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Analysis of P(VdCl-co-AN-co-MMA)-LiClO4-EC triblock copolymer electrolytes

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Abstract

The lithium ion conducting copolymer electrolytes based on poly(vinylidene chloride-co-acrylonitrile- co-methyl methacrylate) P(VdCl-co-AN-co-MMA)-lithium per chlorate (LiClO4) (P(VdCl-co-AN-co-MMA): LiClO4) and poly(vinylidene chloride-co-acrylonitrile-co-methyl methacrylate)P(VdCl-co-AN-co-MMA)-lithium per chlorate (LiClO4)-ethylene carbonate (EC) (P(VdCl-co-AN-co-MMA):LiClO4:EC) of different compositions were prepared by solution-casting technique. Structural and surface morphological characterizations were studied by X-ray diffraction analysis and scanning electron microscopy measurements, respectively. Thermal and conductivity behaviour of copolymer–salt and copolymer–salt–plasticizer complexes were studied by employing differential scanning calorimetry and AC impedance measurements, respectively. The highest bulk conductivity was found to be 1.94 × 10−4 S cm−1 at 303 K for the plasticized sample. The dielectric behaviour and relaxation parameters of the samples have been presented and discussed.

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Authors and Affiliations

  1. Research and Development Centre, Bharathiar University, Coimbatore, 641 046, India

    D INBAVALLI

  2. Materials Research Centre, Coimbatore, 641 045, India

    D INBAVALLI, S SELVASEKARAPANDIAN & S NITHYA

  3. Department of Physics, Alagappa University, Karaikudi, 630 003, India

    C SANJEEVIRAJA

  4. Institute of Multi Disciplinary Research for Advanced Materials, Tohoku University, Sendai, 980-8577, Japan

    R BASKARAN & JUNICHI KAWAMURA

  5. SRNM College, Sattur, 626 203, India

    S NITHYA

  6. National Institute of Advanced Industrial Science and Technology (AIST), Nagoya, 463-8560, Japan

    YOSHITAKE MASUDA

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  1. D INBAVALLI
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  2. S SELVASEKARAPANDIAN
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  3. C SANJEEVIRAJA
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  4. R BASKARAN
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  6. JUNICHI KAWAMURA
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INBAVALLI, D., SELVASEKARAPANDIAN, S., SANJEEVIRAJA, C. et al. Analysis of P(VdCl-co-AN-co-MMA)-LiClO4-EC triblock copolymer electrolytes. Bull Mater Sci 38, 183–190 (2015). https://doi.org/10.1007/s12034-014-0797-4

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  • DOI: https://doi.org/10.1007/s12034-014-0797-4

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