Abstract
Mordenite (HM) catalysts with three different Si/Al ratios were compared for their activity and selectivities in gas phase toluene isopropylation with isopropanol. Catalyst with Si/Al ratio 44.9 offered better cumene selectivity, hence, it was chosen for detailed kinetic investigations. The influence of various process parameters like temperature, time-on-stream, weight hourly space velocity (WHSV), reactant mole ratio on this catalyst activity are discussed. The cymene selectivity was found to increase with reaction temperature and passed through a maximum at 473 K. The deactivation with time-onstream is almost negligible. Lower isopropyl alcohol concentration in the feed improved cymene selectivity. The conversion and selectivity to cymenes were compared with those of the large pore beta catalyst. The rate constant and activation energy were found to be 7.34 m3/kg h and 41.84 kJ/mol, respectively using homogeneous kinetic model.
Similar content being viewed by others
References
Allen R H and Yats L D 1961 J. Amer. Chem. Soc. 83 2799
Olah G A, Kuhn S J and Flood S H 1962 J. Amer. Chem. Soc. 84 1688
Fraenkel D and Levy M 1989 J. Catal. 118 10
Parikh PA, Subrahmanyam N, Bhat Y S and Halgeri AB 1992 Appl. Catal. A 90 1
Guo H, Han C and Wang X 1993 Shiyou Xuebao Shiyou Jiagong 9 41
Čejka J, Kapustin G A and Witchterlová B 1994 Appl. Catal. A108 187
Reddy K S N, Rao B S and Shiralkar V P 1995 Appl. Catal. A121 191
Witchterlová B, Čejka J and Zilkova N 1996 Microporous Mater. 6 405
Medina-Valtierra J, Sanchez M A, Montoya J A, Navarrete J and De Los Reyes J A 1997 Appl. Catal. A158 11
Witchterlová B and Čejka J 1994 J. Catal. 146 523
Yue P L and Olaofe O 1984 Chem. Eng. Res. Des. 62 167
Palekar M G and Rajadhyaksha R A 1986 Catal. Rev. Sci. Eng. 28 371
Parikh P A, Subrahmanyam N, Bhat Y S and Halgeri A B 1991 Chem. Eng. J. 54 79
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Upadhyayula, S. Gas phase toluene isopropylation over high silica mordenite. J Chem Sci 122, 613–619 (2010). https://doi.org/10.1007/s12039-010-0096-6
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12039-010-0096-6