Abstract
TiO2 nanoparticle (NP), composite TiO2 nanoparticle–nanorod (NP–NR) and bi-layer TiO2 nanoparticle/nanorod (NP/NR) with the optimized diameter of NRs had been prepared as anode layer in dye-sensitized solar cells (DSSCs). Morphology and thickness of anode layers were provided by field emission scanning electron microscope (FE-SEM) and scanning electron microscopy (SEM) devices. Current density–voltage diagrams were prepared by potentiostat and solar simulator devices at air mass (AM) 1.5. It is determined that DSSCs based on composite NP–NR photoelectrode had the best conversion efficiency of 5.07%. Also, the results of the electrochemical modelling of these DSSCs indicated that solar cells based on NP–NR electrode had the highest electron transport time (τ d) of 312.87 ms, electrons’ recombination lifetime (τ n) of 130.4 ms and the lowest transfer resistance (R ct) as well as transport resistance (R t) of 22.46 and 9.4 Ω, respectively.
Similar content being viewed by others
References
O’Regan B and Gratzel M 1991 Nature 353 737
Noack V, Weller H and Eychmuller A 2002 J. Phys. Chem. B 106 8514
Chiba Y, Islam A, Watanabe Y, Komiya R, Koide N and Han L Y 2006 J. Appl. Phys. 45 638
Rhee S W and Kwon W 2011 Korean J. Chem. Eng. 28 1481
Yoon Y I, Moon H S, Lyoo W S, Lee T S and Park W H 2009 Carbohydr. Polym. 75 246
Nazeeruddin M K, Pechy P, Renouard T, Zakeeruddin S M, Humphry-Baker R, Comte P et al 2001, J. Am. Chem. Soc. 123 1613
Tae E L, Lee S H, Lee J K, Yoo S, Kang E J and Yoon K B 2005 J. Phys. Chem. B 109 22513
Shan C X, Liu Z, Zhang Z Z, Shen D Z and Hark S K 2006 , J. Phys. Chem. B 110 11176
Gratzel M 2003 J. Photochem. Photobiol. C 4 145
Du S F, Liu H D and Chen Y F 2009 Nanotechnology 20 1
Yang L and Leung W 2013 Adv. Mater. 25 1792
Meng L, Li C and dos Santos M P 2013 J. Inorg. Organomet. Polym. 23 787
Zhang W, Zhu R, Liu B and Ramakrishna S 2011 Aust. J. Chem. 64 1282
Ghadiri E, Taghavinia N, Zakeeruddin S M, Gratzel M and Moser E 2010 Nano Lett. 10 1632
Gratzel M 2005 Inorg. Chem. 44 6841
Laurence P 2009 Acc. Chem. Res. 42 1839
Jang Y H, Xin X K, Byun M, Jang Y J, Lin Z Q and Kim D H 2011 Nano Lett. 12 479
Li X, Lin H, Li J B, Li X X, Cui B and Zhang L Z 2008 , J. Phys. Chem. C 112 13744
Parvazian E, Karimzadeh F and Enayati M H 2014 J. Electron. Mater. 43 1450
Ferber J and Luther J 1998 Sol. Energy Mater. Sol. C 54 265
Tan B and Wu Y 2005 J. Phys. Chem. B 110 15932
Kang S H, Choi S H, Kang M S, Kim J Y, Kim H S, Hyeon T and Sung Y E 2008 Adv. Mater. 20 54
Adachi M, Murata Y, Takao J, Jiu J, Sakamoto M and Wang F 2004 J. Am. Chem. Soc. 126 14943
Wu J J, Chen G R, Lu C C, Wu W T and Chen J S 2008 Nanotechnology 19 105702
Madhugiri S, Dalton A, Gutierrez J, Ferraris J J P and Balkus K J 2003 J. Am. Chem. Soc. 125 14531
Bognitzki M, Czado W, Frese T, Schaper A, Hellwig M, Steinhart M, Greiner A and Wendorff J H 2001 Adv. Mater. 13 70
Zhan S H, Chen D R, Jiao X L and Liu S S 2007 J. Colloid Interface Sci. 308 265
Li D and Xia Y N 2003 Nano Lett. 3 555
Hou H Q and Reneker D H 2004 Adv. Mater. 16 69
Zhao J G, Jia C W, Duan H G, Sun Z W, Wang X M and Xie E Q 2008 J. Alloys Compd. 455 497
Ito S, Murakami T N, Comte P, Liska P, Grätzel C, Nazeeruddin M K and Grätzel M 2008 Thin Solid Films 516 4613
Bisquert J, Fabregat-Santiago F, Mora-Seró I, Garcia-Belmonte G and Gimenez S 2009 J. Phys. Chem. C 113 17278
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
REZVANI, F., PARVAZIAN, E. & HOSSEINI, S.A. Dye-sensitized solar cells based on composite TiO2 nanoparticle–nanorod single and bi-layer photoelectrodes. Bull Mater Sci 39, 1397–1402 (2016). https://doi.org/10.1007/s12034-016-1278-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-016-1278-8