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Study on physico-chemical properties, mineral matters and leaching characteristics of some Indian coals and fly ash

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Journal of the Geological Society of India

Abstract

Six high sulphur coal samples along with two fly ash samples were characterized by using X-ray diffraction (XRD), Energy Dispersive x-ray Fluorescence (EDXRF), Atomic Absorption Spectroscopy (AAS), Fourier Transform Infrared (FT-IR) and Scanning Electron Spectroscopy (SEM) techniques to interpret their mineral matters and inorganic constituents. The proximate, ultimate and sulfur analyses of the coal and fly ash samples were also performed to know their possible aspects of utilization. Significant amount of silicate/clay minerals along with other elements are found to be present in these coals and fly ash samples. The SEM micrographs showed the presence of pyrite and marcasite in different forms including clusters of pyrites in the coals. The leaching characteristics of the coal and fly ash samples showed the mobilization of some potentially hazardous elements (PHEs) from them. Mercury was found to be leached out with ~0.50 ppm from fly ash samples in water.

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References

  • Acharya, B.S. (1992) Quantitative determination of minerals in Indian coal by X-ray diffraction, Fuel. v.71, pp.346–348.

    Article  Google Scholar 

  • Baruah, B.P. (2009) Environmental Studies around Makum Coalfields, Assam, India, LAP Lambert Academic Publishing.

    Google Scholar 

  • Baruah, B.P., Saikia, B. K., Kotoky, P., Rao, P.G. (2006) Aqueous leaching on high sulphur sub-bituminous coals in Assam, India, Energy & Fuels, v.20(4), pp.1550–1555.

    Google Scholar 

  • Boruah, R.K., Saikia, B.K., Baruah, B.P., Dey, N.C. (2008) Xray scattering study of the average poly-cyclic aromatic unit in Ledo coal, Jour. Appld. Crystallography, v.41, pp.27–30.

    Article  Google Scholar 

  • Cooke, N.E., Fuller, M.O. Gaikwad, R.P. (1986) FT-IR Spectroscopic analysis of coals and coal extracts, Fuel, v.65, pp.1254.

    Article  Google Scholar 

  • Gadsen, J.A. (1975) Infrared spectra of minerals and related inorganic compounds, Butterworths, London.

    Google Scholar 

  • Ghose, S.K. and Dutta, S.C. (1996) Indian Soc. Nuclear Tech. Agric Biol., pp.98.

    Google Scholar 

  • Ghose, S.K. and Kapoor, B.S. (1982) Review of soil research in India, Part 2, Indian Society of Soil Science, New Delhi

    Google Scholar 

  • Given, P.H., Davis, A., Kuchn, D., Painter, P., Spackman, W. (1985) A multi-facetted study of a cretaceous coal with algal affinities. Provenance of the coal samples and basic compositional data, Internat Jour. Coal Geol., v.5, pp.247–260.

    Google Scholar 

  • Grigoriew, H. (1990) Diffraction Studies of coal structure, Fuel, v.69(7), pp.840–845.

    Article  Google Scholar 

  • KARR, C. (ffixJr) (1978a) Analytical methods for coal and coal products, New York, Academic Press, pp.192–224.

    Google Scholar 

  • KARR, C. (ffixJr). (1978b) Analytical methods for coal and coal products, New York, Academic Press

    Google Scholar 

  • Khare, P. and Baruah, B.P. (2010) Structural Parameters of Perhydrous Indian Coals. Internat. Jour. Coal Preparation and Utilization, v.30(1), pp.44–67.

    Article  Google Scholar 

  • Lopez-Anton, M.A., Diaz-Somoano, M., Ochoa-Gonzalez, R., Martinez-Tarazona, M.R. (2012) Analytical methods for mercury analysis in coal and coal combustion by-products, Internat. Jour. Coal Geol., v.94(1), pp.44–53.

    Article  Google Scholar 

  • Mandile, A.J. and Hutan, A.C. (1995) Quantitative X-ray diffraction analysis of mineral and organic phase in organicrich rocks, Internat. Jour. Coal Geol., v.28, pp.51–69.

    Article  Google Scholar 

  • Nayak, B. (2013) Mineral matter and the nature of pyrite in some high-sulfur tertiary coals of Meghalaya, northeast India, Jour. Geol. Soc. India, v.81, pp.203–214.

    Article  Google Scholar 

  • Nayak, P.S. and Singh, B.K. (2007) Instrumental characterization of clay by XRD, XRF and FTIR. Bull. Mater Sci., v.30(3), pp.235–238.

    Article  Google Scholar 

  • Oliveira, M.L.S., Marostega, F., Taffarel, S.R., Saikia, B.K., Waanders, F.B., Daboit, K., Baruah, B.P., Silva, L.F.O. (2014) Nano-mineralogical investigation of coal and fly ashes from coal-based captive power plant (India): An introduction of occupational health hazards. Science of the Total Environment. v.468–469, pp.1128–1137

    Article  Google Scholar 

  • Painter, P.C., Rimmer, S.M., Snyder, R.W. and Davis, A. (1981) A Fourier Transform Infrared Study of Mineral Matter in coal: The Application of a Least Square Curve-Fitting Programme, Applied Spectroscopy, v.35, pp.102–106.

    Article  Google Scholar 

  • Qiu, Y., Zhang, Q., Tian, Y., Zhang, J., Cao, J., Xiao, T. (2011) Composition and structure of Luxing Coal with different particle sizes, Petroleum and Coal. v.53(1), pp.45–55

    Google Scholar 

  • Rabek, J.F. (1980) Experimental Methods in Polymer Chemistry, John Wiley & Sons, Chichester. pp.507–510.

    Google Scholar 

  • Saikia, B.K. (2009) Scanning electron microscopy of Assam coals. Jour. Geol. Soc. India, v.74, pp.749–752.

    Article  Google Scholar 

  • Saikia, B.K., Boruah, R.K., Gogoi, P.K. (2007) FT-IR and XRD analysis of coal from Makum coalfield of Assam. Jour. Earth Syst. Sci., v.116 (6), pp.575–579.

    Article  Google Scholar 

  • Saikia, B.K., Boruah, R.K., Gogoi, P.K. (2007) XRD and FT-IR investigation of sub-bituminous Assam coals, Bull Mater Sci., v.30(4), pp.421–426.

    Article  Google Scholar 

  • Saikia, B.K., Boruah, R.K., Gogoi, P.K., Baruah, B.P. (2009) A Thermal Study on Coals from Makum coalfield, Assam, India, Fuel Processing Technology, v.90, pp.196–203.

    Article  Google Scholar 

  • Saikia, B.K., Goswamee, R.L., Baruah, B.P., Boruah, R.K. (2009) Occurrence of Some Metals in Assam (India) Coals. Coke and Chemistry, v.52(2), pp.54–59.

    Article  Google Scholar 

  • Saikia, B.K., Ninomiya, Y. (2011) An investigation on the heterogeneous nature of mineral matters in Assam (India) coal by CCSEM technique. Fuel Process. Tech., v.92, pp.1068–1077.

    Article  Google Scholar 

  • Saikia, B.K., Sahu,O.P., Boruah, R.K. (2007) FT-IR Spectroscopic Investigation of High Sulphur Assam Coals and their Solventextracts. Jour. Geol. Soc. India, v.70, pp.917–922.

    Google Scholar 

  • Saikia, B.K., Sarmah, M., Khare, P., Baruah, B.P. (2013) Investigation on inorganic constituents in Indian coal and emission characteristics of the particulates (PM2.5 and PM10), Energy Exploration and Exploitation. v.31, pp.287–315

    Article  Google Scholar 

  • Saikia, B.K., Ward, C.R., Oliveira, M.L.S., Hower, J.C, Baruah, B.P., Braga, M., Silva, L.F. (2014) Geochemistry and nanomineralogy of two medium-sulfur northeast Indian coals, Internat. Jour. Coal Geol., v.121, pp.26–34

    Article  Google Scholar 

  • Scheinman, F. (1970) An introduction to spectroscopic methods for the identification of organic compounds, Oxford, Pergamon Press

    Google Scholar 

  • Senior, C.L., Zeng, T., Che, J., Ames, M.R., Sarofim, A.F., Olmez, I., Huggins, F.E., Shah, N., Huffman, G.P., Kolker, A., Mroczkowski, S., Palmer, C., Finkelman, R. (2000) Distribution of trace elements in selected pulverized coals as a function of particle size and density, Fuel Processing Technology. v. 63, pp. 215–241

    Article  Google Scholar 

  • Silverstein, R.M., Bassler, G.C., Morril, T.C. (1987) Spectrometric identification of organic compunds. New York: Wiley

    Google Scholar 

  • Song, D., Yang, C., Zhang, X., Su, X., Zhang, X. (2011) Structure of the organic crystallite unit in coal as determined by X-ray diffraction. Mining Science and Technology (China), v.21 (5), pp.667–671.

    Article  Google Scholar 

  • Speight, J.G. (2005) Handbook of coal analysis, John Wiley & Sons, Inc, New Jersey

    Book  Google Scholar 

  • Speight, J.G. (1983) The chemistry and technology of coal, Marcel Dekker, New York

    Google Scholar 

  • Speight, J.G. (1973) Application of Spectroscopic Technique to the Structural Analysis of Coal. Appld. Spectro. Rev., v.29, pp.117.

  • Wang, J. and Tomita, A. (2003) Chemistry on the volatility of some trace elements during coal combustion and pyrolysis, Energy and Fuel, v.17, pp.954.

    Article  Google Scholar 

  • Ward, C.R. (2002) Analysis and significance of mineral matter in coal seams, Int. J. Coal. Geol., v.50, pp.135–168.

    Article  Google Scholar 

  • Wilson, M.J. (Ed.) (1994) Clay Mineralogy: Spectroscopic and Chemical determinative methods

    Book  Google Scholar 

Download references

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Correspondence to Binoy K. Saikia.

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Saikia, B.K., Sharma, A., Sahu, O.P. et al. Study on physico-chemical properties, mineral matters and leaching characteristics of some Indian coals and fly ash. J Geol Soc India 86, 275–282 (2015). https://doi.org/10.1007/s12594-015-0312-6

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  • DOI: https://doi.org/10.1007/s12594-015-0312-6

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