Skip to main content
SpringerLink
Log in

Study on Saturated Solubility of MgO in Converter Vanadium Slag

  • Advances in Process Metallurgy
  • Published:
JOM Aims and scope Submit manuscript

Abstract

This article investigated the saturated solubility of MgO in converter vanadium slag and its influencing factors. The experimental results of MgO dissolution equilibrium are consistent with the theoretical calculation results. The results show that in MgO saturated vanadium slag, MgO mainly exists in MgV2O4 and MgSiO3. The increase of V2O3 content or the decrease of the FeO/SiO2 ratio is beneficial to increasing the saturated solubility of MgO in the FeO-SiO2-V2O3 slag system. The saturated solubility of MgO in vanadium slag increases from 7.5 to 8.0 wt.% when the temperature increases from 1633 to 1753 K. In addition, the solubility of MgO also increases with the increase of TiO2 and Al2O3 content and decreases with the increase of MnO content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. T.S. Su and LL, Converter Slag Splashing Protection Technology, 1st ed. (Beijing: Metallurgical Industry Press, 1999), pp. 7–14.

    Google Scholar 

  2. K.C. Mills, Y.C. Su, A.B. Fox, Z. LI, and R.P. Thackray, ISIJ Int. 45, 620 (2005).

    Article  Google Scholar 

  3. B.T., Z.Y. Zhao, H.B. Li, X.F. Ren, B.L. H.C. Chen, J.W., Y.L. Zhang. Earth and Environmental Science.199, 2 (2018).

  4. F. Du, Shanghai Metal. 22, 55 (2000).

    Google Scholar 

  5. J.C. Wang, H.S. Chen, G.S. Li, Q.L. Xie, and X.B. Deng, Iron Steel Vanadium Titanium. 19, 43 (1998).

    Google Scholar 

  6. S.L. Zeng and W.L. Zeng, Metal Mine. 5, 61 (2008).

    Google Scholar 

  7. D. Huang, Vanadium Extraction and Steelmaking, 1st ed. (Beijing: Metallurgical Industry Press, 2000), pp. 24–25.

    Google Scholar 

  8. Q. Zhang, unpublished Research (Chongqing: Chongqing University, 2019).

    Google Scholar 

  9. C.W. Bale, P. Chartrand, S.A. Degterov, G. Eriksson, K. Hack, R. Ben Mahfoud, J. Melançon, A.D. Pelton, and S. Petersen, Calphad Comput. Coupling Phase Diagr. Thermochem. 26, 191 (2002).

    Google Scholar 

  10. German Metal Institute, Slag Atlas, 2nd ed. (Beijing: Metallurgical Industry Press, 1995), p. 47.

    Google Scholar 

  11. Y.Q. Liu, Silicate Ceramic Phase Diagram, 1st ed. (Beijing: Chemical Industry Press, 2011), p. 82.

    Google Scholar 

  12. K. Norihito, T. Makoto, and Y. Yuji, Catal. Lett. 127, 65 (2009).

    Google Scholar 

  13. W.T. Du and I.H. Jung, Calphad. 67, 9 (2019).

    Article  Google Scholar 

  14. J. Diao, B. Xie, C. Ji, X. Guo, Y. Wang, and X.J. Li, Cryst. Res. Technol. 44, 707 (2009).

    Article  Google Scholar 

  15. J. Diao, Y. Qiao, X. Zhang, C.Q. Ji, and B. Xie, Cryst Eng Comm. 17, 7302 (2015).

    Article  Google Scholar 

  16. M. Nohair, D. Aymes, and P. Perriat, Vib. Spectrosc. 9, 181 (1995).

    Article  Google Scholar 

  17. K. Dodd and R.A. Mackay, International Textbook (London: Elsevier, 1981), p. 206.

    Google Scholar 

  18. German Metal Institute, Slag Atlas, 2nd ed. (Beijing: Metallurgical Industry Press, 1995), p. 94.

    Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (no. 51974047).

Author information

Authors and Affiliations

  1. College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, China

    Jiang Diao, Yi-Yu Qiu, Jing Lei, Quan Zhang, Wen-Feng Tan, Hong-Yi Li & Bing Xie

  2. Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing, 400044, China

    Jiang Diao, Yi-Yu Qiu, Jing Lei, Quan Zhang, Wen-Feng Tan, Hong-Yi Li & Bing Xie

Authors
  1. Jiang Diao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yi-Yu Qiu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jing Lei
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Quan Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Wen-Feng Tan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hong-Yi Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Bing Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jiang Diao.

Ethics declarations

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Diao, J., Qiu, YY., Lei, J. et al. Study on Saturated Solubility of MgO in Converter Vanadium Slag. JOM 73, 999–1003 (2021). https://doi.org/10.1007/s11837-020-04450-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-020-04450-8

Search

Navigation