic-binder oxidate pellets and strengthen measures [J]. Journal of Central South University (Science and Technology), 2009, 40(3):550–554. (in Chinese)

    Google Scholar 

  12. AROI A I, ÖZBYOGLU G, HIÇYILMAZ C, AKDEMIR Ü, MAMUREKLI M. Determination of an alternative binder to bentonite in iron ore pelletization [C]// 11th Turkey Mining Scientific and Technical Congress. Ankara, 1989:393–405.

    Google Scholar 

  13. QIU Guan-zhou, FA Ke-qi, ZHU De-qing, WANG Dian-zuo. Interfacial characterizations of iron ore concentrates affected by binders [J]. Powder Technology, 2004, 139(1):1–6.

    Article  Google Scholar 

  14. FAN Xiao-hui, WANG Yi, GAN Min, YUAN Li-shun, DAI Lin-qing, ZHAO Gai-ge. Strength enhancement of oxide pellet with organic binder [J]. Jounal of Iron and steel Research, 2008, 20(5):5–8+19. (in Chinese)

    Google Scholar 

  15. JIANG Tao, HAN Gui-hong, ZHANG Yuan-bo, HUANG Yan-fang, LI Guang-hui, GUO Yu-feng, YANG Yong-bin. Improving extraction yield of humic substances from lignite with anthraquinone in alkaline solution [J]. Journal of Central South University, 2011, 18:68–72.

    Article  Google Scholar 

  16. JIANG Tao, HAN Gui-hong, ZHANG Yuan-bo, LI Guang-hui, HUANG Yan-fang. A further study on the interaction between one of organic active fractions of the MHA binder and iron ore surface [J]. International Journal of Mineral Processing, 2011, 100(3):172–178.

    Article  Google Scholar 

  17. HAN Gui-hong, ZHANG Yuan-bo, HUANG Yan-fang, LI Guang-hui, JIANG Tao. Adsorption behaviours of humic substances onto iron ore particle surface [C]// Proceedings of XXV International Mineral Processing Congress. New York: Curran Associates, Inc, 2010:163–171.

    Google Scholar 

  18. ZHANG Yuan-bo, LI Peng, ZHOU You-lian, HAN Gui-hong, LI Guang-hui, XU Bin, JIANG Tao. Adsorption of lignite humic acid onto magnetite particle surface [J]. Journal of Central South University, 2012, 19:1967–1972.

    Article  Google Scholar 

  19. ZHANG Yuan-bo, HAN Gui-hong, JIANG Tao, HUANG Yan-fang, LI Guang-hui, GUO Yu-feng, YANG Yong-bin. Structure characteristics and adhesive property of humic substances extracted with different methods [J]. Journal of Central South University, 2011, 18:1041–1046.

    Article  Google Scholar 

  20. HAN Gui-hong, JIANG Tao, LI Guang-hui, HUANG Yan-fang, ZHANG Yuan-bo. Investigation on modified humic substances based binders for iron ore agglomeration [J]. Journal of Engineering Materials and Technology, 2012, 134(1):1–5.

    Article  Google Scholar 

  21. ZHANG Yuan-bo, ZHOU You-lian, JIANG Tao, HAN Gui-hong, LI Guang-hui, XU Bin. Application of MHA binder in oxidized pellets preparation from vanadiu, titanium-bearing magnetite concentrates [J]. Journal of Central South University (Science and Technology), 2012, 43(7):2459–2466. (in Chinese)

    Google Scholar 

  22. LI Xiao-qin. Effects of atmosphere on roasting behaviors of carbon-burdened hematite pellets [D]. Changsha: Central South University, 2009. (in Chinese)

    Google Scholar 

  23. BAI Guo-hua, ZHANG Dao-yuan, ZHANG Yuan-bo, HAN Gui-hong, SU Zi-jian. Oxidized pellet preparation from refractory specularite concentrates using modIfied humic acid (MHA) binders [C]// Proceedings of the 2nd International Symposium on High-Temperature Metallurgical Processing. USA: John Wiley & Sons, Inc, 2011:299–305.

    Chapter  Google Scholar 

  24. RIPKE S J, KAWATRA S K. Can fly-ash extend bentonite binder for iron ore agglomeration? [J]. International Journal of Mineral Processing, 2000, 60(3):181–198.

    Article  Google Scholar 

  25. BASANTSEV G P. Temperature conditions for maghematite (gamma hematite) formation [J]. Russian Metallurgy, 1976, 4:30–32.

    Google Scholar 

  26. EDSTROM J O. The mechanism of reduction of iron oxides [J]. Journal of the Iron and Steel Institute, 1953, 175(3):289.

    Google Scholar 

  27. SCHULZ D L, MCCARTHY G J. X-ray powder data for an industrial magnetite (γ-Fe2O3) [J]. Powder Diffraction, 1988, 3(2):104–105.

    Article  Google Scholar 

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Correspondence to Yuan-bo Zhang  (张元波).

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Foundation item: Project(50804059) supported by the National Natural Science Foundation of China; Project(CX2012B121) supported by the Innovation Research Program for Graduate Student of Hunan Province, China

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Zhou, Yl., Zhang, Yb., Liu, Bb. et al. Effect of modified humic acid binder on pelletisation of specularite concentrates. J. Cent. South Univ. 22, 1247–1255 (2015). https://doi.org/10.1007/s11771-015-2640-5

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  • DOI: https://doi.org/10.1007/s11771-015-2640-5

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