Abstract
The characteristics of inclusions in high-Al steel refined by electroslag remelting (ESR) were investigated by image analysis, scanning electron microscopy (SEM), and energy-dispersive spectrometry (EDS). The results show that the size of almost all the inclusions observed in ESR ingots is less than 5 μm. Inclusions smaller than 3 μm take nearly 75% of the total inclusions observed in each ingot. Inclusions observed in ESR ingots are pure AlN as dominating precipitates and some fine spherical Al2O3 inclusions with a size of 1 μm or less. It is also found that protective gas operation and slag deoxidation treatment during ESR process have significant effects on the number of inclusions smaller than 2 μm but little effects on that of inclusions larger than 2 μm. Thermodynamic calculations show that AlN inclusions are unable to precipitate in the liquid metal pool under the present experimental conditions, while the precipitation of AlN inclusions could take place at the solidifying front due to the microsegregation of Al and N in liquid steel during solidification.
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References
H.B. Yin, Inclusion characterization and thermodynamics for high-Al advanced high-strength steels, Iron Steel Technol., 25(2006), p.64.
V. Weber, A. Jardy, B. Dussoubs, D. Ablitzer, S. Rybéron, V. Schmitt, S. Hans, and H. Poisson, A comprehensive model of the electroslag remelting process: description and validation, Metall. Mater. Trans. B, 40(2009), No.3, p.271.
S.K. Maity, N.B. Ballal, G. Goldhahn, and R. Kawalla, Development of ultrahigh strength low alloy steel through elec troslag refining process, ISIJ Int., 49(2009), No.6, p.902.
Z.B. Li, Electroslag Metallurgy Theory and Practice, Metallurgical Industry Press, Beijing, 2010, p.63.
N.H. Croft, A.R. Entwisle, and G.J. Davies, Origins of dendritic AlN precipitates in aluminium-killed steel castings, Met. Technol., 10(1983), p.125.
J. Fu and J. Zhu, Change of oxide inclusions during electroslag remelting process, Acta Metall. Sin., 7(1964), No.3, p.250.
D.G. Zhou, X.C. Chen, J. Fu, P. Wang, J. Li, and M.D. Xu, Inclusions in electroslag remelting and continuous casting bearing steels, J. Univ. Sci. Technol. Beijing (in Chinese), 22(2000), No.1, p.26.
Z.B. Li, W.H. Zhou, and Y.D. Li, Mechanism of removal of non-metallic inclusions in the ESR process, Iron Steel, 15(1980), No.1, p.20.
Z.B. Li, J.W. Zhang, and X.Q. Che, Control of content and composition of non-metallic inclusion in ESR steel, J. Iron Steel Res., 9(1997), No.2, p.7.
S. Ahmadi, H. Arabi, A. Shokuhfar, and A. Rezaei, Evaluation of the electroslag remelting process in medical grade of 316LC stainless steel, J. Mater. Sci. Technol., 25(2009), No.5, p.592.
D.A.R. Kay and R.J. Pomfret, Removal of oxide inclusions during ac electroslag remelting, J. Iron Steel Inst., 209(1971), p.962.
J.C. Labbe and A. Laïmeche, Study of the behaviour of aluminium nitride in the iron and steel industry, J. Eur. Ceram. Soc., 16(1996), No.8, p.893.
H. Wada and R.D. Pehlke, Nitrogen solubility and aluminum nitride precipitation in liquid iron, Fe-Cr, Fe-Cr-Ni, and Fe-Cr-Ni-Mo alloys, Metall. Trans. B, 9(1978), No.4, p.441.
J.H. Park, S.B. Lee, D.S. Kim, and J.J. Pak, Thermodynamics of titanium oxide in CaO-SiO2-Al2O3-MgOsatd-CaF2 slag equilibrated with Fe-11mass%Cr melt, ISIJ Int., 49(2009), No.3, p.337.
H. Ohta and H. Suito, Activities in CaO-SiO2-Al2O3 slags and deoxidation equilibria of Si and Al, Metall. Mater. Trans. B, 27(1996), No.6, p.943.
H. Itoh, M. Hino, and S. Ban-ya, Assessment of Al deoxidation equilibrium in liquid iron, Tetsu-to-Hagané, 83(1997), No.12, p.773.
The 19th Committee in Steelmaking of the Japan Society for the Promotion of Science, Steelmaking Data Sourcebook, Gordon and Breach Science Publishers, New York, 1988, p.280.
M. Suzuki, R. Yamaguchi, K. Murakami, and M. Nakada, Inclusion particle growth during solidification of stainless steel, ISIJ Int., 41(2001), No.3, p.247.
T. Binran, Handbook of Iron and Steel, Vol.1, 3rd, Edited by Iron and Steel Institute of Japan, Maruzen, Tokyo, 1980, p.205.
M.A.T. Andersson, P.G. Jönsson, and M.M. Nzotta, Application of the sulphide capacity concept on high-basicity ladle slags used in bearing-steel production, ISIJ Int., 39(1999), No.11, p.1140.
H. Ohta and H. Suito, Calcium and magnesium deoxidation in Fe-Ni and Fe-Cr alloys equilibrated with CaO-Al2O3 and CaO-Al2O3-MgO slags, ISIJ Int., 43(2003), No.9, p.1293.
S.K. Choudhary and A. Ghosh, Mathematical model for prediction of composition of inclusions formed during solidification of liquid steel, ISIJ Int., 49(2009), No.12, p.1819.
W. Kurz and D.J. Fisher, Fundamentals of Solidification, 3rd Ed, Trans Tech Pubilcations, Switzerland, 1992, p.280.
E.T. Turkdogan, Fundamentals of Steelmaking, The Institute of Materials, London, 1996, p.298.
A. Mitchell, Oxide inclusion behavior during consumable electrode remelting, Ironmaking Steelmaking, 1(1974), No.3, p.172.
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This work was financially supported by the International Science and Technology Cooperation and Exchange of Special Projects (No. 2010DFR50590).]
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Shi, Cb., Chen, Xc. & Guo, Hj. Characteristics of inclusions in high-Al steel during electroslag remelting process. Int J Miner Metall Mater 19, 295–302 (2012). https://doi.org/10.1007/s12613-012-0554-x
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DOI: https://doi.org/10.1007/s12613-012-0554-x